• Korean Journal of Materials Research
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• v.26 no.12
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• pp.681-687
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• 2016

Zirconium(Zr) nuclear fuel cladding tubes are made using a three-time pilgering and annealing process. In order to remove the oxidized layer and impurities on the surface of the tube, a pickling process is required. Zr is dissolved in HF and $HNO_3$ mixed acid during the process and pickling waste acid, including dissolved Zr, is totally discarded after being neutralized. In this study, the waste acid was recycled by adding $BaF_2$, which reacted with the Zr ion involved in the waste acid; $Ba_2ZrF_8$ was subsequently precipitated due to its low solubility in water. It is very difficult to extract zirconium from the as-recovered $Ba_2ZrF_8$ because its melting temperature is $1031^{\circ}C$. Hence, we tried to recover Zr using an electrowinning process with a low temperature molten salt compound that was fabricated by adding $ZrF_4$ to $Ba_2ZrF_8$ to decrease the melting point. Change of the Zr redox potential was observed using cyclic voltammetry; the voltage change of the cell was observed by polarization and chronopotentiometry. The structure of the electrodeposited Zr was analyzed and the electrodeposition characteristics were also evaluated.

• Resources Recycling
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• v.7 no.1
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• pp.27-33
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• 1998

A study on thc recovcry oi nickel from waste pickling solutions removed li-ee nil~ica cid and hydmflnoric acid is carried out with pulsed column extractor for thc industrial application. The ~esults show that thc Iron and chromium arc efteclively elunmatcd from the waste solution by precipitalion as the form of hydraxidc with thc adjustment of pH with CaCO;, whlle the nickel is not prcc~pitatcd. Thc cxlraction eficicncy ol nickel with column cxtraclor generally improves 8s the pulse velosity (product of amplmde and frequency) incrcascs, optimum pcrfarmancc typically occuring slightly below an amplihldefrecluency product which results in flooding the column because of excessive emulsiIicalian And the nickel loaded in the organic is erfeclively conce~~trtratebdy ZM H2S0,, ~ I It he stlipping stage. The solubility of NiSO, in the H,SO, solution dccreaaes w~th thc higher H,SO, concentralion and appears to be 55 grL in the 2M HSO* solulian.

• Nuclear Engineering and Technology
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• v.42 no.1
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• pp.17-36
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• 2010

In this study, we compare the mass release rates of radionuclides(1) from waste forms arising from the KIEP-21 pyroprocessing system with (2) those from the directly-disposed pressurized-water reactor spent fuel, to investigate the potential radiological and environmental impacts. In both cases, most actinides and their daughters have been observed to remain in the vicinity of waste packages as precipitates because of their low solubility. The effects of the waste-form alteration rate on the release of radionuclides from the engineered-barrier boundary have been found to be significant, especially for congruently released radionuclides. the total mass release rate of radionuclides from direct disposal concept is similar to those from the pyroprocessing disposal concept. While the mass release rates for most radionuclides would decrease to negligible levels due to radioactive decay while in the engineered barriers and the surrounding host rock in both cases even without assuming any dilution or dispersal mechanisms during their transport, significant mass release rates for three fission-product radionuclides, $^{129}I$, $^{79}Se$, and $^{36}Cl$, are observed at the 1,000-m location in the host rock. For these three radionuclides, we need to account for dilution/dispersal in the geosphere and the biosphere to confirm finally that the repository would achieve sufficient level of radiological safety. This can be done only after we have known where the repository site would by sited. the footprint of repository for the KIEP-21 system is about one tenth of those for the direct disposal.

• Journal of Korean Society on Water Environment
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• v.35 no.4
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• pp.299-307
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• 2019

The purpose of this study was to investigate the effect of low temperature thermal pre-treatment on biodegradation of waste activated sludge for anaerobic digestion as a countermeasure for increasing sludge generation. The experimental condition was accomplished in 2 %, 4 %, and 6 % TS concentration, and $70^{\circ}C$, $80^{\circ}C$, $90^{\circ}C$ of temperature for a maximum of 120 minutes retention time. Then, it was followed by analysis of physical/chemical properties, BMP test and composition of biogas. The biogas characteristic was evaluated by applying the modified Gomperz model. As a result, solubility of dissolved substrate, such as $SCOD_{Cr}$, soluble carbohydrate, and soluble protein, and biogas production increased as temperature increased. Solubilization efficiency at $90^{\circ}C$ was 18.4 %, 17.03 % and 16.88% in 2 %, 4 %, and 6 % TS concentration respectively. Also, solubilization rates of carbohydrate and protein similarly increased. BMP test results also showed that methane production in excess sludge increased to 0.194, 0.187 and $0.182m^3/kg$ VS. respectively, and lag phase decreased to 0.145, 0.220, 0.351 day due to acceleration of the hydrolysis step. Consequently, low-temperature thermal pre-treatment could increase biodegradability of sludge, positively affecting biogas production and sludge reduction.

• New & Renewable Energy
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• v.19 no.4
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• pp.35-45
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• 2023

Global efforts are focused on achieving carbon neutrality due to the increases in the levels of greenhouse gases. Moreover, the greenhouse gases generated from the disposal of municipal solid waste (MSW) are the primary sources of emissions in South Korea. In this study, we conducted the biological conversion of syngas (CO, H₂, and CO₂) generated from MSW gasification. The MSW-derived syngas was used as a feed source for cultivating Eubacterium limosum KIST612, and pressurization was employed to enhance gas solubility in culture broth. However, the pH of the medium decreased owing to the pressurization because of the CO₂ in the syngas and the cultivation-associated organic acid production. The replacement of conventional HEPES buffer with a phosphate buffer led to an approximately 2.5-fold increase in acetic acid concentration. Furthermore, compared with the control group, the pressurized reactor exhibited a maximum 8.28-fold increase in the CO consumption rate and a 3.8-fold increase in the H2 consumption rate.

