• Title/Summary/Keyword: Waste liquid

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Extraction Behavior of Uranyl Ion From Nitric Acid Medium by TBP Extractant in Ionic Liquid

  • Kim, Ik-Soo;Chung, Dong-Yong;Lee, Keun-Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.4
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    • pp.457-464
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    • 2020
  • In this study, extraction of uranium(VI) from an aqueous nitric acid solution was investigated using tri-n-butyl phosphate (TBP) as an extractant in an ionic liquid, 1-alkyl-3-methylimidazolium bis (trifluoromethylsulfonyl)imide ([Cnmim][Tf2N]). The distribution ratio of U(VI) in 1.1 M TBP/[Cnmim][Tf2N] was significantly high when the concentration of nitric acid was low. The value of the distribution ratio decreased as the concentration of the nitric acid increased at lower acidities, and then increased with a nitric acid concentration of up to 8 M. This can be attributed to the different extraction mechanisms of U(VI) based on nitric acid concentrations. Thus, a cation exchange at low acidity levels and an ion-pair extraction at high acidity levels were suggested as the extraction mechanism of U(VI) in the TBP/[Cnmim][Tf2N] system.

Immobilization of sodium-salt wastes containing simulated 137Cs by volcanic ash-based ceramics with different Si/Al molar ratios

  • Sun, Xiao-Wen;Liu, Li-Ke;Chen, Song
    • Nuclear Engineering and Technology
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    • v.53 no.12
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    • pp.3952-3965
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    • 2021
  • In this study, volcanic ash was used as raw material to prepare waste forms with different silicon/aluminum (Si/Al) molar ratios to immobilize sodium-salt waste (SSW) containing simulated 137Cs. Effects of Si/Al molar ratios (3:1 and 2:1) and sodium salts on sintering behavior of waste forms and immobilization mechanism of Cs+ were investigated. Results indicated that the main mineral phase of sintered waste-form matrixes was albite, and the formation of major phases was found to depend on Si/Al molar ratios. Si/Al molar ratio of 2 was favorable for the formation of pollucite, and the formation and crystallization of mineral phases were also decided based on physicochemical characteristics of sodium salts. Furthermore, product consistency test results indicated that the immobilization of Cs+ was related to Si/Al molar ratio, types of sodium salts, and glassy phase. Waste forms with Si/Al molar ratio of 2 exhibited better ability to immobilize Cs+, whereas the influence of sodium salts and glassy phases on the immobilization of SSW showed more complicated relationship. In waste forms with Si/Al molar ratio of 2, Cs+ leaching concentrations of samples containing Na2B4O7·10H2O and NaOH were low. Na2B4O7·10H2O easily transformed into liquid phase during sintering to consequently achieve low temperature liquid-phase sintering, which is beneficial to avoid the volatilization of Cs+ at high temperature. Results clearly reveal that waste forms with Si/Al molar ratio of 2 and containing Na2B4O7·10H2O show excellent immobilization of Cs+.

A Study on the Effect of Food size and Washing rate on the Mixed Digestion of food Waste and Sewage Sludge (음식물쓰레기의 슬러지 병합처리에 있어서 입경 및 세척율의 영향)

  • 최성문;김은호;성낙창;김정권;윤태경;임영석
    • Journal of environmental and Sanitary engineering
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    • v.15 no.4
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    • pp.84-90
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    • 2000
  • 5L laboratory-scale anaerobic digester was used to study the effects of food size and washing rate of food waste on the mixed digestion with sewage sludge. Food waste was crushed with particle diameters of 4mm and 2mm and washed two to three times, and seven to eight times before feeding the batch digester. The digester with crushed of washed food waste showed better performance than that with uncrushed of unwashed to produce methane gas of reduce volatile solids. The digester with 2mm food waste showed 17.4% higher VS/TS reduction rate and 18ml higher methane production rate per gram VS input than that with uncrushed food waste, where VS and TS are volatile solid and total solids in the liquid effluent, respectively. Also food waste crushed eight times gave 8% higher VS/TS reduction rate and 11ml higher methane production rate per gram VS input than unwashed food waste.

