• Title/Summary/Keyword: Waste PET

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Preparation and Characterization Study of PET Nanofiber-reinforced PEI Membrane, Investigation of the Application of Organic Solvent Nanofiltration Membrane (PET 나노섬유 강화 PEI 막의 제조 및 특성화 연구, 그에 따른 유기용매 나노여과막 가능성 검증)

  • Sung-Bae Hong;Kwangseop Im;Dong-Jun Kwon;Sang Yong Nam
    • Journal of Adhesion and Interface
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    • v.24 no.1
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    • pp.17-25
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    • 2023
  • In this study, waste polyethylene terephthalate (PET) was recycled to produce a support and then polyetherimide (PEI) was used for environmentally friendly organic solvent nanofiltration. The prepared composite membrane was first prepared by electrospinning a PET support, then casted on the support using PEI having excellent solvent resistance, and organic solvent nanoparticles using a Non-solvent Induced Phase Separation (NIPS) method. A filtration membrane was prepared. First, the fiber diameter and tensile strength of the PET scaffold prepared prior to membrane fabrication were identified through morphology analysis, and the optimal scaffold for the organic solvent nanofiltration membrane was identified. Afterward, the PET/PEI composite membrane prepared was checked for the DEA removal rate of Congo red having a molecular weight of 697 g/mol in ethanol to understand the performance as an organic solvent nanofiltration membrane according to the concentration of PEI. Finally, the removal rate of Congo red was 90% or more.

A Study on Material Separation of Heavy Group Plastics by Triboelectrostatic Separation (마찰하전형(摩擦荷電型) 정전선별(靜電選別)에 의한 고비중(高比重) 플라스틱 혼합물(混合物)의 재질분리(材質分離)에 관한 연구(硏究))

  • Jeon, Ho-Seok;Baek, Sang-Ho;Park, Chul-Hyun;Kim, Byoung-Gon
    • Resources Recycling
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    • v.16 no.2 s.76
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    • pp.56-62
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    • 2007
  • In this study, we carried out the research on triboelectrostatic separation for heavy group plastics (PET, PVC) recovered from wet gravity separation. From the research on charging characteristic for the choice of charging materials, it was found that PP was optimum charging material to make high charging amount with opposite polarity for PET and PVC of heavy group. Therefore, we manufactured a charger of cyclone type using PP material for separation of PET and PVC. At optimum test conditions that used PP cyclone charger developed in this study, we developed a triboelectrostatic separation technique that can separate PET plastic up to grade of 98.5% and recovery of 86.2%. We established new separation technology that could recycle the PET and PVC heavy group plastics recovered from wet gravity separation.

Research on Pyrolysis Properties of Waste Plastic Films (폐플라스틱 필름의 열분해특성에 대한 연구)

  • Kim, Young-Min;Lee, Boram;Han, Tae Uk;Kim, Seungdo;Yu, Tae-U;Bang, Byoung Yeol;Kim, Joug-Su;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.28 no.1
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    • pp.23-28
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    • 2017
  • Pyrolysis characteristics of waste plastic films were investigated by using a thermogravimetric analysis and pyrolyzer-gas chromatography/mass spectrometry. Thermogravimetric analysis results revealed that the pyrolysis of waste plastic films can be divided into two distinct reactions; (1) the decomposition reaction of starch at between 200 and $370^{\circ}C$ and (2) that of other plastic polymers such as PS, PP, PE at between 370 and $510^{\circ}C$. The kinetic analysis results obtained by using the revised Ozawa method indicated that the apparent activation energy of the pyrolysis reaction of waste plastic films was also changed dramatically according to the different decomposition reactions of two major waste plastic film components. Py-GC/MS results also revealed that the typical pyrolyzates of each polymer in waste plastic films were levoglucosan (starch), terephthalic acid (PET), styrene monomer, dimer, and trimer (PS), methylated alkenes (PP), and triplet peaks (PE) composed of alkadiene/alkene/alkane. The phthalate, used as a polymer additive, was also detected on the pyrogram of waste plastic films mixture.

