• Title/Summary/Keyword: Waste acid

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Bioconversion of Dairy Processing Waste into Value-Added Chemicals

  • Kim, Dong-Shik
    • Journal of Environmental Policy
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    • v.2 no.2
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    • pp.65-79
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    • 2003
  • More than 145 million tons of liquid whey is produced world-wide as dairy processing waste per year, and half of it is discarded without proper treatment. Due to its high nutrient value, the environmental impact can be significant. Bioconversion of cheese whey can provide an effective way to reduce the waste and, at the same time, generate economically attractive value-added chemicals. In this study, cheese whey was fermented with P. acidipropionici to produce propionic acid which has a high market value for chemical and pharmaceutical industries. In order to specifically enhance propionic acid production, acetic acid production was suppressed using o-iodosobenzoic acid as an enzyme inhibitor. When grown in the presence of the inhibitor, propionic acid production rate increased by a factor of 2 while acetic acid production rate decreased by a factor of 3. Furthermore, when 0.3 mM of o-iodosobenzoic acid was used, the incipient stage(creeping growth period) was considerably reduced. Therefore, the inhibitor helps the cells begin to grow earlier and speed up the production of propionic acid. Although the production rate of propionic acid effectively increased, the final concentration(or production yield) remained unchanged due to product inhibition. Methods that can reduce product inhibition are being tested combined with o-iodosobenzoic acid to optimize both the production rate and yield. The results are expected to be informative for controlling the other byproducts for other applications.

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Preliminary Study on the Regeneration of Spent Electro-decontamination Solution Using Phosphoric Acid and Oxalic Acid

  • Naznin, Marufa;Septian, Ardie;Shin, Won Sik
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2015.10a
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    • pp.465-466
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    • 2015
  • In this study, different amount of (fe(0)) were dissolve into different strength of phosphoric ($H_3PO_4$) acid and the optimum solubility was observed at 0.89M Fe(0) into 4M of $H_3PO_4$ acid. Different concentration of oxalic acid was added to determine the optimum precipitated condition. The dissolution kinetics of Fe(0) into $H_3PO_4$ acid was investigated at $40-50^{\circ}C$. The optimum Fe-oxalate precipitate was dried and thermal decomposition using DSC-TG was conducted. Approximately 52 wt(%) of oxalic acid was removed at $300^{\circ}C$. Iron oxides such as magnetite and hematite that may be formed on the surface of nuclear waste were also dissolved into the $H_3PO_4$ acid and the optimum solubility for magnetite is 0.005M while that for hematite is 0.02M in 8M $H_3PO_4$ acid, respectively.

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Effect of Temperature and Pre-treatment for Elutriated Acidogenic Fermentation of Piggery Waste (돈사폐수의 세정산발효시 온도와 전처리의 영향)

  • Bae, Jin-Yeon;Min, Kyung-Sok
    • Journal of Korean Society on Water Environment
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    • v.21 no.1
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    • pp.34-39
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    • 2005
  • The performance of elutriated acid fermentation with slurry-type piggery waste was investigated, especially to evaluate the effects of temperature and pre-treatment. In the first phase, the acid elutriation reactor with piggery waste after centrifugation operated at both mesophilic and thermophilic conditions to evaluate the effect of temperature. Solubilization yield($gVFAs/gSCOD_{prod.}$) and acidification rate($gVFAs/gSCOD_{prod.}$) in the thermophilic digestion were 0.45 and 0.55, which were higher than those of the mesophilic digestion, 0.25 and 0.45. In addition, the acid elutriation reactor at thermophilic temperature is more effective in removing e-coli. In the second phase, the acid elutriation reactor was fed with piggery waste before centrifugation. With piggery wastes before centrifugation, the solubilization yield and the acidificaton rate were 0.40 and 0.80, respectively, which were higher than the rates using piggery waste after centrifugation at both mesophilic and thermophilic conditions. The higher sludge volume reduction of 80% benefits sludge management. Furthermore, economical advantages can be achieved by removing the pre-treatment process, such as centrifugation. Consequently, the treatment with piggery waste before centrifugation proved to be effective. Also, the optimum temperature condition was estimated at mesophilic or thermophilic conditions, considering solubilization yields and acidification rates, though the system should be heated.

임기광산 폐석 및 퇴적물의 산성배수발생 능력 평가

  • 정영욱;임길재;지상우;민정식;최용석
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.390-393
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    • 2004
  • This study was carried out to evaluate the acid producing potential of geological materials such as pit wall, waste rock and stream sediments near the abandoned Imgi mine. The 17 samples used in this study were collected and then treated by static test such as Acid Base Accounting and etc. Samples of pit wall and waste rocks with high S content display a NAGpH values below 4.5 and net acid potential. Therefore some cost effective measures such as capping and groudwater flow barriers, will be required to reduce the impacts of ARD from the waste rock impoundment and the pit wall on near the stream.

