• Title/Summary/Keyword: Waste oil

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Degradation Characteristics of Algae Coagulated with Poly Aluminum Chloride by Thermophilic Oxic Process (고온·호기법을 이용한 Poly Aluminum Chloride에 의해 응집된 조류의 분해특성)

  • Yang, Jae-Kyung;Choi, Kyung-Min
    • Journal of the Korea Organic Resources Recycling Association
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    • v.7 no.1
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    • pp.67-77
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    • 1999
  • The biodegradation of algae coagulated with poly aluminum chloride(PAC) was investigated by using the thermophilic oxic process. The compositions of coagulated algae were 83.5% of water content, 24.6% of ash, 32% of organic carbon with in total solid, respectively. In present study, food waste oil was used for the increment of calorie of mixtures in order to accelate the microbial activity. As a result, the maximum temperature of mixtures was higher than $50^{\circ}C$ when the mixing ratio of food oil was over 10%. However the temperature indicated the lower than $50^{\circ}C$ when conditions of no mixing with waste food oil, and 5% of mixing ratio. Therefore, the optimum condition was 10% of the mixing ration at $217l{\cdot}m^{-3}{\cdot}min^{-1}$ of air supply rate. The conversion efficiency of carbon was highest as 92% at the optimum condition. And then water was evaluated from imxture without accumulation at 10% of mixing ratio. The thermophilic oxic process well conducted that is good process for the treatment of waste algae without effluents however it has to consider the retreatment of accumulated aluminum in the reactor.

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Catalytic Pyrolysis of Waste Paper Cup Containing Coffee Residuals (커피 잔류물을 함유한 폐종이컵의 촉매 열분해)

  • Shin, Dongik;Jeong, Seokmin;Kim, Young-Min;Lee, Hyung Won;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.29 no.2
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    • pp.248-251
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    • 2018
  • Catalytic pyrolysis of the waste paper cup containing coffee residual (WPCCCR) was performed using a fixed bed reactor and pyrolyzer-gas chromatography/mass spectrometry (Py-GC/MS). Non-catalytic pyrolysis of WPCCCR produced a large amount of oil together with gas and char. The use of both HZSM-5 and HY decreased the yields of oil and increased the yield of gas due to the additional catalytic cracking. Owing to the acidic catalytic properties of HZSM-5 and HY, catalytic Py-GC/MS analysis of WPCCCR increased the selectivity to aromatic hydrocarbons in product oil. Owing to properties of HZSM-5 having a stronger acidity and medium pore size, the catalytic pyrolysis of WPCCR over HZSM-5 produced much larger amounts of aromatic hydrocarbons than that of using HY.

Production of Biodiesel from Waste Frying Oil by Transesterification on Zeolite Catalysts with Different Acidity (산성도가 다른 제올라이트 촉매에서 전이에스터화 반응에 의한 폐식용유로부터 바이오디젤 제조)

  • Koh, Tae-Suck;Chung, Kyong-Hwan
    • Applied Chemistry for Engineering
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    • v.19 no.2
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    • pp.214-221
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    • 2008
  • The production of biodiesel by transesterification of waste frying oil was conducted on various zeolite catalysts with different acidity and pore structure. $H^+$ ion exchanged MOR, MFI, FAU, and BEA zeolites were employed in the reaction with silicalite which has no strong acid sites. $H^+$ ion exchanged MOR(10) zeolite, which has more acid sites and stronger acid strength than other zeolites, exhibited the highest methyl esters yield as 95%. Dealumination to the HMOR zeolite induced decreasing of acid amount and acid strength. It brought about the decrease of fatty acid methyl esters (FAME) yield. The yield increased linearly with enhancing of acid strength and increasing of amount of strong acid sites. The yields were independent on pore structure of the zeolites.

A Study on the Oil-mist/Smoke Collecting Module for the Pure Energy Recycling (청정에너지 회수용 유증기/매연 포집모듈에 관한 연구)