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Solid-liquid Separation Characteristics of Membrane Filter Press according to Coagulant Properties of Anaerobic Digestion Waste Water (혐기소화폐액의 응집제 특성에 따른 멤브레인 필터프레스의 고액분리 특성)

  • Han, Seong Kuk;Jung, Hee Suk;Song, Hyoung Woon;Kim, Ho;Ahn, Dae Hyun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.22 no.3
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    • pp.23-32
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    • 2014
  • Recently, it is increase in the processing of organic waste using anaerobic digestion. Therefore, the studies on the processing method for increasing the anaerobic digestion waste water. But it is very difficult to solid-liquid separation, because the characteristics of anaerobic digestion waste water. So this study evaluate solid-liquid separation efficiency of anaerobic digestion sludge using CST(Capillary Suction Time), TTF(Time to Filter). To address this problem, a membrane filter press of the lab scale was produced and the anaerobic digestion wastewater was applied to it. Polymer coagulants were found to be most suitable 7192PLUS and 1T60, It is necessary to minimum injection concentration is 7192PLUS (200 mg/L), 1T60 (100 mg/L). To evaluate dehydration efficiency, it was measured the moisture content of the dehydrated cake and suspended solids of decanted water. As a result, showed that a high removal efficiency of 97.4% when the solid-liquid separation using the membrane filter press. And the moisture content of the dehydrated cake was less than 65%.

Treatment of Liquid Waste Containing Highly Concentrated Ethylenediaminetetraaceticacid by Using Underwater Electrical Discharge (수중 전기방전을 이용한 에틸렌디아민테트라아세트산 폐액의 처리)

  • Jo, Jin-Oh;Mok, Young-Sun;Kang, Duk-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.5
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    • pp.564-570
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    • 2007
  • This study investigated the treatment of liquid waste containing highly concentrated iron(III)-ethylenediaminetetraaceticacid (Fe(III)-EDTA) of 70,000 mg/L by an underwater electrical discharge process using low voltage and high current. When AC voltage is applied to the discharging electrode with the other electrode grounded, the temperature of the liquid waste around the discharging electrode rapidly increases, and at the same time, hydrogen and oxygen gases are formed at the electrode as a result of electrochemical reactions. Ultimately, gases formed by vaporization of water and electrochemical reactions cover the electrode. Since the liquid waste is electrically conductive, it elongates the ground electrode up to the border of the gas layer, where electrical discharge occurs. Without hydrogen peroxide, electrical discharge was able to remove about 50% of Fe(III)-EDTA. As the concentration of hydrogen peroxide added increased, the removal efficiency of Fe(III)-EDTA increased. When the molar ratio of hydrogen peroxide to the initial Fe(III)-EDTA was higher than 24.7, more than 80 g of Fe(III)-EDTA was removed with an energy of 1 kWh. A comparison between tungsten and steel electrodes showed that electrode material did not affect the Fe(III)-EDTA removal. In the present underwater electrical discharge process, the removal of Fe(III)-EDTA was completed within 30 min at molar ratios of hydrogen peroxide to the initial Fe(III)-EDTA higher than 24.7.

Evaluation of dry feeding and liquid feeding to lactating sows under high temperature environment

  • Hong, J.S.;Jin, S.S.;Jung, S.W.;Fang, L.H.;Kim, Y.Y.
    • Journal of Animal Science and Technology
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    • v.58 no.10
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    • pp.36.1-36.5
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    • 2016
  • Background: Liquid feeding system has been introduced to domestic swine farms, but negative cognition about liquid feeding system has been remained for feed waste decay related with poor management and microbial contamination. For these reasons, this study was conducted to evaluate the effects of feeding method in lactating sows. Methods: A total of 30 mixed-parity (average 4.13) lactating sows (Yorkshire ${\times}$ Landrace) with an initial BW of $218.8{\pm}19.5kg$ was used in a 3 week trial. Sows were allotted to 1 of 2 treatments in a completely randomized design by their body weight, backfat thickness, parity and alive litter weight. One of treatments was dry feeding and the other was liquid feeding (water to feed ratio, 1:1). Experimental diets contained 3265 kcal ME/kg, 12.6 % CP, 5.76 % EE, 1.09 % total lysine, 0.25 % total methionine, as fed basis. Results: Dry feeding treatment had high body weight loss rather than liquid feeding treatment (P = 0.04). Dry feeding treatment had tendency to increase litter weight at 21d of lactation (P = 0.06) and litter weight gain (P = 0.04) during lactation period (0-3 week). Sows fed dry feeding method made milk containing high content of casein and total solid rather than sows fed liquid feeding method (P = 0.04). In addition, dry feeding treatment had tendency to higher content of milk fat, protein and solid not fat on 21d of lactation (P = 0.07). Sows fed dry feeding type also showed higher milk energy content in milk of 21d lactation (P = 0.05). Furthermore, liquid feeding treatment showed high occurrence in feed waste during lactation period (P <0.01). Conclusion: Dry feeding method was more suitable feeding method to lactating sows under high temperature environment like lactating barn.