• Title/Summary/Keyword: Waste gas

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Development of CO2 Emission Factor for Wood Chip Fuel and Reduction Effects (목질계 바이오매스 중 대체연료 우드칩의 온실가스(CO2) 배출계수 개발 및 저감 효과)

  • Lee, Seul-Ki;Kim, Seung-Jin;Cho, Chang-Sang;Jeon, Eui-Chan
    • Journal of Climate Change Research
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    • v.3 no.3
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    • pp.211-224
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    • 2012
  • Technology for energy recovery from waste can reduce the greenhouse gas emissions. So recently, there are several companies using RDF, RPF, WCF instead of using only coal fuel and it's part of the fuel on the increase. In this study, we developed Wood chip fuel $CO_2$ emission factor through fuel analysis. It's moisture content is 23%, received net calorific value is 2,845 kcal/kg, and received basis carbon is 34%. The result of emission factor is $105ton\;CO_2/TJ$, it's 5.9% lower than 2006 IPCC guideline default factor $112ton\;CO_2/TJ$. The gross GHG(Greenhouse gases) emissions of plant A is $178,767ton\;CO_2 eq./yr$, and Net GHG emissions is $40,359ton\;CO_2 eq./yr$. Therefore, the reduction of GHG emissions is $138,408ton\;CO_2/yr$ through using WCF, and I accounts for 77% of all GHG emissions.

Comparison of the CO2 Emissions Estimations among Four Tier Methods for the Facilities from Different Industrial Sectors in Korea (국내 산업 부문에 대한 온실가스 배출량 산정 방법 결과 비교)

  • Kim, Hee Jin;Yeo, Min Ju;Kim, Yong Pyo;Jang, Geon Woo;Shin, Won Geun;Lee, Myung Hwoon;Choi, Hyung Wook
    • Journal of Climate Change Research
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    • v.3 no.3
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    • pp.195-209
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    • 2012
  • There are four differentiated levels to quantify the amount of greenhouse gas emissions from a facility, which are Tier 1 to 4 based on the IPCC guidelines. In this study, the emission estimates from all tier levels were calculated to compare their total $CO_2$ emission results among themselves for seven facilities, including three sectors of electricity generation, municipal solid waste incineration, and cement manufacturing for three months between February and May 2011. Generally the measured $CO_2$ emissions by Tier 4 were higher than the calculated $CO_2$ emissions by Tier 3, which had been also observed for the power plants in the USA. It was found out that to obtain more reliable estimation for Tier 3, accurate analysis of the composition of the fuel used should be carried out. It was suggested that further refinement on the administrative guidelines be made to make it more robust.

Effect of Guide Fin Structures and Boundary Parameters on Thermal Performances of Heat Exchanger for Waste Heat Recovery Thermoelectric Generator (가이드 핀 구조와 경계 파라미터가 폐열 회수용 열전발전 열교환기의 열적 성능에 미치는 영향)

  • Garud, Kunal Sandip;Seo, Jae-Hyeong;Lee, Moo-Yeon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.3
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    • pp.30-35
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    • 2021
  • The present study examined the effects of various guide fin structures and boundary parameters on the thermal performance of heat exchangers used in heat recovery thermoelectric generators. The heat transfer rate and pressure drop of the heat exchangers without fins, with circular fins, with triangular fins, and with combined circular and triangular fins were simulated numerically using ANSYS 19.1 commercial code to confirm the effect of the guide fin structures. The heat transfer rate of the heat exchanger with combined fins was 27.0%, 5.2%, and 1.5% higher than those without fins, with circular fins, and with triangular fins, respectively. The pressure drop characteristic of the heat exchanger with the combined fins was 28.3% higher than that without fins but 9.2% and 10.5% lower than those with circular fins and with triangular fins, respectively. The heat exchanger with combined fins as the optimal model showed the highest heat transfer rate of 5664.9 W and pressure drop of 1454.02 Pa for highest hot gas temperature, maximum flow rates of hot gas and coolant, and lowest coolant temperature.

