• Clean Technology
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• v.26 no.3
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• pp.221-227
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• 2020

When the waste solid fuel (SRF, Bio-SRF) is burnt in a boiler, a problem occurs in the combustion process involving the alkali components (Na, K) contained in large amounts in the fuel. The alkaline component has a low melting point, which usually forms low melting point salt in the temperature of the furnace, with the resulting low melting point salts attaching to the heat pipe to form a clinker. Various additives are used to suppress clinker generation, and the additive based on the kaolinite has alkali-aluminum-silica to inhibit the clinker. In this study, the reactivity of the additives based on the kaolinite was compared. The additives utilized were R-kaolinite, B-kaolinite, and A-kaolinite. Also silica and MgO were sourced as the comparison group. The experimental group was employed as a laboratory-scale batch horizontal reactor. The additive and alkaline salts were reacted at a weight ratio of 1 : 1, and the reaction temperature was performed at 900 ℃ for 10 hours. The first measurement of HCl occurring during the experiment was performed 30 minutes after the detection tube was used, and the process was repeated every hour after the experiment. After the reaction, solid residues were photographed for characterization analysis by means of an optical microscope. The reaction characteristics of the kaolinite were confirmed based on the analysis results.

• KEPCO Journal on Electric Power and Energy
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• v.2 no.4
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• pp.531-536
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• 2016

The worldwide research and development for high-efficiency power generation system is progressing steadily because of the growing demand for reducing greenhouse gas emissions. Many countries have spurred the research and development of supercritical $CO_2$ power generation technology since 2000 because it has the advantage of compactness, efficiency, and diversity. Supercritical $CO_2$ power generation system can be classified into an indirect heating type and a direct heating type. As of now, most studies have concentrated on the development of indirect type supercritical $CO_2$ power generation system. In the United States, NREL(National Renewable Energy Lab.) is developing supercritical $CO_2$ power generation system for Concentrating Solar Power. In addition, U.S. DOE(Department of Energy) also plans to start investing in the development of the supercritical $CO_2$ power generation system for coal-fired thermal power plant this year. GE is developing not only 10MW supercritical $CO_2$ power generation turbomachinery but also the conceptual design of 50MW and 450MW supercritical $CO_2$ power generation turbomachinery. In Korea, the Korean Atomic Energy Research Institute has constructed the supercritical $CO_2$ power generation test facility. Moreover, KEPRI(Korea Electric Power Research Institute) is developing a 2MW-class supercritical $CO_2$ power generation system using diesel and gas engine waste heat with Hyundai Heavy Industries.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.172-172
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• 2011

Anaerobic digestion(AD) has successfully been used for many applications that have conclusively demonstrated its ability to recycle biogenic wastes. AD has been successfully applied in industrial waste water treatment, stabilsation of sewage sludge, landfill management and recycling of biowaste and agricultural wastes as manure, energy crops. During AD, i.e. organic materials are decomposed by anaerobic forming bacteria and fina1ly converted to excellent fertilizer and biogas which is primarily composed of methane(CH4) and carbon dioxide(CO2) with smaller amounts of hydrogen sulfide(H2S) and ammonia(NH3), trace gases such as hydrogen(H2), nitrogen(N2), carbon monoxide(CO), oxygen(O2) and contain dust particles and siloxanes. The production and utilisation of biogas has several environmental advantages such as i)a renewable energy source, ii)reduction the release of methane to the atomsphere, iii)use as a substitute for fossil fuels. In utilisation of biogas, most of biogas produced from small scale plant e.g. farm-scale AD plant are used to provide as energy source for cooking and lighting, in most of the industrialised countries for energy recovery, environmental and safety reasons are used in combined heat and power(CHP) engines or as a supplement to natural. In particular, biogas to use as vehicle fuel or for grid injection there different biogas treatment steps are necessary, it is important to have a high energy content in biogas with biogas purification and upgrading. The energy content of biogas is in direct proportion to the methane content and by removing trace gases and carbon dioxide in the purification and upgrading process the energy content of biogas in increased. The process of purification and upgrading biogas generates new possibilities for its use since it can then replace natural gas, which is used extensively in many countries, However, those technologies add to the costs of biogas production. It is important to have an optimized purification and upgrading process in terms of low energy consumption and high efficiency giving high methane content in the upgraded gas. A number of technologies for purification and upgrading of biogas have been developed to use as a vehicle fuel or grid injection during the passed twenty years, and several technologies exist today and they are continually being improved. The biomethane which is produced from the purification and the upgrading process of biogas has gained increased attention due to rising oil and natural gas prices and increasing targets for renewable fuel quotes in many countries. New plants are continually being built and the number of biomethane plants was around 100 in 2009.

