• Title/Summary/Keyword: Waste acid

Search Result 955, Processing Time 0.041 seconds

Biosorption of Heavy-metal Ions by Waste Brown Seaweed and Their Derivatives (미역 폐기물 및 미역폐기물 유도체에 의한 중금속이온의 생물흡착)

  • 박권필;김태희;김영숙;차왕석;우명우
    • Journal of Environmental Science International
    • /
    • v.10 no.2
    • /
    • pp.153-158
    • /
    • 2001
  • The biosorption abilities of different parts of waste brown seaweeds and their derivatives to remove heavy metals (Cd, Zn, Pb, Cu, Fe, Ni, Mn) from waste were evaluated. The two parts of waste brown seaweeds (Undaria pinnatifida) were stems and sporophyls, and the brown seaweed derivatives were alginic fibers, active carbon added alginate(AC-alginate) and dealginate. The abilities of the sporophyls to adsorb the heavy metal ions were higher than those of stems, and those of alginates were slightly higher than those of dealginate in single ion solution. With decreasing the size of biosorbents, the velocity and the amount of adsorption increased. The abilities of alginate to remove the heavy metal ions increased in multi-ion solutions by adding active carbon to alginate. The selectivity of these biosorbents(alginate, AC-alginate) to lead ion was highest and to manganese ion was lowest.

  • PDF

An Experimental Study on Properties of Light-Weight Foamed Concrete Using the Waste Concrete Powder (폐콘크리트 미분을 사용한 경량기포콘크리트의 특성에 관한 실험적 연구)

  • Choi, Hun-Gug;Kim, Jae-Won;Seo, Jung-Pil;Lee, Jung-Goo;Kang, Cheol;Kim, Jin-Man
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2007.04a
    • /
    • pp.75-78
    • /
    • 2007
  • The recycling program about waste concrete is being progressed to national research. But research on waste concrete powder which is occurred in control process of concrete powder is not enough. Waste concrete powder includes in $SiO_2,\;Al_2O_3$, and CaO so that the create of tobermorite is possibile through Hydrothermal Syntesis Reaction. Tobermorite have an advantage of high strength, sulphuric acid resistance and the lower drying shrinkage. Accordingly, this study investigate in properties of light-weight foamed concrete made with waste concrete powder. As a results, light-weight foamed concrete made with waste concrete powder is the higher than stone powder sludge of density and porosity, and the tower compressive strength. Therefore, it is thought that light-weight foamed concrete using waste concrete powder is possible.

  • PDF

Recovery of Nitric Acid from Waste Solder Stripper by Diffusion Dialysis (폐솔더 박리액으로부터 확산투석법에 의한 질산의 회수)

  • Ryu, Seong-Hyung;Kim, Tae-Young;Ahn, Nak-Kyoon;Gang, Myeong-Sik;Ahn, Jae-Woo;Ahn, Jong-Gwan
    • Resources Recycling
    • /
    • v.24 no.5
    • /
    • pp.33-39
    • /
    • 2015
  • A basic study was conducted to effectively recover nitric acid from a waste solder stripper by diffusion dialysis using anion exchange membranes. The effects of flow rate, flux ratio, nitrate concentration, and metallic ion types and concentration on the recovery percentage of nitric acid were investigated. The recovery percentage of nitric acid was decreased with the increase of flow velocity. But the recovery percentage of nitric acid was increased as the increase of flux ratio(W/F) and showing a recovery percentage of nitric acid of about 99% at a flux ratio of 1.5 or more. As the increase of nitric acid concentration in feed solution, the recovery percentage of nitric acid was increased up to 3.0M, but in case of greater than 3.0M, the recovery percentage gradually was decreased. Leakage percentage of metallic ions through the membrane were in the order of Pb, Na and Cu but Fe and Sn did not leakaged. As a result of diffusion dialysis using real waste solder stripper at a flow rate of $0.9L/hr-m^2$, W/F = 1.3, a recovery percentage of nitric acid of approximately 94% was gained.

A study on the Separation/recovery of Rare Earth Elements from Wast Permanent Magnet by a Fractional Crystallization Method and Sulfuric Acid Leaching (폐영구자석 황산침출과 분별결정법에 의한 희토류 분리·회수에 대한 연구)

  • Kim, Dae-Weon;Kim, Hee-Seon;Kim, Boram;Jin, Yun-Ho
    • Clean Technology
    • /
    • v.28 no.2
    • /
    • pp.103-109
    • /
    • 2022
  • Nd-Fe-B waste permanent magnet contains about 20~30% rare earth elements and about 60~70% iron elements, and the rare earth and iron components were recovered through sulfuric acid leaching and fractional crystallization. Oxidation roasting was not performed for separation and recover of the rare earth and iron elements. The leaching characteristics were confirmed by using as variables the sulfuric acid concentration and the mineral solution concentration ratio. Sulfuric acid leaching was carried out for 3 hours for each sulfuric acid concentration. The leached solid phase was characterized for its crystalline phase, composition, and quantitative components by XRD and XRF analysis, and the filtrate was analyzed for components by ICP analysis. With sulfuric acid leaching at 3M sulfuric acid concentration, neodymium compounds were formed, the iron content was the least, and the recovery rate was high. After the filtrate remaining after sulfuric acid leaching was subjected to fractional crystallization through evaporation and concentration, the neodymium component was found to be concentrated 7.0 times and the iron component 2.8 times. In this study, the recovery rate of waste permanent magnets through sulfuric acid leaching and a fractional crystallization method without an oxidation and roasting process was confirmed to be about 99.4%.

