• Title/Summary/Keyword: Waste products

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Study on the Pre-treatment for Quantitative Analysis of Mercury in Paper Packaging Materials (지류포장재에서의 수은 정량분석을 위한 전처리 방법 연구)

  • Ko, Seung-Tae;Lee, Tai-Ju;Park, Ji-Hyun;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.5
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    • pp.67-73
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    • 2010
  • Paper packaging materials are essential in protection and transportation of commercial or industrial products. Raw materials for packaging paper production are mainly obtained from various grades of waste paper. For this reason, the recycled fibers from waste paper would probably have possibility of containing heavy metals. This study was focused on the development of optimum pre-treatment method for the quantitative analysis of mercury. The optimum pre-treatment for open digestion system were obtained at the treatment conditions of acid combination with $HNO_3/HCl/H_2O_2$ or $HNO_3/H_2SO_4$ at $80^{\circ}C$. The optimum pre-treatment conditions in closed digestion system were determinated by the acid combination with $HNO_3/HCl/H_2O_2/HF$ in microwave at 320 W for 20 min. The recovery rate in open digestion system was 85~94% and in closed digestion system was indicated as about 100%. Therefore, the closed system is superior than the open system in pre-treatment method for the quantitative analysis of mercury, and the detected mercury contents in the sample of KOCC, AOCC and kraft sack paper were measured below 1 ppm.

EUTECTIC(LiCl-KCl) WASTE SALT TREATMENT BY SEQUENCIAL SEPARATION PROCESS

  • Cho, Yung-Zun;Lee, Tae-Kyo;Choi, Jung-Hun;Eun, Hee-Chul;Park, Hwan-Seo;Park, Geun-Il
    • Nuclear Engineering and Technology
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    • v.45 no.5
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    • pp.675-682
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    • 2013
  • The sequential separation process, composed of an oxygen sparging process for separating lanthanides and a zone freezing process for separating Group I and II fission products, was evaluated and tested with a surrogate eutectic waste salt generated from pyroprocessing of used metal nuclear fuel. During the oxygen sparging process, the used lanthanide chlorides (Y, Ce, Pr and Nd) were converted into their sat-insoluble precipitates, over 99.5% at $800^{\circ}C$; however, Group I (Cs) and II (Sr) chlorides were not converted but remained within the eutectic salt bed. In the next process, zone freezing, both precipitation of lanthanide precipitates and concentration of Group I/II elements were preformed. The separation efficiency of Cs and Sr increased with a decrease in the crucible moving speed, and there was little effect of crucible moving speed on the separation efficiency of Cs and Sr in the range of a 3.7 - 4.8 mm/hr. When assuming a 60% eutectic salt reuse rate, over 90% separation efficiency of Cs and Sr is possible, but when increasing the eutectic salt reuse rate to 80%, a separation efficiency of about 82 - 86 % for Cs and Sr was estimated.

Recycling of the Waste Rock and Tailings from Yangyang Iron Mine (양양철광산 선광 부산물의 순환자원화)

  • Jung, Moon Young;An, Yong Hyeon;Kim, Young Hun
    • Resources Recycling
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    • v.25 no.4
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    • pp.23-31
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    • 2016
  • It was found that there was no problem in recycling by-products (waste rock and tailings) from Yangyang iron mine themselves through matter conversion because they are not hazardous according to results of KSLT method. In case of using tailings as sub-materials of cement, it recommended the use of less than 3% tailings dosage not to exceed 0.6% of total alkali ($R_2O$) content based on standard quality of portland cement (KS L 5201). Non sintered eco-brick corresponding to class 1 quality of recycled clay brick (KS I 3013) can replace 15% of cement with tailings and 100% of general fine aggregate with waste rock from iron mine. As mentioned above, recycling the by-products (waste rock and tailings) as sub-materials of cement and non sintered eco-brick could gain both environmental and economic benefits, that is, reduction of scale and maintenance cost of tailing ponds, decrease of energy use and $CO_2$ emission.

Technical Trends in the Patents and Papers for the Recycling of Organic Residues from Waste Printed Circuit Boards (특허(特許)와 논문(論文)으로 본 폐(廢)PCB 유기계(有機界) 잔유물(殘留物) 재활용(再活用) 기술(技術) 동향(動向))

  • Lee, Dai-Soo;Shin, Sera;Cho, Young-Ju;Cho, Bong-Gyoo
    • Resources Recycling
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    • v.22 no.2
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    • pp.71-77
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    • 2013
  • Electronic products such as appliances, computers, and cellular phones have printed circuit boards (PCBs) in common and the PCBs in the waste electronic products contain valuable metals and organic resins. In Korea, recovery and recycling of the organic resins as well as the valuable metallics from the wastes are required indeed as the most of resources are being imported from abroad. In this article, the patents and papers for the recycling of organic residues from the waste PCBs were collected and analyzed. The open patents of USA (US), European Union (EP), Japan (JP), and Korea (KR) and SCI journals from 1979 to 2012 were investigated. The patents and journals were collected using key-words and filtered by the definition of the technology. The patents and journals were analyzed by the years, countries, companies, and technologies and the technical trends were discussed in this paper. It is showed sluggish relatively activity of published papers and patent applications for polymer manufacturing technology in local and abroad.