  • Kim, Myung-Soo;Ohkura, Shigenobu;Ham, Koung-Chun
    • 한국태양에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.279-284
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    • 2009
  • Traditionally, so-called "industrial waste gases", such ad exhaust from boilers at industrial installations and a large quantity of soot discharged from power station, before their release into the atmosphere, have been on occasion subjected to an air cleaning process to remove fine particles that may pollute the atmosphere (such as mist and dust containing various powdery or oily substances and moisture from industrial waste gases). The release of industrial waste gases containing these particles directly into the atmosphere poses a serious threat to the earth environment; and recovery of these noxious substances is required by law in some countries and local governments. in urban areas, air pollution from automobile exhaust and others creates a serious condition. Some homes are equipped with and use indoor air purifiers. In many of the kitchens of restaurants, smoke generated during cooking and otherwise contaminated air are cleansed by air purifiers before being released outside or recycled inside. For the dust collecting devices to recover the fine particles contained in contaminated air, the cause for air pollution and how to purify air, many types based on various principles are known. Specifically, classified based on theories of particle collection, filtration, gravity, inertia, centrifugation, electricity, and cleaning types are cited as available processes. Among them, an appropriate type is selected according to the size or type of fine particles to be collected and conditions for installation. For the efficiency of dust collection, a filtration system (by using bag filters and others) and electric system are particularly outstanding and are therefore used widely in various areas of industry. In this research, rotary type high performance oil mist and smoke collecting system with self auto cleaning device equipped with the cleaning fluid spraying section is investigated.

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Autogenous Shrinkage and Fundamental Properties of the High Strength Mortar Containing Waste Vegetable Oil (폐식용유를 사용한 고강도 모르터의 자기수축 및 공학적 특성)

  • Han, Min-Cheol;Song, Ri-Fan
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.1
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    • pp.97-102
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    • 2010
  • The objective of this paper is to explore the possibility of reuse of waste vegetable oil (WO) as an autogenous shrinkage reducer for high strength concrete and to compare the amount of autogenous shrinkage of the mortar using existing shrinkage reducing agent(SR) and expansive additives(EA). According to test results, as the dosages of WO increased, flow value exhibited to decrease, while the use of SR increased flow value. For the effect of WO on strength, although the use of SR and WO resulted in a slight decrease in compressive strength at early age, at 91 days they had similar strength level of the plain mixture. For autogenous shrinkage, as expected, the addition of WO, SR and EA resulted in a decrease of autogeneous shrinkage considerably especially, WO had superiority in autogenous shrinkage reducing effect compared with the case of SR and EA.

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Effect of waste cooking oil addition on ammonia emissions during the composting of dairy cattle manure

  • Kuroda, Kazutaka;Tanaka, Akihiro;Furuhashi, Kenichi;Fukuju, Naoki
    • Animal Bioscience
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    • v.35 no.7
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    • pp.1100-1108
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    • 2022
  • Objective: The objective of this study was to evaluate the effect of waste cooking oil (WCO) addition on ammonia (NH3) emissions during the composting of dairy cattle manure under two aeration conditions. Methods: The composting tests were conducted using the laboratory-scale composting apparatuses (14 L of inner volume). Three composting treatments (Control, WCO1.5, and WCO3, with WCO added at 0 wt%, 1.5 wt%, and 3 wt% of manure, respectively) were performed in two composting tests: aeration rate during composting was changed from 0.55 to 0.45 L/min in Test 1, and fixed at 0.3 L/min in Test 2, respectively. The NH3 emitted and nitrogen losses during the composting were analyzed, and the effect of the addition of WCO on NH3 emissions were evaluated. Results: Both tests indicated that the composting mixture temperature increased while the weight and water content decreased with increasing WCO content of the composting mixtures. On the other hand, the NH3 emissions and nitrogen loss trends observed during composting in Tests 1 and 2 were different from each other. In Test 1, NH3 emissions and nitrogen losses during composting increased with increasing WCO contents of the composting samples. Conversely, in Test 2, they decreased as the WCO contents of the samples increased. Conclusion: The WCO addition showed different effect on NH3 emissions during composting under two aeration conditions: the increase in WCO addition ratio increased the emissions under the higher aeration rate in Test 1, and it decreased the emissions under the lower aeration rate in Test 2. To obtain reduction of NH3 emissions by adding WCO with the addition ratio ≤3 wt% of the manure, aeration should be considered.

Effect of Chestnut-shell Tea Waste and Castor Oil as an Additive on Fuel Characteristics of Pellets Fabricated with Pitch Pine and Mongolian Oak (첨가제로서 율피차 부산물과 피마자유가 리기다소나무 및 신갈나무 펠릿의 연료적 특성에 미치는 영향)