A Study of Adsorption Behaviour of Humic Acid and Americium on the Kaolinite (카올리나이트에 대한 휴믹산 및 아메리슘 흡착거동 연구)

  • Lee, Myung-Ho;Lee, Kyu-Whan;Park, Kyung-Kyun;Jung, Euo-Chang;Song, Kyu-Seok;Shin, Hyun-Sang
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
    • /
    • v.8 no.2
    • /
    • pp.107-113
    • /
    • 2010
  • In this study, the adsorption reactions in the binary component system such as kaolinite-humic acid, kaolinite-americium and humic acid-americium were investigated. After performing the basic physico-chemical properties of the kaolinite, the adsorption reactions of the humic acid on the kaolinite were carried out with varying concentration of humic acid and ion strength, and pH. With increasing HA concentration and pH, the sorption of HA onto KA decreased, while the sorption of HA onto KA increased with increasing ionic stre ngth. Also, with varying pH, the adsorption reactions of the americium-kaolinite and americium-humic acid were studied. In the acid and neutral region, Am easily adsorbed on the HA, while the sorption of Am on the HA in the alkali region decreased because of electrostatic repulsion. The results from these studies make it possible to understand the characteristics of adsorption behaviour of the americium by the humic acid in the water environment.

Effect of Food Waste Mixing on Hydrogen Gas Production in Anaerobic Digestion of Brown Water from Urine Diversion Toilet (소변분리변기오수(Brown water)의 혐기성 처리 시 음식물 쓰레기 혼합에 따른 수소생산 특성)

  • Seong, Chung-Yeol;Yoon, Cho-Hee;Seo, Gyu-Tae
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.36 no.12
    • /
    • pp.865-872
    • /
    • 2014
  • The study was conducted to evaluate the effect of addition of food waste in brown water for anaerobic hydrogen production. Batch experiment was carried out to determine appropriate food waste to brown water mixing ratio. Maximum hydrogen yield of $6.92mmol\;H_2/g\;COD_{removed}$ was obtained at 70% food waste and 30% brown water. Semi-pilot scale reactor was operated based on result of batch experiment. Semi-pilot reactor operated, mixing 70% food waste and 30% brown water showed significant increment in butyric acid concentration. B/P (Butyric to propionic acid ratio) which is considered as governing factor for hydrogen production was found high (52.64). Maximum hydrogen yield of $25.03mmol\;H_2/g\;COD_{removed}$ was obtained. Result of this study concluded that mixing of food waste to brown water at appropriate ratio assists in enhanced hydrogen fermentation.

Studies on the feeding value of the waste wood of Leniinus eddodes (표고 재배(栽培) 폐재(廢材)의 사료화(飼料化)에 관(關)한 연구(硏究))

  • Kim, Bub-Whoe;Lee, Teck-Won;Min, Du-Sik;Kim, Nae-Soo
    • Journal of the Korean Wood Science and Technology
    • /
    • v.6 no.1
    • /
    • pp.8-14
    • /
    • 1978
  • In order to determine the feeding value of t:1e waste wood of Lentinus eddodes, the waste wood was milled and treated with $Ca(OH)_2$ and cellulase, then raw waste wood and the treated waste wood were fed to broiler chicken and Korean native goates. The results obtained were as follows; 1. The chemical composition of the waste wood was c. protein 2.26%. c. fat 2.57%. c. fiber 44.60 and c. ash 5.58%. No differences were detected between the raw waste wood and $Ca(OH)_2$ or cellulase treated waste wood in chemical composition. 2. In amino acid composition. no cystine and methionine was showed, but trace amount of Vitamin A, $B_1$, and $B_2$, and cholin chloride were detected. 3. Trichoderma viride SANK. No. 16374 was used to decompose the cellulose. 4. In broiler performance, when waste wood meal was subsituted for 5% wheat bran, no adverse effect was showed on weight gain, feed in take and feed efficiency. But $Ca(OH)_2$ and cellulase treated waste wood meal could be subsituted for 8% wheat bran. 5. In Korean native goat performance, feeding waste wood meal subsituted by 50% various bran (25% defatted rice bran and 25% barley bran) had no adverse effect on growth and feed efficiency. 6. Considering the above results, though the waste wood meal could be replaced to part of various bran, there was a bottle-neck to process the waste wood. The waste wood of Lentinus edodes was little feeding value on bed of ruminant.

  • PDF

Nondestructive determination of humic acid in compost by NIRS

  • Seo, Sang-Hyun;Han, Xiao-Ri;Cho, Rae-Kwang;Park, Woo-Churl
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
    • /
    • 2001.06a
    • /
    • pp.1623-1623
    • /
    • 2001
  • Composting is a biological method used to transform the organic waste into stable, humified organic amendments. Humification is indicated as the key factor in improving the quality of compost, because of the importance of humic substances to soil ecology, fertility and structure, and their beneficial effects on plant growth The compost constituents vary widely, however, the degree of maturity is very important factor in compost quality. So this experiment carried out to determine the rapid estimation of the quality in cattle, pig, chicken and waste composts using near infrared reflectance spectroscopy(NIRS). Near infrared reflectance spectra of composts was obtained by Infra Alyzer 500 scanning spectrophotometer at 2-nm intervals from 1100 to 2500nm. Multiple linear regression(MLR) or partial least square regression (PLSR) was used to evaluate a NIRS method for the rapid and nondestructive determination of humic acid contents in composts. The results summarized that NIR spectroscopy can be used as a routine testing method to determine quantitatively the humic acid content in the compost samples ondestructively. Especially, we supposed that absorbance around 2300nm is related to humic acid as a factor of compost maturity. However the NIR absorption approach is empirical, it actually requires many combinations of samples and data manipulations to obtain optimal prediction.

  • PDF