• 대한전자공학회:학술대회논문집
• /
• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
• /
• pp.448-452
• /
• 2001

An Experimental study was carried out to develop a simple method of processing copper waste sludge which is produced by PBC manufacturing. The procedure is based on leaching of wet sludge in 2N H$_2$SO$_4$, and the solid / liquid ratio is controlled approximately at 1/10. The recovery of copper is 85.4%, and pH of the leachate is 3.20. Adding ammonia solution into leachate forms ammine, and hydroxide compounds derived from other impurities in leachate at pH 10. The hydroxide compound can be treated by ferrite process, and the product is a stable oxide compound. Then the ammine solution is heated to evaporate ammonia, and the copper hydroxide is formed. Heating at 8$0^{\circ}C$by aeration, copper hydroxide is transformed into copper oxide with a purity of 98.4%. This process can recover most copper from sludge and the residue can be stabilized by the formation of a stable oxide compound which is not hazardous to environment.

• 한국환경보건학회지
• /
• 제26권3호
• /
• pp.11-17
• /
• 2000

There are among the most relevant toxic emissions from incinerators such as polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), dioxin-like polychlorinated biphenyls (PCBs). Induction of cytochrome P4501A1 catalyzed 7-ethoxyresorufin O-deethylase(EROD) activity in mammalian cell culture(EROD bioassay) is thought to be a selective and sensitive parameter used for the quantification of dioxin-like components. In this study, the toxic emissions from several school waste incinerators were evaluated by determination of CYPIA catalytic activity and cytotoxicity using cell culture microbioassay. The incinerator residue and soil samples were collected from the schools located in Kyunggi province from April to June 1999. The samples were extracted in a Soxhlet apparatus using toluene for 20 hours. In order to clean-up, concentrated crude extracts were applied to basic alumina column. The EROD activities of extracts in the H4IIE cells were from 1.91$\pm$0.32 ng-TEQ/g to 24.54$\pm$3.48 ng-TEQ/g of biochemical-TEQ value. In soil samples, CYP1A catalytic activity was 0.09~0.64 ng-TEQ/g. EROD bioassay, seems to be a useful short-term bioassay when information about the biological response of complex environmental samples is needed. Although further study is needed, these results indicate that the potent toxic emissions are produced from school waste semi-incinerators.

• 대한전자공학회:학술대회논문집
• /
• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
• /
• pp.183-187
• /
• 2001

Present states on reutilization of metal-bearing solid wastes in China including metal-containing gangue, red mud, nonferrous metallurgical slag or residue, arsenical slag, steel - iron slag, waste batteries, were described in detail. The wastes pile up at a large quantity, resulting in seriously potential harm to environment. Most of these wastes, however, contain valuable metals, which are regarded as important secondary resources for extracting metals. Waste slag and batteries with a high grade of metals are treated by a hydro-based and / or pyre-based method for extracting valuable metals. While gangue and waste slag with a low grade are as a raw material in architecture field. In the future, a novel technology, such as high-grads magnetization separation technique and biological technique, will be designed to treat these wastes for protecting environment and recycling valuable components. These wastes, furthermore, are synthetically reutilized to produce various architectural materials, including glass and ceramics.

• Korean Chemical Engineering Research
• /
• 제47권2호
• /
• pp.230-236
• /
• 2009

국내 하수슬러지는 2012년부터 런던협약에 의해 해양투기가 금지될 예정에 있어 이에 대한 처리방법이 절실한 실정이다. 본 연구에서는 하수슬러지 케익을 재활용하기 위한 방법으로 탄화공정을 이용하여 탄화물 제조 및 에너지 특성에 대한 검토를 실시하였다. 하수슬러지 케익의 기초적 특성과 조성에 의하면, 하수슬러지 케익에는 27%의 인산염이 포함되어 있으며 이는 환원제로서 유해물질 처리에 이용될 수 있다. 하수슬러지 케익의 발열량을 파악한 결과, 저위발열량은 38.7 kcal/kg으로 하수슬러지 케익을 탄화하지 않고 직접 에너지원으로 사용하는 것은 바람직하지 않다. 하수슬러지 케익의 탄화공정에서 최적 탄화온도와 최적 탄화시간은 $250^{\circ}C$와 15분으로 설정되었다. 이 조건에서의 탄화물의 발열량은 비교적 낮아 하수슬러지 케익 탄화물 자체는 신재생 에너지원으로의 가능성은 크지 않다고 판단되나 인산염이 27% 정도가 포함되어 있어 다른 유기성 폐기물과 혼합하여 탄화하는 것이 적합하다고 판단되었다.

• 대한전자공학회:학술대회논문집
• /
• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
• /
• pp.264-269
• /
• 2001