Development of Adsorbent for Vapor Phase Elemental Mercury and Study of Adsorption Characteristics (증기상 원소수은의 흡착제 개발 및 흡착특성 연구)

  • Cho, Namjun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.5
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    • pp.1-6
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    • 2021
  • Mercury, once released, is not destroyed but accumulates and circulates in the natural environment, causing serious harm to ecosystems and human health. In the United States, sulfur-impregnated activated carbon is being considered for the removal of vapor mercury from the flue gas of coal-fired power plants, which accounts for about 32 % of the anthropogenic emissions of mercury. In this study, a high-efficiency porous mercury adsorption material was developed to reduce the mercury vapor in the exhaust gas of coal combustion facilities, and the mercury adsorption characteristics of the material were investigated. As a result of the investigation of the vapor mercury adsorption capacity at 30℃, the silica nanotube MCM-41 was only about 35 % compared to the activated carbon Darco FGD commercially used for mercury adsorption, but it increased to 133 % when impregnated with 1.5 % sulfur. In addition, the furnace fly ash recovered from the waste copper regeneration process showed an efficiency of 523 %. Furthermore, the adsorption capacity was investigated at temperatures of 30 ℃, 80 ℃, and 120 ℃, and the best adsorption performance was found to be 80 ℃. MCM-41 is a silica nanotube that can be reused many times due to its rigid structure and has additional advantages, including no possibility of fire due to the formation of hot spots, which is a concern when using activated carbon.

Effect of Proteolytic Enzyme on the Unhairing Degree of Pelt (나피의 탈모율에 미치는 단백질 분해 효소의 효과)

  • Lee, Jong-Seok;Seo, Gyo-Taeg;Kim, Young Chai;Moon, Sei-Ki
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.635-638
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    • 1999
  • The effect of proteolytic enzyme on the unhairing process has been studied. this enzyme significantly changed the physical properties of pelt for leather shoes. A SEM was used to examine physical properties of the pelt. Even though bio-tech treatment using proteolytic enzyme slightly reduced the degree of unhairing compared to chemical treatment. Physical property of the pelt is better and this method is environmentally favorable. $H_{2}S$ gas produced in the chemical treatment was not detected and the value of COD and BOD for waste water after the unhairing process were reduced to 939 mg/L and 5268 mg/L, respectively. We found that a process with 0.4~0.5% proteolytic enzyme for 20 h at $29{\sim}30^{\circ}C$ is most suitable for the unhairing process.

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Removal Effect of Acid Gases by Reactant Mixer and Distributor of Bag Filter in Dry Scrubbing with NaHCO3 (중탄산나트륨 건식공정에서 반응제 혼합 장치 및 백필터 분배장치에 의한 산성가스 제거 영향)

  • Lee, Young-Man;Kwak, Yeon-Ho;Bae, Woo-Keun;Kwon, Ki-Wook
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.5
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    • pp.402-409
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    • 2009
  • Sodium bicarbonate ($NaHCO_3$) was used as a reactant for the removal of acid gases from a waste incinerator. The removal efficiencies of HCl and $SO_x$ were tested with a reactant mixing apparatus and a distributor installed at the bag filter inlet. It was shown that the stoichiometric ratio of $NaHCO_3$ to the acid gases which allows a removal of over 90% for both HCl and $SO_2$ was about 1.2. When a reactant mixing apparatus was installed on the duct, the removal efficiencies of HCl and $SO_2$ at the end of the duct were increased by approximately 1.5 and 3 times respectively, compared to when the apparatus was not installed. At the end of the bag filter, the removal efficiencies of the both were as high as 98% with a stoichiometric ratio of 1.35. Installing a reactant mixing apparatus on the duct and a distributor at the entrance of the bag filter and using $NaHCO_3$ as a reactant helped overcome the problem of low removal efficiencies of acid gases by dry scrubbing.

The Characteristics of High Ozone Concentration.Yield Multi-discharge Type Ozonizer for Water Environment Improvement (수질환경개선용 고농도.고수율 다중방전형 오존발생기의 특성)

  • Song, Hyun-Jig;Rahman, M. F.;Kim, Yeong-Hun;Kim, Geun-Young;Park, Won-Zoo;Lee, Kwang-Sik
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.13 no.2
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    • pp.71-79
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    • 1999
  • In this paper, high concentration.yield trulti-discharge type ozonizer( MDO ) of new discharge type using superposed silent discharge was designed and manufactured MDO can be consisted with 3 kind of superposed silent discharge type ozmizer( SDO ) in accordance with power supply method that suwlying power, which has $180[^{\circ}]$ phase difference, to 3 electrodes and amble gap. At the rroment, discharge characteristics and ozone generation characteristics of each SDO were investigated in accordance with quantity of suwlied gas, the number of SDO, and the shapes of each SDO. In result, ozone generatioo characteristics of 17185[ppm] and 783[g/kWh] were obtained, and when ozone of 17185[ppm] was in contact with dyeing water waste, decolorization characteristics was excellent, so it confinred that MDO could be used as water environment improvement facility.cility.

