• Journal of the Korean Crystal Growth and Crystal Technology
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• v.10 no.2
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• pp.159-165
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• 2000

This study was investigated the environment of waste shells such as oyster, cockle and paphia on southern shore in korea and established the recycling method to prevent the environmental pollution, etc. The waste shells were reclaimed at public shore illegally or leaved on the surroundings of shore. The origin mechanism, XRD and TG-DTA analyses were performed to effective recycling of waste shells, and the optimal recycling method was preparation of the calcium carbonate. In this work, calcium carbonate and lime fertilizer of granular shape were prepared using the waste shell.

• Journal of the Korean Ceramic Society
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• v.53 no.1
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• pp.1-6
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• 2016

In this year, Koreans have a shortage in agricultural and drinking water due to severe algal blooms generated in major lakes. Waste oyster shells were obtained from temporary storage near the workplace at which oysters were separated from their shells. Heating ($1000^{\circ}C$ for 1 h in air) was employed to convert raw oyster shell powders into calcium oxide powders that reacted efficiently with phosphorus and nitrogen to remove algal blooms from eutrophicated wastewater. As the dispersed amount of heated oyster shell powders was increased, water clarity and visual light penetration were improved. Coagulation, precipitation and carbonation process of the heated oyster shell powders in a water purifier facilitated removal of eutrophication nutrient such as phosphorus and nitrogen, which is both beneficial and economically viable. $CO_2$ implantation by carbonation treatment not only produced thermodynamically stable CaO in oyster shells to derive precipitated calcium carbonate (PCC) but also accelerated algal removal by activation of coagulation and precipitation process. The use of oyster shell powders led to a mean reduction of 97% in total phosphate (T-P), a mean reduction of 91% in total nitrogen (T-N) and a maximum reduction of 51% in chemical oxygen demand (COD), compared with the total pollutant load of raw algal solution. Remarkable water quality improvement of algal removal by heated oyster shell powders and PCC carbonation treatment will allow utilization as water resources to agricultural or industrial use.

• Resources Recycling
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• v.11 no.2
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• pp.45-51
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• 2002

This study was performed to investigate removal efficiency of wastewater by the prepared coagulant using waste oyster shell and loess. Waste oyster shell and loess contain respectively high CaO(55.43% by weight), $SiO_2$(45.30% by weight). Waste oyster shell was calcined to improve the purity of CaO at the calcination condition of $900^{\circ}C$ for 2hours, and then crushed 0.074 mm(200mesh) size by ball mill. Also, coagulant was prepared with calcined waste oyster shell and loess powder by hydration reaction. Calcined waste oyster shell and loess powder were combined with mixing ratio of 6 : 4, 7:3, 8:2 and 9:1. Though comparison experiment between prepared coagulant and chemical )$Ca(OH_2$, prepared coagulant was proved as having replaceable possibility of chemical )$Ca(OH_2$in wastewater treatment plant.

• Korean Journal of Environmental Agriculture
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• v.18 no.3
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• pp.209-214
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• 1999

Objective of the research is to estimate neutralization capacity and to determine practical running parameters required in packing tower design of waste oyster shells using Bohart-Adams equation. It is expected that waste oyster shells are able to be recycled for removal of heavy metals through neutralization of plating wastewater because those contain approximate 93% $CaCO_3$. By applying the results of the continuous experiment to Bohart-Adams equation, service time decreases in the order of Cr>Fe>Cu, while removal efficiencies of metals become less in the order of Fe>Cr>Cu.

• Proceedings of the Korean Geotechical Society Conference
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• 2002.10a
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• pp.681-688
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• 2002

Study was peformed to develop the‘environmental double pile’for the remediation of low-permeable contaminated soil. This technique is similar in function to‘sand drain pile’But this applies recyclable oyster shell treated as waste materials to a drain material and the pile is consisted of two layers. Inner metal pile is located in center and oyster shells are filled around it. By this technology, contaminated ground water is pumped out through the oyster shell and purified by drainage, adsorption, and reaction processes. Afterwards, the grout material is injected through the inner pile for the effect of the solidification / stabilization. As a result, the concept of this technique is a development of one-step process technology. Through the test, a consolidation characteristic by radial drain is going to be evaluated and the optimum standard of this technology will be calculated.

