• Title/Summary/Keyword: Waste solution

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Preparation of High Purity ZnO Powder from zinc-bearing waste by the Hydrometallurgical Process (함아연 폐기물로부터 습식법에 의한 고순도 ZnO 분말의 제조)

  • 이재천;이강인;유효신
    • Resources Recycling
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    • v.1 no.1
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    • pp.58-68
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    • 1992
  • A process development for direct synthesis of high pure ZnO powders from zinc-bearing waste was investigated. This waste contains a 55% of zinc and it was extracted by the sulfuric acid(leaching). After removal of iron ion by precipitation from the zinc solution, the purification through a solvent extraction by the use of D2EHPA as an extractant was carried out. Then, loaded zinc in organic solution was stripped and precipitated simultaneously using a precipitant such as oxalic acid. Then, loaded zinc in organic solution was stripped and precipitated simulataneously using a precipitant such as oxalic acid. The synthesized $ZnC_2O_4$ powders by the precipitation stripping method was calcined to obtain more than 99.9% of ZnO powders. The effect of sulfuric acid concentration, leaching time, pulp density on the extraction of zinc was studied and the optimum conditions for the solvent extraction were obtained through the investigation of purification of zinc solution. The size, morphology and size distribution of synthesized $ZnC_2O_4$ powders were studied in terms of oxalic acid concentration, temperature, surfactant added, precipitation time, etc.

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A basic study on the defiberation of waste newspaper (폐지의 해섬에 관한 연구)

  • 윤태환;김형석;조동성
    • Resources Recycling
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    • v.4 no.1
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    • pp.31-37
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    • 1995
  • This study was to investigate the effects oi agitation speed, pulp concentration, ion concentration ill the slurry solution, printed area of the waste newspaper, immerwng time and the temperature on the defiberation process for the waste newspaper. The defikration efficiency at 50% is twice that of 16%. The efficiency is improved as two times according to elevate the agtation speed as two times in the range of 200-2WO r.p.m.. Defiberation with NaOH 1X10-'M solution has higher efficiency than that of NaOH 1 x 1 0 - M solution as 3 times at the conditions of 16%, 1200 r.p.m, and 1% pulp concentration The temperature of immersing salut~on aifects on the efficiency more than immersing time does. Increasing the printed area of newspaper decreases the velocity of defiberation. The alkaline solution is effective to defiberate and the defiberation efficiency at the same dosage of alkalinity is in the order a1 NaOH) KOH) Na,SiO, ) Na,CO, ) Ca(OH)2.

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One-pot synthesis of silica-gel-based adsorbent with Schiff base group for the recovery of palladium ions from simulated high-level liquid waste

  • Wu, Hao;Kim, Seong-Yun;Ito, Tatsuya;Miwa, Misako;Matsuyama, Shigeo
    • Nuclear Engineering and Technology
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    • v.54 no.10
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    • pp.3641-3649
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    • 2022
  • A simple solvothermal reaction was used to prepare a 3-aminopropyl-functionalized silica-gel-based adsorbent for adsorbing Pd(II) from the nitric acid solution. Scanning electron microscopy, fourier transform infrared spectroscopy, and thermogravimetry analysis were performed on the as-synthesized adsorbent to demonstrate the successful introduction of Schiff base groups. Batch experiments were used to investigate the effects of contact time, nitric acid concentration, solution temperature, and adsorption capacity. It is worth noting that the prepared adsorbent exhibited a higher affinity toward Pd(II) with the uptake approximately 100% even in a 2 M HNO3 solution. At an equilibrium time of 5 h, the maximum adsorption capacity of Pd(II) was estimated to be 0.452 mmol/g. The adsorbed Pd(II) could be completely eluted by dissolving 0.2 M thiourea solution in 0.1 M HNO3. Using a combination of particle-induced X-ray emission analysis and an X-ray photoelectron spectrometer, the adsorbed Pd was found to be uniformly distributed on the surface of the prepared adsorbent and the existing species were Pd(II) and zero-valent Pd(0). Due to the desirable performances, facile preparation method, and abundant raw material source, the prepared adsorbent demonstrated a high application potential in the recovery of Pd(II) from simulated high-level liquid waste treatment.

