• Title/Summary/Keyword: Waste artificial marble

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Study on Recycling Technology of Waste Artificial Marble using Starch (전분을 이용한 폐인조대리석의 재활용 기술에 관한 연구)

  • Ryoo, Keon Sang
    • Journal of the Korean Chemical Society
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    • v.62 no.6
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    • pp.433-440
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    • 2018
  • The pyrolysis has been universally applied to recycle the waste artificial marble. However, the existing heat treatment equipment has relatively low heat transfer efficiency into the inner part of the waste artificial marble. Besides, it leads to unnecessary excessive gas during the partial carbonization of the polymethyl methacrylate (PMMA) and raises the risk of fire due to heat at an extremely high temperature. This study suggests the process of pyrolysis at the formation state after adding the starch to waste artificial marble to overcome above-mentioned problems. As the result of experiments, this method showed that the pyrolysis of waste artificial marble was greatly improved at comparatively low temperature condition of $350^{\circ}C$. Moreover, it also manifested the effect on securing the stability and energy savings necessary for the recovery of methyl methacrylate (MMA) and ${\alpha}$-alumina (${\alpha}-Al_2O_3$).

A Study on Recovery of Aluminum Oxide from Artificial Marble Waste by Pyrolysis (열분해에 의한 폐인조대리석으로부터 산화알루미늄 회수에 관한 연구)

  • Kim, Bok Roen;Kim, Chang Woo;Seo, Yang Gon;Lee, Young Soon
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.567-573
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    • 2012
  • Compared with the natural marble, the artificial marble has the advantages of excellent appearance, high degree of finish, even color, fine pressure and wear resistance, bear erosion and weathering, etc. It can be widely used in kitchen countertops, bath vanity tops, table tops, furniture, reception desks, etc. However, large amounts of artificial marble waste such as scraps or dust have been generated from sawing and polishing processes in artificial marble industry. Waste from artificial marble industry is increasing according to demand magnification of luxurious interior material. Artificial marble wastes can be recycled as aluminum oxide used as raw materials in electronic materials, ceramics production, etc., and methyl methacrylate(MMA) which become a raw material of artificial marble by pulverization, pyrolysis and distillation processes. The characteristics of artificial marble wastes was analyzed by using TGA/DSC and element analysis. Crude aluminum oxide was obtained from artificial marble waste by pulverization and thermal decomposition under nitrogen atmosphere. In this work, Box-Behnken design was used to optimize the pyrolysis process. The characteristics of crude aluminum oxide was evaluated by chromaticity analysis, element analysis, and surface area.

The Characterization and Sintering Behavior of Alumina Powder Prepared by Heat-treatment of Artificial Marble Waste Containing $Al(OH)_3$ Powder ($Al(OH)_3$ 함유(含有) 인조대리석폐기물(人造大理石廢棄物)로부터 제조(製造)된 알루미나 분말(粉末)의 특성(特性) 및 소결거동(燒結擧動) 연구(硏究))

  • Ryu, Sung-Soo;Seo, Sung-Gyu;Kim, Hyung-Tae;Kim, Hyeong-Jun;Park, Jun-Gyu;Yang, Jae-Gyu
    • Resources Recycling
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    • v.18 no.2
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    • pp.69-76
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    • 2009
  • Alumina powder was prepared from heat-treatment of artificial marble waste fine aggregate containing $Al(OH)_3$ for the purpose of the feasibility of its recycling. Artificial marble waste was heat-treated between $500^{\circ}C$ and $1000^{\circ}C$ and XRD, BET surface area, BJH pore size distribution and adsorption of As were analyzed for heat-treated powder. It was found that the adsorption efficiency of As was significantly affected by phase composition of alumina powder rather than its physical characteristic. Heat-treated powder compact was sintered to produce the pellet. Alumina pellet with porosity more than 60% could be obtained after sintering below $1200^{\circ}C$ and also the addition of glass powder as a sintering aid had a positive effect on lowering sintering temperature, led to the high porosity near 60% and adsorption of As over 60% even at $900^{\circ}C$.

A Study on the Trend and Utilization of Stone Waste (석재폐기물 현황 및 활용 연구)

  • Chea, Kwang-Seok;Lee, Young Geun;Koo, Namin;Yang, Hee Moon
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.3
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    • pp.333-344
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    • 2022
  • The quarrying and utilization of natural building stones such as granite and marble are rapidly emerging in developing countries. A huge amount of wastes is being generated during the processing, cutting and sizing of these stones to make them useable. These wastes are disposed of in the open environment and the toxic nature of these wastes negatively affects the environment and human health. The growth trend in the world stone industry was confirmed in output for 2019, increasing more than one percent and reaching a new peak of some 155 million tons, excluding quarry discards. Per-capita stone use rose to 268 square meters per thousand persons (m2/1,000 inh), from 266 the previous year and 177 in 2001. However, we have to take into consideration that the world's gross quarrying production was about 316 million tons (100%) in 2019; about 53% of that amount, however, is regarded as quarrying waste. With regards to the stone processing stage, we have noticed that the world production has reached 91.15 million tons (29%), and consequently this means that 63.35 million tons of stone-processing scraps is produced. Therefore, we can say that, on a global level, if the quantity of material extracted in the quarry is 100%, the total percentage of waste is about 71%. This raises a substantial problem from the environmental, economical and social point of view. There are essentially three ways of dealing with inorganic waste, namely, reuse, recycling, or disposal in landfills. Reuse and recycling are the preferred waste management methods that consider environmental sustainability and the opportunity to generate important economic returns. Although there are many possible applications for stone waste, they can be summarized into three main general applications, namely, fillers for binders, ceramic formulations, and environmental applications. The use of residual sludge for substrate production seems to be highly promising: the substrate can be used for quarry rehabilitation and in the rehabilitation of industrial sites. This new product (artificial soil) could be included in the list of the materials to use in addition to topsoil for civil works, railway embankments roundabouts and stone sludge wastes could be used for the neutralization of acidic soil to increase the yield. Stone waste is also possible to find several examples of studies for the recovery of mineral residues, including the extraction of metallic elements, and mineral components, the production of construction raw materials, power generation, building materials, and gas and water treatment.