• Proceedings of the Korean Geotechical Society Conference
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• 2005.03a
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• pp.1390-1395
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• 2005

To analyze the effects of oyster shell particles, inserted in the self-hardening matrix such as cement paste, on strength, homogenization analysis using micro structure was used to estimate and assess the apparent elastic modulus of oyster shell particle. DIB modeling technique was used to represent of the micro structure of oyster shell mixed concrete. The results showed that the apparent elastic modulus of LOS (large oyster shell particle) was changed with the amount of LOS inserted. In particular, when the amount of LOS was 200% of the weight of cement, the apparent elastic modulus of LOS tended to decrease rapidly. This could mean that the strength of oyster shell mixed concrete is much affected by LOS inserted material in mixed ratio of 200%.

• Journal of Environmental Health Sciences
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• v.29 no.2
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• pp.45-49
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• 2003

In this study, lots of methods have been studing to utilize energy and decrease contaminated effluents. There has been great progress on IGCC (Integrated gasification combined cycle) to reduce thermal energy losses. The following results have been conducted from desulfurization experiments using waste shell to remove H$_2$S. According to TGA results, temperature had influenced on H$_2$S removal efficiency. As desulfurization temperature increased, desulfurization efficiency increased. Also, maximum desulfurization efficiency was observed at 80$0^{\circ}C$. Desulfurization was related to calcination temperature. Considering temperature ranges of exhausted gas from hot gas gasification equipment were 400~80$0^{\circ}C$. Thus, desulfurization efficiency would be increased desulfurization temperature situation at highly. Experiments by TGA showed that particle size of sorbents had influenced on desulfurization capacity. Maximum desulfurization capacity was observed at 0.631 mm for oyster and clam. Rest of sorbents showed similar capacity within 0.171~0.335 mm particle size range. So, particle size would be considered. When would be used waste shells as IGCC sorbents. According to the results about desulfurization capacity by TGA, oyster had the best desulfurization capacity among limestone and waste shell. We would be identify to substituted oyster for existing sorbents

• Applied Chemistry for Engineering
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• v.19 no.4
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• pp.439-444
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• 2008

The oyster shell adsorbents were prepared by steam activation method to evaluate their adsorption characteristics. Washed and pulverized waste oyster shells were prepared by steam activated process in converter at the temperature range of about $700{\sim}800^{\circ}C$ after carbonized at the range of $600{\sim}1000^{\circ}C$. The shell carbonized at $1000^{\circ}C$ showed the best performance among those of other temperature ranges. Also, comparison between gas and liquid phase adsorption was performed to verify adsorbent possibility of waste shell. In case of gas phase, the adsorbent showed lower performance than existing commercial adsorbents. On the other hand, the liquid phase, they showed similar adsorption performance to commercial adsorbents when benzene was used.

• Journal of the Korean Geotechnical Society
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• v.22 no.11
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• pp.143-149
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• 2006

An experimental study was carried out to investigate the stabilizing capability of oyster shell binder, which was developed using waste oyster shell inducing environmental pollutions by piling up out at the open or the temporary reclamation. The purpose of this paper is to compare stabilinzing capability of oyster shell binder and cement binder with treated soils. For this, a series of compressive laboratory tests were peformed to evaluate strength characteristics of treated soils by both oyster shell binder and cement binder with varing water content of dredged soils, different mixing rates of binder and curing days. Based on test results, eco-friendly binder manufactured by oyster shells showed more stabilizing capacity than cement binder and is estimated as good resource materials for soft soil improvements.

• Clean Technology
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• v.29 no.2
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• pp.95-101
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• 2023

An experiment was conducted to produce vaterite-type precipitated calcium carbonate from waste oyster shells in order to use them as recyclable resources. Calcined oyster shells containing calcium oxide as their main component were prepared at a temperature of 800℃ for 24 h. The oyster shells were dissolved in nitric acid or hydrochloric acid solution to make 0.1 M calcium nitrate or calcium chloride aqueous solution, and a carbonation reaction was performed using a 0.1 M sodium carbonate aqueous solution under various experimental conditions, which included varying the amount of aspatic acid additive, the amount of NH₄OH added, the reaction time, the reaction temperature, the stirring speed, and the type of dissolved acid. The XRD, SEM, and size distributions were analyzed and the vaterite content was calculated. Spherical precipitated calcium carbonate with a vaterite content of 95.9% was synthesized by adding 0.1 mol aspatic acid/1 mol CaO and 2 cm³ of NH₄OH, and reacting for 1 h at 25℃ while stirring at 600 rpm. The average particle diameter was found to be 12.11 ㎛. Calcium carbonate contatining high vaterite is used as high value added calcium carbonate for medical, food, inke additiver, etc.