Manufacture of Nano-Sized Ni-ferrite Powder from Waste Solution by Spray Pyrolysis Process (분무열분해 공정에 의한 폐액으로부터 니켈 페라이트 나노 분말 제조)

  • Yu Jae-Keun;Suh Sang-Kee;Kang Seong-Gu;Kim Jwa-Yeon;Park Si-Hyun;Park Yaung-Soo;Choi Jae-Ha;Sohn Jin-Gun
    • Resources Recycling
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    • v.12 no.4
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    • pp.20-29
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    • 2003
  • In order to efficiently recycle the waste solution resulting from shadow mask processing, nano-sized Ni-ferrite powder was fab-ricated through spray pyrolysis process. The average particle size of the powder was below 100nm. In this study, the effects of the reaction temperature. the concentration of raw material solution and the injection speed of solution on the properties of powder were respectively investigated. As the reaction temperature increased from $800^{\circ}C$ to $1100^{\circ}C$, average particle size of the powder significantly Increased and power structure became more solid, whereat its specific surface area was greatly reduced. Formation rate and crystallization of($NiFe_2$$O_4$) phale increased along with the temperature rise. As the concentrations of iron and nickel components in wastere solution increased, particle size of the powder became larger, particle size distribution became more irregular, and specific surface area was reduced. Formation rate and crystallization of $NiFe_2$$O_4$ phase increased significantly along with the increase of the concentration of solution. As the inlet speed of solution increased, particle size of the powder became larger, particle size distribution became wider, specific surface area was reduced and powder structure became less solid. As the inlet speed of solution decreased, formation rate and crystallization of $NiFe_2$$O_4$ phase significantly increased.

Engineering characteristics of dune sand-fine marble waste mixtures

  • Qureshi, Mohsin U.;Mahmood, Zafar;Farooq, Qazi U.;Qureshi, Qadir B.I.L.;Al-Handasi, Hajar;Chang, Ilhan
    • Geomechanics and Engineering
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    • v.28 no.6
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    • pp.547-557
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    • 2022
  • Dune sands are poorly graded collapsible soils lacking fines. This experimental study explored the technical feasibility of sustainable invigoration of fine waste materials to improve the geotechnical properties of dune sand. The fine waste considered in this study is fine marble waste. The fine waste powder was mixed with dune sand at different contents (5, 10,15, 20, 25, 50%), where the gradation, void ratio, compaction, and shear strength characteristics were assessed for each fine marble waste -dune sand blend. The geotechnical properties of the dune sand-fine marble waste mix delineated in this study reveal the enhancement in compaction and gradation characteristics of dune sand. According to the results, the binary mixture of dune sand with 20% of fine marble waste gives the highest maximum dry density and results in shear strength improvement. In addition, a numerical study is conducted for the practical application of the binary mix in the field and tested for an isolated shallow foundation. The elemental analysis of the fine marble waste confirms that the material is non-contaminated and can be employed for engineering applications. Furthermore, the numerical study elucidated that the shallow surface replacement of the site with the dune sand mixed with 20% fine marble waste gives optimal performance in terms of stress generation and settlement behavior of an isolated footing. For a sustainable mechanical performance of the fine marble waste mixed sand, an optimum dose of 20% fine marble waste is recommended, and some correlations are proposed. Thus, for improving dune sand's geotechnical characteristics, the addition of fine marble waste to the dune sand is an environment-friendly solution.

The Study of Area-division Strategy for Medical Waste Disposal (의료폐기물 처리의 권역화 방안 연구)

  • Ahn, Sae-Hee;Ahn, Sang-Yoon
    • Journal of Digital Convergence
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    • v.12 no.9
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    • pp.255-263
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    • 2014
  • It is different from other countries, they limit the possibility of long-distance travel of infectious waste by principles around treatment and recommend to use various techniques. Medical waste generated from the health medical institutions requires more thorough management because it causes potential danger to anybody exposed and also greatly harmful to natural ecosystems. The amendment bill of Wastes Control Act points out growing risk while consigning to remote waste treatment facilities because of the low processing cost and propose area-division as a solution. This study based on literature reviews, comparison of foreign countries and Korean acts. It requires area-division strategies as a suitable alternative considering the domestic situation.