• Nuclear Engineering and Technology
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• v.56 no.3
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• pp.824-831
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• 2024

In order to investigate the occurring processes during long-term dry storage of spent fuel assemblies, a joined project called SPIZWURZ, between the Karlsruhe Institute of Technology and the Gesellschaft für Anlagen-und Reaktorsicherheit (GRS), was started. Aim of the SPIZWURZ project is the determination and quantification of the influence of texture and elastic strain on diffusion and solubility of hydrogen in three different zirconium alloys used in western Europe during a long-term cooling transient (1 K/d) starting at 400 ℃. The strain in the cladding of an irradiated spent fuel rod shall be measured. Models predicting the formation of radial oriented hydrides will be validated, improved, and implemented in the GRS fuel rod performance code TESPA-ROD. This paper describes the SPIZWURZ project and already obtained first results.

• Journal of the Korean Ceramic Society
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• v.35 no.12
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• pp.1286-1293
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• 1998

${SO_4}^{2-}$ ions present in industrial waste water if combined with other metal ions in the water can cause serious scale problem in a transporting pipe. In this study therefore ${SO_4}^{2-}$ ions in an acidic solution have been removed by using surface active glasses. Glasses with various compositions of $SiO_2-Na_2O-B_2O_3-RO$ (R=Mg, Ca, Sr, Ba) system were reacted in a ${SO_4}^{2-}$ ion-containing solution with various pHs ranging from 1 to 4 for various time the reacted glass surfaces were analyzed by XRD and SEM and all ions in the reacted solution were also measured ${SO_4}^{2-}$ ions in the solution were combined with divalent ions leached out of glass and precipitated on the glass surface as sulfate crystals. In this was the surface ion could be removed from the acidic solution. The sulfate ion removal capacity is closely related to the solubility product con-stants of the newly formed sulfate crystals. Almost no sulfate crystal was formed on the MgO-containing glass while sulfate crystals were easily formed on the glass containing either SrO or BaO This indicates that those glasses have strong removal efficiency of ${SO_4}^{2-}$ ions from the solution.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.8 no.1
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• pp.57-63
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• 2010

Layer crystallization process was tested for the separation(or concentration) of cesium and strontium fission products in a LiCl waste salt generated from an electrolytic reduction process of a spent oxide fuel. In a crystallization process, impurities (CsCl and $SrCl_2$) are concentrated in a small fraction of the LiCl salt by the solubility difference between the melt phase and the crystal phase. Based on the phase diagram of LiCl-CsCl-$SrCl_2$ system, the separation possibility by using crystallization was determined and the molten salt temperature profile during layer crystallization operation was predicted by using mathematical calculation. In the layer crystallization process, the crystal growth rate strongly affects the crystal structure and therefore the separation efficiency. In the conditions of about 20-25 l/min cooling air flow rate and less than 0.2g/min/$cm^2$ crystal flux, the separation efficiency of both CsCl and $SrCl_2$ showed about 90% by the layer crystallization process, assuming a LiCl salt reuse rate of 90wt%.

• Journal of the Korea Organic Resources Recycling Association
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• v.6 no.1
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• pp.1-12
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• 1998

To examine the possibility of protein recycling of shaving scraps containing chromium generated from manufacturing process of leather, the optimum hydrolysis conditions and the withdrawal methods of low molecular weight protein for using the liquid fertilizer sources by investigation of solubilities of hydrolyzed protein, inorganic nutrients contents and molecular weight distributions of hydrolyzed protein from shaving scraps treated with mixed alkaline inducing agents and mixed alkaline proteolytic enzymes including MgO were investigated. In hydrolysis of shaving scraps treated with mixed alkaline inducing agents, the solubility of shaving scraps were clearly different with 65~85% according to the sorts of the inducing agents, and the degree of hydrolysis was high in the order of NaOH, $Ca(OH)_2$ and KOH. The average molecular weights of withdrawal hydrolyzed protein were 10, 40 and 80 KD treated with NaOH, $Ca(OH)_2$ and KOH, respectively. And the chromium contents was about 15 ppm. In hydrolysis of shaving scraps treated with mixed alkaline proteolytic enzymes, the bility of shaving scraps were high in the order of alcalase, esperase and savinase. In c of treating 0.5% alcalase, the low molecular weight of hydrolyzed protein could be withdrawn. The solubility of the hydrolyzed protein was about 85%, the average molecular weight of the protein was below 1 KD and chrome content of the protein was below 10 ppm.

• Journal of the Korean Applied Science and Technology
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• v.34 no.2
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• pp.210-216
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• 2017

Recovery of low level nitric acid and sulfuric acid ions, which were contained in wastewater of a wet scrubber for de-NOx and de-SOx from ship engines, was attempted as fertilizing materials. This study utilized a selective extraction method using four organic solvents to precipitate the solid salts of ammonium nitrate and ammonium sulfate. The IR analysis showed almost same composition of the extracted ammonium salts with a commercial product, and recovery rate of nitrogen and sulfuric ions was 89% and 80% respectively. It was found that the selectivity and solubility consequently could be the crucial factors to recover the low level ions from the waste scrubbing water.