Studies on the Bituminization Process of Radioactive Liquid Waste[I]

  • Lee, Sang-Hoon;Chun, Kwan-Sik;Lim, Eung-Keuk
    • Nuclear Engineering and Technology
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    • v.7 no.3
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    • pp.213-222
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    • 1975
  • Immobilization of the second-cycle radioactive liquid wastes from a Purex process was developed with the blown asphalt (manufactured by Kukdong Shell Oil Company Ltd) to eliminate the possibility that the radioactive materials will be redispersed into the environment. Attempts to incorporate these wastes directly into the asphalt martrices without any pretreatment were not successful, as it was observed that the sulphuric acid in the waste oxidised the asphalt. Hence, the waste was treated with caustic soda and made alkaline prior to bituminization, so that it was found that this pretreatment made the waste compatible to the asphalt matrices. The pure blown asphalt samples irradiated with doses of 4.0$\times$10$^{7}$ rad showed no evidence of volume increase. The suitable temperature for incorporation of the alkaline wastes into blown asphalt was 180-20$0^{\circ}C$. The Products containing 50 wt% salts represented the following good properties viz., volume reduction (about 1.4), homogeneity, teachability etc. During the period of 131 day $s^{l37}$Cs from products containing 40wt% salts was leached at rates ranging from 2.70$\times$10-4 to 8.27$\times$10-4g/cm2_day but the rate for $^{90}$ Sr was lower by one to two orders of magnitude by distilled water. The leaching rates for $^{137}$ Cs and $^{90}$ Sr by sea water were slightly lower than by distilled water. Both of the leaching rates decreased with increasing pH.H.

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A study on the response of environmental sanitation problems in action of the volume based waste charge system (쓰레기 종량제 실시에 따른 환경위생 문제에 관한 조사)

  • 김영환;손종렬;문경환;류재근
    • Journal of environmental and Sanitary engineering
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    • v.10 no.1
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    • pp.35-44
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    • 1995
  • The study was carried out to investigate on the response of environmental sanitation problems in action of the volume based waste charge system in Seoul The responses from the 346 persons who dwelled in Seoul was stimulatively answered, this system was considered as a successful on 70.5% of total answers, but little portion(29.4 % ) of those was unknown on the mean of this system. And we knew that this system was need to the communication and education through the press media about this one. After the action of the volume based waste system, the volume of refuse discharged in a day was decreased 30 ∼40% than before. In the problems of environmental sanitation after this system, the number of sanitary insect( cockroach etc ) and rat was decreased, also the production of orders and dust caused by refuse was decreased in comparison with those before. This results were considered that the Separate Collection should be perfectly performed. In response, the regular envelope of refuse was serious problems, the improvement for this one was demanded. The kind of difficult refuse treated was waste rubbers> electric products > furniture> foodstuffs> bottles, cans> papers, pulps etc, and the next proposal for this system should be prepared. Conclusively, the volume based waste charge system should be remarkable system In terms of resources recycling as well as wastes reduction. Above all in order to conform this system the separate collection system should be systematically performed, the next improvable proposal of the detailed methods in this system should be prepared.

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Survey and Economic Analysis of Food Industry Residues for Biomass-to-energy Conversion in Merced and Stanislaus Counties, California, USA (바이오에너지로의 전환을 위한 캘리포니아 식품가공공장 오.폐수 특성 조사 및 경제성 분석)

  • Kim, Dae-Hyun
    • Journal of Biosystems Engineering
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    • v.34 no.4
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    • pp.243-253
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    • 2009
  • This research expands investigations into the biomass resource potential associated with California's food processing industry by surveying industries within a two county region in the San Joaquin Valley, California, USA. A previous survey conducted in 2005 for the Sacramento Municipal Utility District (SMUD) quantified residue and waste generation from food processors and food preparation businesses in the Sacramento region. The present survey investigates residue and waste streams from food processors located in Merced and Stanislaus Counties. Sixty food processors were identified to participate in the survey, of which 49 responded (82%) and data were acquired for 38 (63%) (6 facilities closed or moved, 8 decided not to participate). Within the two counties, total annual waste among survey respondents amounted to 24,044 dry tons of high moisture (${\geq}$60%) food residuals, 5,358 dry tons of low moisture (<60%) food residuals; and 23.7 million $m^3$ of wastewater containing 38,814 tons of biochemical oxygen demand ($BOD_5$). The total potential electric power generation from these food residues was estimated at approximately $7\;MW_e$. Total solid waste resource included in the survey response was estimated at about 10% of statewide residue generation for processors falling within the Standard Industrial Classification (SIC) System Major Group 20 (Food and Kindred Products) categories.