A Study on the Development of Waste-Water Maintenance Management System Using GIS (GIS를 활용한 하수도 유지관리시스템 개발에 관한 연구)

  • Kim, Ki-Woo;Cho, Sung-Eon
    • Proceedings of the Korea Information Processing Society Conference
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    • 2001.10a
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    • pp.11-14
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    • 2001
  • This paper is studied on waste water maintenance management system for Integrated computing environment. This computing environment consist of Waste-Water Maintenance Management and GIS(Geographic Information System). This system can be developed by constructing Database which is set of rules occurring while management work of waste water system is processed. This system will help person who has responsible for making decision. Objective of such computing environment is providing efficient working environment for waste water facility management. Especially we analyzed problems of existing waste water maintenance management. We carried out efficient management of water facility and it will provide solution for major decision making work with low cost using Waste-Water Maintenance Management System

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Waste Classification by Fine-Tuning Pre-trained CNN and GAN

  • Alsabei, Amani;Alsayed, Ashwaq;Alzahrani, Manar;Al-Shareef, Sarah
    • International Journal of Computer Science & Network Security
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    • v.21 no.8
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    • pp.65-70
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    • 2021
  • Waste accumulation is becoming a significant challenge in most urban areas and if it continues unchecked, is poised to have severe repercussions on our environment and health. The massive industrialisation in our cities has been followed by a commensurate waste creation that has become a bottleneck for even waste management systems. While recycling is a viable solution for waste management, it can be daunting to classify waste material for recycling accurately. In this study, transfer learning models were proposed to automatically classify wastes based on six materials (cardboard, glass, metal, paper, plastic, and trash). The tested pre-trained models were ResNet50, VGG16, InceptionV3, and Xception. Data augmentation was done using a Generative Adversarial Network (GAN) with various image generation percentages. It was found that models based on Xception and VGG16 were more robust. In contrast, models based on ResNet50 and InceptionV3 were sensitive to the added machine-generated images as the accuracy degrades significantly compared to training with no artificial data.

Packing placement method using hybrid genetic algorithm for segments of waste components in nuclear reactor decommissioning

  • Kim, Hyong Chol;Han, Sam Hee;Lee, Young Jin;Kim, Dai Il
    • Nuclear Engineering and Technology
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    • v.54 no.9
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    • pp.3242-3249
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    • 2022
  • As Kori unit 1 is undergoing the decommissioning process, estimating the disposal amount of waste from the decommissioned nuclear reactor has become one of the challenging issues. Since the waste disposal amount estimation depends on the packing of the waste, it is highly desirable to optimize the waste packing plan. In this study, we developed an efficient scheme for packing waste component segments. The scheme consists of 1) preparing three-dimensional models of segments, 2) orienting each segment in such a way to minimize the bounding box volume, and 3) applying hybrid genetic algorithm to pack the segments in the disposal containers. When the packing solution converges in the algorithm, it comes up with the number of containers used and the placement of segments in each container. The scheme was applied to Kori-1 reactor pressure vessel. The required number of containers calculated by the developed scheme was 24 compared to 42 that was the estimation of the prior packing plan, resulting in disposal volume savings by more than 40%. The developed method is flexible for applications to various packing problems with waste segments from different cutting options and different sizes of containers.

Alternative Method for the Treatment of Chemical Wastes Containing Uranium (우라늄함유 화학폐수의 적정처리 기술)

  • Kim Kil-Jeong;Shon Jong-Sik;Hong Kwon-Pyo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.4 no.2
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    • pp.179-186
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    • 2006
  • Chemical wastes are generated from nuclear facilities and R&D laboratories, but the uranium concentration in the final dried cake is evaluated into 11.2 Bq/g, which exceeds the exemption level of 10 Bq/g for each U isotopes, so the cake is categorized into a radioactive waste. Acid dissolution was applied to extract uranium from the waste sludge, and uranium adsorption on the dissolved solution was experimented by using IRN-77 and Diphosil bead. A large amount of resin was required to get above 80% of uranium removal, which was found to be due to a large amount of metal ions simultaneously dissolved from the precipitates with uranium. As an alternative method, acid dissolution is applied to the dewatered wet cake of the sludge, and the natural evaporation method is adopted for the dissolved solution. The uranium concentration of the dissolved solution was estimated to be 6.97E-01 Bq/ml, and the specific activity of the final waste sheets is evaluated to be 4.3 Bq/g. These results lead to the suggestion that the application of acid dissolution to the wet cake and the natural evaporation for the dissolved solution is an effective treatment method for chemical wastes containing uranium.

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