  • Kim, HyeonJeong;Yang, In;Han, Gyu-Seong
    • New & Renewable Energy
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    • v.18 no.2
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    • pp.1-8
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    • 2022
  • This study aimed to determine the optimal conditions for fabricating pitch pine (PCP) and Mongolian oak (MOK) pellets using chestnut-shell tea waste (CSW) and castor oil (CSO) as additives. For pellets fabricated using a pilot-scale flat-die pellet mill, all moisture content (MC) was in line with A1 wood pellet standards for residential and small-scale commercial uses designated by the National Institute of Forest Science at the Republic of Korea (NIFOS), regardless of fabricating conditions; the durability of PCP pellets prepared using PCP particles with 10% MC, and CSW addition also satisfied these criteria. The moisture tolerance of PCP pellets improved with combination of 2 wt% CSW and 2-6 wt% CSO. Overall, use of 20 mesh CSW as an additive, PCP with 10% MC, and MOK with 12% MC was found to be optimal. Moreover, using CSO as an additive, high-quality PCP and MOK pellets can be fabricated by adjusting the particles to 12% MC. However, the durability of PCP and MOK pellets prepared using these conditions did not meet the wood pellet standards for residential and small-scale commercial use. Therefore, further research is needed to improve the durability of these pellets.

A study for cyclic Process technique of mineral base engine used oil resource (Engine 폐유 자원순환 기술에 관한 연구)

  • 김주항
    • Journal of the Korean Professional Engineers Association
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    • v.18 no.2
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    • pp.6-15
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    • 1985
  • A new process disregraded the H$_2$SO$_4$ treatment process heretofore in use, was developed and substituted for mineral base engine used oil of homemade SAE-30 grade H.V.I., which was used covering 4,500km, as samples, and the following results in research, was obtained. (1) A good quality of rerefinded base oil was obtained through roughly a course of developed processes of vacuum distillation process, solvent extraction process, neutralization treatment process and clay treatment process. (2) Through vacuum distillation process, the size of fine grains of insoluble colloid carbon that is, colloid carbon which was produced by burning of internal combustion engine oil and fuel, could be brought up and precipitated (3) The insoluble matters and admixtures could be easily dispersed and dissolved by mixing and extracting solvent disregarded the H$_2$SO$_4$ treatment process heretofore in use (4) waste matter heretofore called acid sludge in consequence of the process, did not appear at all. accordingly, the environmental pollution could be removed. (5) The troubles of corrosion to copper strip which was faults of the usual used oil refined products and peculiar offensive odor of the rerefined oil, could be solved through the neutralization process. (6) The yield of rerefined oil obtained through a course of processes was over 86 percent, and it is of practical use, not to speak of commercial value.

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Performance Analysis of a Vacuum Pyrolysis System

  • Ju, Young Min;Oh, Kwang Cheol;Lee, Kang Yol;Kim, Dae Hyun
    • Journal of Biosystems Engineering
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    • v.43 no.1
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    • pp.14-20
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    • 2018
  • Purpose: The purpose of this study was to investigate the performance of a vacuum pyrolysis system, to analyze bio-oil characteristics, and to examine the applicability for farm-scale capacity. Methods: The biomass was pyrolyzed at 450, 480, and $490^{\circ}C$ on an electric heat plate in a vacuum reactor. The waste heat from the heat exchanger of the reactor was recycled to evaporate water from the bio-oil. The chemical composition of the bio-oil was analyzed by gas chromatography-mass spectrometry (GC-MS). Results: According to the analysis, the moisture content (MC) in the bio-oil was approximately 9%, the high heating value (HHV) was approximately 26 MJ/kg, and 29 compounds were identified. These 29 compounds consisted of six series of carbohydrates, 17 series of lignins, and six series of resins. Conclusions: Owing to low water content and the oxygen content, the HHV of the bio-oil produced from the vacuum reactor was higher by about 6 MJ/kg than that of the bio-oil produced from a fluidized bed reactor.

Field Test Assessment of Biological Recovering Agent for treating Oil Contaminated Soil (생물학적 유류오염토양 복원제의 현장 적용성 평가)

  • Kim, Soo-Hong;Song, Seung-Koo;Suh, Jung-Ho
    • KSBB Journal
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    • v.25 no.1
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    • pp.73-78
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    • 2010
  • In this study, recovering agent was produced with organic sludge and modified peat moss (MPM) in pilot plant mixer to recover oil contaminated soil, and field test of it was estimated using landfarming method. Oil contaminated soil recovering agent was thought to contain more microorganisms than raw waste sludge and was no problem to come onto the market because there were not any items of specified wastes. According to the results of TPH variation with time, it was observed the initial degradation velocity of oil with produced recovering agent was rapid up to 50% after 4 days, remarkably. Because the microorganisms in the organic sludge discharged from chemical plant already acclimated with oil, therefore, it could be estimated initial degradation velocity of recovering agent might be rapid. It was concluded that the oil contaminated soil recovering agent produced in this study have high marketability because of its two aspects on recycling of wastes and initial rapid degradation capacity.