A Study on the Separation of Mixed Waste Plastics by Trioboelectrification (마찰대전을 이용한 혼합폐플라스틱 분리에 관한 연구)

  • Lee, Jong-Ho;Shin, Jin-Hyuk;Kim, Doo-Hyun;Kim, Jang-Woo;Lee, Jae-Keun
    • Proceedings of the KSME Conference
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    • 2000.11b
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    • pp.538-543
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    • 2000
  • The purpose of this study is to develope electrostatic separation system for recycling of mixed waste plastics. The electrostatic separation system is designed and investigated the separation efficiency for separating of mixed waste plastics. Electrostatic separation system consisted of a tribocharger, separator (two electrode), collector (5 tray) and controller (positive/negative high voltage power supply). The tribocharger is a fluidized bed using tribo-electrification mechanism between particles and particles. In experimental results, the tribocharger of the fluidized bed was more effective separation efficiency. It showed the purity of $85{\sim}99\;%$ and the recovery of $80{\sim}98\;%$ from the powder of mixed plastics such as LDPE, HDPE, PP, PS, PET and PVC. Especially, In the separation experiment of Polyvinylchloride(PVC) which generates hazardous hydrogen chloride gas in case of the combustion. its purity was over 99 % and recovery was over 95 %.

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Study on Concrete Activation Reduction in a PET Cyclotron Vault

  • Bakhtiari, Mahdi;Oranj, Leila Mokhtari;Jung, Nam-Suk;Lee, Arim;Lee, Hee-Seock
    • Journal of Radiation Protection and Research
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    • v.45 no.3
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    • pp.130-141
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    • 2020
  • Background: Concrete activation in cyclotron vaults is a major concern associated with their decommissioning because a considerable amount of activated concrete is generated by secondary neutrons during the operation of cyclotrons. Reducing the amount of activated concrete is important because of the high cost associated with radioactive waste management. This study aims to investigate the capability of the neutron absorbing materials to reduce concrete activation. Materials and Methods: The Particle and Heavy Ion Transport code System (PHITS) code was used to simulate a cyclotron target and room. The dimensions of the room were 457 cm (length), 470 cm (width), and 320 cm (height). Gd2O3, B4C, polyethylene (PE), and borated (5 wt% natB) PE with thicknesses of 5, 10, and 15 cm and their different combinations were selected as neutron absorbing materials. They were placed on the concrete walls to determine their effects on thermal neutrons. Thin B4C and Gd2O3 were placed between the concrete wall and additional PE shield separately to decrease the required thickness of the additional shield, and the thermal neutron flux at certain depths inside the concrete was calculated for each condition. Subsequently, the optimum combination was determined with respect to radioactive waste reduction, price, and availability, and the total reduced radioactive concrete waste was estimated. Results and Discussion: In the specific conditions considered in this study, the front wall with respect to the proton beam contained radioactive waste with a depth of up to 64 cm without any additional shield. A single layer of additional shield was inefficient because a thick shield was required. Two-layer combinations comprising 0.1- or 0.4-cm-thick B4C or Gd2O3 behind 10 cm-thick PE were studied to verify whether the appropriate thickness of the additional shield could be maintained. The number of transmitted thermal neutrons reduced to 30% in case of 0.1 cm-thick Gd2O3+10 cm-thick PE or 0.1 cm-thick B4C+10 cm-thick PE. Thus, the thickness of the radioactive waste in the front wall was reduced from 64 to 48 cm. Conclusion: Based on price and availability, the combination of the 10 cm-thick PE+0.1 cmthick B4C was reasonable and could effectively reduce the number of thermal neutrons. The amount of radioactive concrete waste was reduced by factor of two when considering whole concrete walls of the PET cyclotron vault.

Mechanical Properties of Green Strain-Hardening Cement-based Composites with Recycled Materials (순환재료를 사용한 그린 변형 경화형 시멘트 복합체의 역학적 특성)

  • Yun, Hyun-Do;Kim, Sun-Woo;Lee, Young-Oh;Nam, Sang-Hyun;Cha, Jun-Ho;Kim, Yun-Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.399-400
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    • 2010
  • This paper presents results of an experimental program for evaluating the mechanical properties of green strain-hardening cementitious composite (SHCC) using recycled material. Recycled poly ethylene terephthalate (PET) fiber, fly ash, and recycled sand from waste concrete are used as materials for green SHCC. Test results indicated that average tensile strength of five dumbbell-shaped specimen is 4.76MPa and average compressive and flexural strength of three specimens are 38MPa and 7.40MPa, respectively.