A Study on the Response of Environmental Sanitation Problems in Action of the Volume Based Waste Charge System. (쓰레기 종량제 실시에 따른 환경위생 문제에 관한 조사)

  • 손종렬;문경환;김영환;류재근
    • Journal of environmental and Sanitary engineering
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    • v.13 no.1
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    • pp.82-90
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    • 1998
  • The study was carried out to investigate on the response of environmental sanitation problems in action of the volume based waste charge system in Seoul. The responses from the 396 persons who dwelled in Seoul was stimulatively answered, this system was considered as a successful one 69.6% of total answers, but little portion (21.2%) of those was unknown on the mean of this system. And we knew that this system was need to the communication and education through the press media about this one. After the action of the volume based waste charge system, the volume of refuse discharged in a day was decreased 30-50% than before. In the problems of environmental sanitation after this system, the number of sanitary insect(cockroach etc) and rat was decreased, also the production of order and dust caused by refuse was decreased in comparison with those before. This results were considered that the Separate Collection should be perfectly performed. In response, the regular envelope of refuge was serious problems, the improvement for this one was demanded, The kind of difficult refuse treated was waste foodstuffs> electric products> rubbers> furniture> bottles, cans>papers, pulps etc. and the next proposal for this system should be prepared. Conclusively, the volume based waste charge system should be remarkable system in terms of resources recycling as well as wastes reduction. Above all in order to conform this system the separate collection system should be systematically performed, the next improvable proposal of the detailed methods in this system should be prepared.

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Gasification and Pyrolysis Technology for the Treatment of Plastics Waste (플라스틱 폐기물의 건류 및 열분해)

  • Ghim, Young Sung
    • Applied Chemistry for Engineering
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    • v.3 no.2
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    • pp.201-206
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    • 1992
  • Annual amount of plastics waste including rubber and leather waste, generated in 1990 was about 2,600,000 tons. Amount of generation of plastics waste has rapidly increased, but fractions of recycling and incineration have gradually decreased. Recently, two-stage incinerator, consisting of gasifier and gas combustor, draws much attention in Korea. Plastics are gasified in the starved air condition in the gasifier and produced gas is fired in the combustor. Combustion of produced gas is much easier than that of solid plastics, and produces a little pollutants. Standardzation of technology and process automation are still needed, but this incineration technology is in the commercial stage. Next topic concerned with this two-stage incineration will be how to treat complex plastics waste including toxic substances generated from automobiles and household appliances. Pyrolysis, realized by indirect heating in inert atmosphere, can provide high-quality products with minimum emissions. Many plastics are easily decomposed into oil in pyrolysis conditions, which can be utilized as chemical feedstocks, or gasoline or kerosene depending on feed materials and operating conditions. This has been demonstrated in several pilot-scale tests performed in Japan, Germany, etc. Easy removal of HCl from PVC is one of the most decisive merits of pyrolysis process. But in general, further efforts should be made for the process to obtain marketability. The future of pyrolysis process depends on public concern about environmental problems and oil prices.

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Studies on the Media Development of Pleurotus ostreatus by Waste Cotton Stuff (느타리버섯 배지개발을 위한 폐면포 이용에 관한 연구)

  • Ryu, Jeong;Lee, Gong-Joon;Jung, Gi-Tai;Na, Jong-Seong;Hwang, Chang-Ju
    • The Korean Journal of Mycology
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    • v.24 no.3 s.78
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    • pp.176-179
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    • 1996
  • Media development of Pleurotus ostreatus were analyzed to recognize the compositional differences depending on rice straw and waste cotton stuff media. Yields of add the rice bran 20% to the waste cotton stuff were increment 11% as compared with rice straw media. Crude protein of products to the waste cotton stuff media on Pleurotus ostreatus was a much and crude ash was less than of rice straw media. Glutamic acid was most and cystine was lowest among the amino acids of Pleurotus ostreatus. Total amino acids and essential amino acids of waste cotton stuff were much than of rice straw media.

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