Large amounts of orange juice are produced in Japan every yea.. Accompanied by the production of orange juice, large amount of juice residues are also generated in nearly the same amounts with juice. Although, at present, some of these residues are marketed as a feed for cattle after drying and mixing with lime, the marketing price is lower than its production cost and the difference is paid by the consumers as a part of the price of orange juice. In the present work, we developed new innovative use of orange juice residue, a biomass waste, as adsorption gel for removing toxic heavy metals such as lead. arsenic, selenium and so on as well as radioactive elements such as uranium and thorium from environments. The major components of orange juice residue are cellulose. hemicellulose and pectin, which are converted into pectic. acid, an acidic polysaccharide, by means of saponification with concentrated sodium hydroxide solution. In the previous work, we found that crosslinked pectic acid gel strongly an selectively adsorbs lead over other metals such as zinc an copper. On the other hand. it is well known that polysaccharides such as cellulose can be easily phosphorylated and that phosphorylated polysaccharides have high affinity to uranium and thorium as well as some trivalent metals such as ferric iron and aluminum. Taking account of the noticeable characteristics of these polysaccharides, 2 types of adsorption gels were prepared from orange juice residue: one is the gel which was prepared by saponificating the residue followed by crosslinking with epichlorohydrin and another is that prepared by crosslinking the residue followed by phosphorylation. The former gel exhibited excellent adsorptive separation behavior for lead away from zinc owing to high content of pectic acid while the latter gel exhibited that for uranium and thorium. Both types of adsorption gels exhibited high affinity to ferric iron, which enables selective and strong adsorption for some toxic oxo-anions of arsenic (V and III), . selenium and so on via iron loaded on these gels. These results demonstrate that biomass wastes such as orange juice residue can be effectively utilized fer the purpose of removing toxic heavy or radioactive metals existing in trace or small amounts in environments.

• 한국미생물·생명공학회지
• /
• 제2권2호
• /
• pp.83-88
• /
• 1974

1) 폐액을 여과했을 때 잔사부분엔 조단백질 33.08%, 총당 19.96%, 회분 2.06% 이었으며, 여액부분은 환원당 1.54%, 조단백진 2.48%, 회분이 0.43%이었으며 1kg/㎤에서 15분간 2차 살균한 결과 그의 pH가 3.15이었다. 2) 여액을 기본배지로 하여 flask 상에서 Saccharomyces cerevisiae YF-1 의 최적배양조건을 구한 결과 배지 100m1 당 Urea 0.428g, KH$_2$PO$_4$ 0.439g, MgSO$_4$ㆍ5$H_2O$ 0.21g을 첨가한 뒤 pH 4.0, 3$0^{\circ}C$ 에서 24~28시간 배양함이 가장 좋았다. 이때 배지 100m1당 1.38g의 건조효모균체 (35$^{\circ}C$에서 24시간 진공건조)를 얻을 수 있었다. 3) 건조효모의 조성은 조단백질 56.96%, 지방 1.30%, 탄수화물6.53%. 회분 9.62%이었다. 본 연구는 문교부 학술연구조성비로 행한 것이다.

• 한국농업기계학회:학술대회논문집
• /
• 한국농업기계학회 2000년도 THE THIRD INTERNATIONAL CONFERENCE ON AGRICULTURAL MACHINERY ENGINEERING. V.III
• /
• pp.792-802
• /
• 2000

The coagulation of Chinese cabbage juice can be accomplished by applying the combine method of the formic acid with rate of 3% and in four hours the propionic acid with rate of 1 % in the juice. The separation of coagulation into the protein paste and the brown juice completed in 6.5 hours by set up method in special storage. The protein paste can be stored safely for 30 days in anaerobic condition.

• 자원리싸이클링
• /
• 제20권2호
• /
• pp.3-15
• /
• 2011

현재 CDM사업 등록은 대부분 에너지, 화학공정, 제조공정 분야에서 이루어지고 있다. 그러나, 무기질 자원재활용을 통한 CDM사업 등록은 그렇게 많지 않은 실정이다. 본 논문에서는 국내 무기질 폐기물의 재자원화를 통한 CDM사업 등록 가능성을 알아보기 위하여 국내외 CDM사업 현황 분석 및 적용사례를 조사하였다. 조사결과 CDM사업 등록 사례는 대량으로 활용할 수 있는 산업 중의 하나인 시멘트산업의 원료 대체화 분야에서 다수의 등록이 이루어진 것으로 조사되었다. 우리나라에서의 CDM사업 적용 전망은 산업의 규모, 무기질 자원 활용 산업 및 온실가스 배출량을 분석하고 대량으로 활용할 수 있을 정도로 지속적으로 발생되는 우기질 폐가물의 현황 등을 면밀히 검토해야 할 것으로 판단된다.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2001년도 가을 학술발표회 논문집
• /
• pp.265-270
• /
• 2001

Nowadays, like any other areas we have asked that the concrete would get more and more properties to increase there performance. So, in this research we are intended to develop the Photocatalytic Concrete which is one of the High Performance Concrete with waste gas reduction and self-cleaning. The fundamental phenomena of the Photocatalytic Concrete were observed by the residue water-weight, SEM, flow and surface hardness(Pencil tester). As a result of this study, the Photocatalytic Concrete used Photocatalytic powder, OPC admixture and other materials can obtain its properties, also photocatalytic efficiency. Last of all, we are convinced of the Photocatalytic Concrete possibility and make an effort to develop its properties added a various study.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
• /
• pp.773-776
• /
• 2005

MSWI ash is the residue from waste combustion processes at temperature between $850^{\circ}C\;and\;1000^{\circ}C$. And the main components of MSWI ash are $SiO_2,\;CaO\;and\;Al_2O_3$. The aim of this study is to find a way to useful application of MSWI ash(after treatment) as a structural material and to investigates the hydraulic activity, compressive strength development, composition variation of such chemicallyi-activated MSWI ashes concrete. And it was found that early cement hydration, followed by the breakdown and dissolving of the MSWI-ashes, enhanced the formation of calcium silicate hydrates(C-S-H), The XRD and SEM-EDS results indicate that, both the hydration degree and strength development are closely connected with a curing condition and a chemically-activator. Compressive strengths with values in the 40.5MFa were obtained after curing the activated MSWI ashes with NaOH+water glass at $90^{\circ}C$.