• Journal of Korean Tunnelling and Underground Space Association
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• v.18 no.4
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• pp.355-364
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• 2016

Recently, a 3,250 meter-long tunnel was constructed beneath the sea bed formed of composite sedimentary soils to transport reusable waste heat gas of industrial complex in the west coast of Korea. Some risks such as machine settlement always exist due to the uncertainties of geological and construction factors during the subsea shield TBM tunnelling. In this construction site, the deviation of tunnel alignment caused by shield TBM settlement was occurred during excavation. It was examined that the lack of bearing capacity of soft clay was a main cause. This paper evaluates the risk of shield TBM tunnelling considering the ground conditions. Correlation between machine settlement and its advance rate was evaluated through the analytical equation in which bearing capacity is considered and a 3-D numerical analysis which can simulate the TBM advance condition (in other words, the dynamic condition). It was found out that a shield TBM could settle due to the insufficient bearing capacity of soft clay layers. In order to prevent such the problem, the best advance rate proper to the ground characteristics is needed to be applied. In the ground conditions of the section of interest, it was turned out that if the shield TBM advance rate was maintained between 35 mm/min and 40 mm/min, the machine settlement could be avoided.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.1
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• pp.25-33
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• 2018

Renewable energy has been of interests in the area of modern alternative fuels. Biogas is produced in waste landfill sites through anaerobic digestion processes, including hydrolysis, acidogenesis, organic acid fermentation (acetogenesis), and methane fermentation (methanogenesis). High contents of fine dust and moisture limited its utilization for direct combustion, town gas and vehicle fuel. Thus, this study proposed a new design for a cooling device using a centrifugal cyclone for simultaneous removal of fine dust and moisture as a pretreatment in the purification processes. A heat exchanger and an ID fan, which are installed inside and outside of the cyclone, in order to cool the humid gas below the freezing point and form a foggy mist. Such an atmosphere enhanced to capture fine dust as recirculating the cold mist flow. The water removal rate was 80.8% at a relative humidity of 95%, and the particle removal efficiency was 98.3% for $2.5{\mu}m$. Simultaneous removal efficiency was 70.8% and 99.6% for particle and moisture respectively.

• Journal of Adhesion and Interface
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• v.21 no.3
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• pp.81-85
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• 2020

Shaving dust is a collagen fiber that is the leather waste occurred for thickness adjustment during the natural leather manufacturing process, and causes problems such as an environmental contamination because of a chromium (Cr) contained when it comes to reclaiming process. Various studies applying the shaving dust are currently being conducted in many countries across the world with an initiative by the EU. Of those applications, the bonded leather is being highlighted as a substitute for natural leather. Since the bonded leather, however, uses latex as a binder, accordingly it entails a high weight and a poor ventilation, which are deemed as disadvantages due to its dense internal tissues compared to other synthetic leathers. To address such disadvantages, this study employed the thermally expandable micro sphere to improve its air permeability and light weight by alleviating the internal structure. This is a study on the manufacturing of light bonded leather using the shaving dusts. In the study, the shaving dusts were forced to foam under 100~120℃ considering the heat resistance of collagen fiber after applying the thermally expandable micro sphere, and then the tendency was analyzed. In the analysis results, the most excellent foaming rate was exhibited when the shaving dusts were treated under 120℃ for 8 minutes and the variation of internal structure according to a foaming was observed through SEM analysis for the cross-section of the bonded leather.

• Journal of Energy Engineering
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• v.25 no.4
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• pp.13-29
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• 2016

In this study, we analyzed the causes of major faults in the biogas plant through the case of gas engine failure when cogenerating electricity and heat using biogas as a fuel in the actual sewage treatment plant and suggested countermeasures. Hydrogen sulfide in the biogas entering the biogas engine and water caused by intermittent malfunction of the water removal system caused intercooler corrosion in the biogas engine. In addition, the siloxane in the biogas forms a silicate compound with silicon dioxide, which causes scratches and wear of the piston surface and the inner wall of the cylinder liner. The substances attached to the combustion chamber and the exhaust system were analyzed to be combined with hydrogen sulfide and other impurities. It is believed that hydrogen sulfide was supplied to the desulfurization plant for a long period of time because of the high content of hydrogen sulfide (more than 50ppm) in the biogas and the hydrogen sulfide was introduced into the engine due to the decrease of the removal efficiency due to the breakthrough point of the activated carbon in the desulfurization plant. In addition, the hydrogen sulfide degrades the function of the activated carbon for siloxane removal of the adsorption column, which is considered to be caused by the introduction of unremoved siloxane waste into the engine, resulting in various types of engine failure. Therefore, hydrogen sulfide, siloxane, and water can be regarded as the main causes of the failure of the biogas engine. Among them, hydrogen sulfide reacts with other materials causing failure and can be regarded as a substance having a great influence on the pretreatment process. As a result, optimization of $H_2S$ removal method seems to be an essential measure for stable operation of the biogas engine.

