• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.144-148
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• 2001

In this study, to improve the color of iron oxide from waste pickling acid at the cold rolling mill, quality control technologies to improve color were investigated. During operation of the spray roaster, the charge amount of waste acid per hour, temperature, and numbers of spray nozzles were investigated. At the admixing process, titanium oxide, silica, and goethite were tested. The color character of iron oxide can be improved by process control of the spray roaster and the admixing process at a pigment factory. Iron oxide from this study is appropriate for use as a colorant of a concrete product.

• Resources Recycling
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• v.11 no.5
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• pp.24-29
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• 2002

In this study, to improve the color of iron oxide from waste pickling acid at the cold rolling mill, the quality control technologies especially about color were investigated on the spray roaster and iron oxide powder. At the operation condition of the spray roaster, the charge amount of waste acid per hour, temperature, numbers of spray nozzle were investigated. At admixing process, titanium oxide, silica, goethite were tested. Color character of iron oxide can be improved by process control at spray roaster and by admixing process at a pigment factory Iron oxide from results of this study is enough to use as the colorant of concrete product.

• The Korean Journal of Ceramics
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• v.2 no.3
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• pp.125-130
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• 1996

Hematite iron ore and waste iron oxide sludge containing about 3-5 wt% $SiO_2$ were purified by three types of method developed on the basis of the Bayer process which is known as the purification process of bauxite ore. The basic principle of the developed methods lies in the fact that the impurities contained in the iron oxides, such as $SiO_2$ and $Al_2O_3$ are soluble in the alkaline reagents. Reaction of the raw materials with KOH was done in pressure vessel, at atmospheric pressure, and by both of these two. By the pressure vessel method $SiO_2$ content was reduced to below 0.5 wt% in the waste iron oxide sludge, while, in iron ore, $SiO_2$ remained at 2-3 wt%. The atmospheric pressure reaction rendered the waste iron oxide sludge $SiO_2$ content below 0.5wt% when the reaction temperature increased to above 90$0^{\circ}C$. The combined method of two previous methods was the most effective process and rendered the refined iron oxide about 300-400ppm of $SiO_2$. Using some refined iron oxides, Ba-ferrite was produced and magnetic properties were measured. The highest quality of magnetic properties obtained in this study were Br=2.09 G, bHc=1.99 KOe, iHc=4.54 KOe, $(BH)_{max}$=1.06 MGOe. Effect of sintering condition and chemical composition will be discussed.

• Resources Recycling
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• v.7 no.4
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• pp.55-63
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• 1998

The main purpose of the present study is to reduce quality variation of iron oxide for soft ferrite produced at hydrochloric acid facility )HAF) in a cold rolled mill factory. We investigated the factor of iron oxide quality variation, the operating condition of hydrochloric acid facility and the iron oxide quality with the production lot. Based on this information, we liad developed proper working plan for the diminution of iron oxide quality variation. To reduce iron oxide quality variation, the first priority is to control the picking steels, which seriously affect iron oxide quality variation, and then to separate generated waste acid. theretore, it was possible to reduce iron oxide quality variation with the proper operation of various kinds of waste acid tanks. We could produce iron oxide below 20 ppm SiO$_{2}$ content variation by operation after separation waste acid generated at TCM line.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.387-392
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• 2001

Kobe Steel, LTD. and Midrex Technologies Inc. jointly developed the FASTMET$\circledR$ process as a steel mill waste recycle technology in which the DRI product meets BF feed material or BOF/EAF feed material requirements. FASTMET(R) process turns value-less wastes into valuable DRI and sellable zinc oxide, and gives the solution for the steel mill wastes recycling from both economical and environmental viewpoints. During the development of the process, Laboratory, Pilot Plant and Demonstration Plant tests were carried out from 1990 to 1998. The first FASTMET(R) commercial plant began operation in April, 2000 and the second commercial plant started in April, 2001 Both commercial plants have proceeded successfully preying that FASTMET$\circledR$ is a suitable process for recycling steel mill waste and for producing DRI as an iron source.

• Korean Journal of Crystallography
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• v.12 no.1
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• pp.20-24
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• 2001

NiZn-ferrite was synthesized usign waste iron oxide catalysts which were produced from styrene monomer process and buried underground as an industrial wastes. The spinel type ferrite was obtained by calcination and sintering of the mixture of finely ground waste catalysts, nickel oxide and zinc oxide powders. The sintered body of Ni/sub 0.5/Zn/sub 0.5/Fe₂O₄ composition at 1230℃ for 5 hours showed the density of 5.38g/㎤, and initial permeability of 59 at 1 kHz. Not only cerium oxide, which existed as a major component in the catalyst, but also unicorporated NiO and ZnO into spinel structure remained as second phases after sintering.

• Korean Journal of Materials Research
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• v.16 no.5
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• pp.336-340
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• 2006

Fluorspar has been essential flux in steelmaking process. The main effects of fluorspar addition are lowering of the viscosity and melting temperature of slag. In recent years, due to the increasing price and environmental problem of fluorspar, various types of fluorspar substitute have been investigated. In this study, iron oxide by-products such as sinter dust, basic oxygen furnace (BOF) sludge and mill scale were developed as a substitute in terms of waste recycling. Several plant trials were carried out by addition of briquetted substitutes of $4{\sim}6$ kg/ton to compare with the fluorspar of $0.7{\sim}1$ kg/ton. The substitutes showed a similar behavior of slag formation, phosphorus removal and MgO saturation content.

• Journal of the Korean Ceramic Society
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• v.38 no.12
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• pp.1162-1166
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• 2001

NiZn-ferrite was synthesized from waste catalysts, which were produced from styrene monomer process and buried underground as an industrial wastes, and its magnetic properties were investigated. Nickel oxide and zinc oxide powders were mixed with finely ground waste catalysts, and spinel type ferrite was obtained by calcination at 900$\^{C}$ and sintering at 1230$\^{C}$ for 5 hours. The intial permeability was measured and reflection loss was calculated from S-parameters for the composition of Ni$\_$x/Zn$\_$1-x/Fe$_2$O$_4$(x=0.36, 0.50, 0.66). NiZn-ferrite synthesized from waste iron oxide catalyst showed a feasibility for the use as electromagnetic wave absorber in X-band.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 1993.03a
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• pp.3.2-3
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• 1993

• Journal of Korea Society of Waste Management
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• v.34 no.5
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• pp.468-473
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• 2017

This study was carried out to examine the characteristics of hydrogen sulfide adsorption using an iron hydroxide-based adsorbent. The prepared adsorbent was discussed with regard to its adsorption capacity and analyzed via surface analysis methods to illustrate the physical characteristics of hydrogen sulfide adsorption. As the drying temperature increased, the adsorption capacity of the adsorbent decreased from 29.15wt% to 22.73wt%. The adsorption capacity was decreased as the space velocity increased and showed an adsorption capacity of about 3.65 at $3,157.6h^{-1}$. The effect of sulfur dioxide was to decrease the adsorption capacity from 29.15wt% to 27.94wt%. The adsorbent exhibited the amorphous type in its physical appearance based on XRD and EDS analysis.