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Pretreatment Effect of Waste Automotive Catalysts for VOCs Combustion (VOCs 연소를 위한 자동차 폐촉매의 전처리 효과)

  • 문정선
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.2
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    • pp.191-198
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    • 2000
  • For a characterization of the pretreated waste automotive catalyst the following analysis techniques were applied : EA(Elemental Analysis) BET(Brunaure-Emmett-Teller) and ICP-AES(Inductively Coupled Plasma-Atomic Emission Spectrometry). The combustion activity of waste automotive catalyst was investigated for methanol acetaldehyde and toluene as model VOCs in a fixed bed reactor. carbon deposit amount was decreased with increasing catalyst showed a good catalytic activity for VOCs combustion at 40$0^{\circ}C$. Catalytic activity for methanol acetaldehyde and toluence combustion was very excellent and decreased with mileage. The catalytic activity of a waste automotive catalyst for methanol combustion increased after acid treatment. The acid effect of catalytic activity was summarized as follows: HNO3>HCI>H2SO4>CH3COOH. The waste automotive catalyst regenerated by the pretreatment method might have a excellent catalytic activity for VOCs combustion.

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Acid Resistance of Unsaturated Polyester Mortar Using Crushed Wate Glass (폐유리를 골재로 사용한 불포화폴리에스테르 모르타르의 내산성에 관한 연구)

  • 한창호;최길섭;김완기;조영국;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.04a
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    • pp.339-342
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    • 2000
  • Recently, the importance of the conutermeasures for waste materials has pointed out. Waste glass is also one to waste materials used for the recycling in construction sites. The crushed waste glass has been used to make a glass polymer composite that can be applied for sewer, storm drain pipe and interlocking block, etc. In this study, the crushed waste glass is explored with the possibility of recycling it, as a substitute for fine aggregates. The prepose of this investigation is to improve the strengths and acid resistance of the UP mortars using crushed waste glass. The UP mortars are prepare with blast furnace slag fly ash filler. the UP-fine aggregate ratios the crushed waste glass replacements for fine aggregate are tested strengths before and after immersion(H (아래첨자2)SO(아래첨자4) 10%), weight change and acid resistance are also tested. From the test results, the relative strength or UP mortars using fly ash as filler are found to be somewhat superior to that of the UP mortars using blast furnace as filler, And a UP mortar with fly ash as a filler, a UP-fine aggregate ratio of 15% and a waste glass replacement if 50% for fine aggregate is recommended as optimal mix proportion of UP mortar using crushed waste glass. Accordingly, it is enough to assure the use of the crushed waare glass as an aggregate for the production of UP mortar.

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Preparation of Alum and Poly Aluminum Chloride Using Waste Aluminum Dross (알루미늄 폐드로스를 재활용(再活用)한 Alum과 Poly Aluminum Chloride 제조(製造) 연구(硏究))

  • Park, Hyung-Kyu;Lee, Hoo-In;Choi, Young-Yoon
    • Resources Recycling
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    • v.16 no.5
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    • pp.3-7
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    • 2007
  • Waste aluminum dross was processed to prepare alum with sulfuric acid, and poly aluminum chloride(PAC) with hydrochloric acid. Metallic aluminum remained in the waste dross was dissolved into the sulfuric acid solution, and the solution could be used as alum for water treatment chemicals after adjusting the required alumina concentration and pH of the solution. Also, it was dissolved into the hydrochloric acid solution and processed to make PAC solution. Compared with the conventional method for preparation of alum and PAC using aluminum hydroxide, material cost could be saved in this method. Also, there is an additional merit in view of recycling of the waste aluminum dross by reducing the amount of waste disposed to landfill.

Improvement of Color for Iron Oxide from Waste Pickling Acid (산화철 안료의 색상개선 연구)

  • 손진군;금대영;이재영;이훈하
    • Resources Recycling
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    • v.11 no.5
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    • pp.24-29
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    • 2002
  • In this study, to improve the color of iron oxide from waste pickling acid at the cold rolling mill, the quality control technologies especially about color were investigated on the spray roaster and iron oxide powder. At the operation condition of the spray roaster, the charge amount of waste acid per hour, temperature, numbers of spray nozzle were investigated. At admixing process, titanium oxide, silica, goethite were tested. Color character of iron oxide can be improved by process control at spray roaster and by admixing process at a pigment factory Iron oxide from results of this study is enough to use as the colorant of concrete product.

Improvement of color for iron oxide from waste pickling acid

  • Sohn, Jin-Gun;Kim, Dae-Young;Lee, Jae-Young;Lee, Hun-Ha;Kim, Jang-Su;Sung, Gee-Woong
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.144-148
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    • 2001
  • In this study, to improve the color of iron oxide from waste pickling acid at the cold rolling mill, quality control technologies to improve color were investigated. During operation of the spray roaster, the charge amount of waste acid per hour, temperature, and numbers of spray nozzles were investigated. At the admixing process, titanium oxide, silica, and goethite were tested. The color character of iron oxide can be improved by process control of the spray roaster and the admixing process at a pigment factory. Iron oxide from this study is appropriate for use as a colorant of a concrete product.

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