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Kinetics of Hydrogen Rich Ethanol as Reductant for HC-SCR over $Al_2O_3$ Supported Ag Catalyst (Ag/$Al_2O_3$ 촉매하의 HC-SCR에서 수소 풍부 에탄올의 반응 특성)

  • Lee, Ju-Heon;Park, Jeong-Whan;Kim, Seong-Soo;Yoo, Seung-Joon;Kim, Jin-Gul
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.6
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    • pp.519-525
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    • 2010
  • Ethanol was used as reductant to remove $NO_x$ over Ag/$Al_2O_3$ catalyst via SCR from stationary emission source. Among the tested hydrocarbon reductants, ethanol showed highest de-$NO_x$ performance over the Ag/$Al_2O_3$ catalyst. De-$NO_x$ efficiency of about 83% was obtained in the condition of GHSV 20,000 $hr^{-1}$, $NO_x$ 200 ppm, CO 200 ppm, $O_2$ 13%, $H_2O$ 5% and mole ratio of ethanol/$NO_x$ = 2 between temperature of $300^{\circ}C$ and $400^{\circ}C$. While $SO_2$ presence in the $NO_x$ exhaust suppressed the catalytic activity, catalyst with acid (0.7% $H_2SO_4$) treatment of catalyst showed higher catalytic activity, where In-Situ DRIFT showed S presence over catalyst surface was increased after acid treatment of catalyst. From in-situ DRIFT and SCR results, it was concluded that sulfur presence over the surface of Ag/$Al_2O_3$ catalyst was the dominant factor to control the de-$NO_x$ reaction yield via HC-SCR from the exhausted gas including $SO_2$.

A Study of Simulation on the Refrigerated Warehouse System Based on the Cold Energy of Lng Using the Pro-Ii Simulator (LNG 냉열을 이용한 냉장·냉동 창고 모사에 관한 연구)

  • HAN, DANBEE;KIM, YOONJI;YEOM, KYUIN;SHIN, JAERIN;BAEK, YOUNGSOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.4
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    • pp.401-406
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    • 2017
  • When Liquified Natural Gas (LNG) is vaporized into NG for industrial and household usage, tremendous cold energy was transferred from LNG to seawater during phase-changing process. This heat exchanger loop is not only a waste of huge cold energy, but will cause thermal pollution to the coastal fishery area also when cold water was re-injected into the sea. In this study, an innovation design has been performed to reclaim the cold energy for -35 to $62^{\circ}C$ refrigerated warehouse. Conventionally, this was done by installing mechanical refrigeration systems, necessitating tremendous electrical power to drive temperature. A closed loop LNG heat exchangers in series was designed to replace the mechanical or vapor-compression refrigeration cycle by process simulator. The process simulation software of PRO II with provision has been used to simulate this process for various conditions, what to effect on cold energy and used energy for re-liquefaction and evaporation process. In addition, through analysis the effect of the change of LNG supply pressure on sensible and latent heat, optimum operational conditions was suggested for LNG cold energy warehouse.

Performance Evaluation of Sintered Metal Filter in LILW Vitrification Facility (중.저준위 방사성폐기물 유리화설비에서 금속필터 적용성평가)

  • Park, Seung-Chul;Kim, Byong-Ryol;Hwang, Tae-Won
    • Journal of Energy Engineering
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    • v.15 no.3 s.47
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    • pp.146-153
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    • 2006
  • A performance test of the stainless steel based sintered metal filter was conducted on the low and intermediate level radioactive waste (LILW) vitrification process. The applicability of the metal filter was based on the test results as well. The baseline pressure drop of the metal filter was evaluated similar to the ceramic filter. During the test, when the flow rate of off-gas was $110Nm^{3}/h$, the total baseline pressure drop was shown as $92mmH_{2}O$. The total pressure drop was attributed to the filter media and the residual dust layer and the value of each was $25mmH_{2}O\;and\;67mmH_{2}O$ respectively. The SEM-EDS spectrum and micrograph of the metal filter specimen showed, no corrosion and no physical damage both at the skin membrane and at the support layer. And most of the baseline pressure drop was caused by the deposition of dust on the surface of the membrane. In conclusion, even though the filter exposure time was short at the test, the performance of the stainless steel based metal filter was acceptable for the treatment of LILW vitrification process.