• Journal of the Korea Institute of Building Construction
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• v.17 no.5
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• pp.411-418
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• 2017

This study classified oyster shells that produced as a industrial waste into 3 distribution by washing, drying and processing them. Mortar specimens with a constant ratio by using this to substitute fine aggregates were made, and the specimens were heated under the heating conditions of $300^{\circ}C$, $600^{\circ}C$ and $900^{\circ}C$ based on the 28-day age. On the age of 28 days, the plain flexural strength was found to be 9.2MPa, and in O 0.15, it was shown to be 4.4~7.9MPa depending on the substitution rate. It was found to be 4.4~7.7MPa in O 1.2~2.5 depending on the substitution rate, and last but not least, it was shown to be 6.1~8.8MPa in case of O 2.5~5.0 depending on the substitution rate. In case of the compressive strength of the 28-day age, it showed the difference of 23.6~43.2MPa in O 0.15 depending on the substitution rate, and 20.4~45.1MPa in O 1.2~2.5 depending on the substitution rate, and last but not least, 17.1~40.4MPa in case of O 2.5~5.0. As a result of measuring the residual strength through heating, in case of substituting fine aggregates less than O 0.15 by 100%, it showed the lowest strength reduction ratio, and it is expected that the heat-resisting property could be achieved through processing and proper mixing of oyster shells through these results.

• Korean Chemical Engineering Research
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• v.47 no.3
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• pp.303-309
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• 2009

The effects of zeolite type catalysts addition on the thermal decomposition of low density polyethylene(LDPE) and ethylene vinyl acetate(EVA) resin have been studied in a thermal analyzer(TGA, DSC) and a small batch reactor. The zeolite type catalysts tested were natural zeolite, FCC catalyst, used FCC catalyst, and catalyst A. As the results of TGA experiments, addition of antifogging-agent decreased the pyrolysis point to $250^{\circ}C$, but addition of longevity-agent and clay reduced the pyrolysis rate in EVA resin. Addition of the zeolite type catalysts in the LDPE resin increased the pyrolysis rate in the order of catalyst A > used FCC catalyst > natural zeolite > LDPE resin. Addition of the zeolite type catalysts in the EVA resin increased the pyrolysis rate in the order of used FCC catalyst > natural zeolite > catalyst A > EVA resin. In the DSC experiments for LDPE resin, addition of zeolite type catalysts decreased the melting point and the heat of pyrolysis reaction in the order of catalyst A > used FCC catalyst > natural zeolite> LDPE resin. In the batch system experiments, the mixing of natural zeolite enhanced the yield of liquid fuel oil.

• Korean Chemical Engineering Research
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• v.51 no.6
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• pp.700-708
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• 2013

Pyroprocessing has been developed for the purpose of resolving the current spent nuclear fuel management issue and enhancing the recycle of valuable resources. Pyroprocessing has been developed with the dry technologies which are performed under high temperature conditions excluding any aqueous processes. Pyro-processes which are based on the electrochemical principles require pretreatment processes and a voloxidation process is considered as a pretreatment step for an electrolytic reduction process. Various kinds of gas conditions are applicable to the voloxidation process and the understanding of Cs behavior during the process is of importance for the analyses of waste characteristics and heat load on the overall pyroprocessing. In this study, the changes of chemical compounds with the gas conditions were calculated by analyzing gas-solid reaction behavior based on the chemical equilibria on a Cs-Te-O system. $Cs_2TeO_3$ and $Cs_2TeO_4$ were selected after a Tpp diagram analysis and it was confirmed that they are relatively stable under oxidizing atmospheres while it was shown that Cs and Te would be removed by volatilization under reducing atmosphere at a high temperature. This work provided basic data for predicting Cs behavior during the voloxidation process at which compounds are chemically distributed as the first stage in the pyroprocessing and it is expected that the results would be used for setting up material balances and related purposes.