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The Effect of Dogmeat Eating on Sanitation and Food Waste Consumption (개고기 식용이 위생과 음식물 쓰레기 처리에 미치는 영향)

  • Ann, Yong-Geun
    • The Korean Journal of Food And Nutrition
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    • v.23 no.1
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    • pp.124-133
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    • 2010
  • The total number of the dogs bred in Korea as of 2007 was 1,917,709, and among them, 77%, 1,476,776 dogs were edible dogs. Dogmeat has been legalized edible as food from Choseon dynasty, Daehan imperial state, Japan-occupied era till the present Korea. Dogs had been included in the article 2, Enforcement Ordinance of Processing and Disposal Rule of Livestock and Its Products until the end of Jan. 1979, but it was crossed out by the Notification No 3,005(Feb. 1 1979 effective) of the Minister of Agriculture and Marine Products, and as a result, the obligation that dogs should be slaughtered at the slaughtering ground was defunct. Thus, the arbitrarily dog slaughtering was empowered. As a matter of fact, the new law was not legalized in order to ban dogs from being slaughtered. The waste amount of slaughtered edible dogs amounts to 7,282 tons annually, and most of its waste from the arbitrarily-slaughtered dog is being illegally dumped without proper management and supervision. Edible dogs defecate 292,509 tons(calculates urine as dung) annually, but it is sanitarily disposed according to the Law of Management and Use of Livestock's Dung and Urine which took effective from Sep. 2009. Annual sales amount of edible dogs comes to 590 billion won on the basis of the shipment at breeding ground, but after passing through various level of marketing, and being processed as Gaesoju, and Boshintang, it forms 4 trillion won market when it reaches customers. The amount of food waste in Korea in 2007 came to 5,274,944 tons, and 633 billion won was spent for its disposal cost. Korean edible dogs of 1,476,776 heads consumed 1,266,705 tons, the 24% of total food waste. Edible dogs are the most effective means to convert food waste into food for man, not entailing the cost of disposal. On the other hand, pet dog culture brought about disposal cost, and the 51,188 dogs were abandoned at 2007, while 7 billion won was spent for the protection, euthanasia of them and the disposal of their dead bodies.

A study of Improvement of Stiffness for Plastic PET bottle with Different Geometries and Numbers of Rib (리브 형상 및 개수에 따른 사각플라스틱 페트병의 강성보강에 관한 연구)

  • Young-Hoon Lee;Bum-Jin Park;Eui-Chul Jung;Jung-Gil Oh;Seok-Guwan Hong
    • Design & Manufacturing
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    • v.17 no.4
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    • pp.33-41
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    • 2023
  • Excessive use of plastic bottles contributes to a significant environmental issue due to the high volume of plastic waste generated. To address this, efforts are needed to reduce the weight of plastic bottles. However, indiscriminate weight reduction may compromise the essential rigidity required for plastic bottles. Extensive research on rib shape for pressure vessels are exists, but there is a few research of rib shapes to enhance the stiffness of plastic bottles. The following results were obtained from the analyses conducted in this study. 1) Among the rib cross-sections of square, trapezoid, and triangle, the buckling critical load of PET bottles with square-shaped ribs is improved by about 14% compared to the buckling critical load of PET bottles without ribs. 2) The buckling critical load is improved by about 18% when a square-shaped rib with an aspect ratio of 0.2 is applied, compared to the buckling critical load of the bottle without the rib. 3) When longitudinal and transverse square ribs were applied to the axial direction of the PET bottle, the buckling critical load was improved by about 32% and 58% compared to the buckling critical load of the PET bottle without ribs, respectively, indicating that applying longitudinal ribs is effective in reinforcing the stiffness of PET bottles. 4) When 14 transverse ribs were applied, the maximum improvement was about 48% compared to the buckling critical load of the plastic bottle without ribs. 5) When 3 longitudinal ribs were applied on each side, the maximum improvement was about 76% compared to the buckling critical load of the bottle without ribs. Therefore, it was concluded that for effective stiffness reinforcement of a 500ml square bottle with a thickness of 0.5mm, 3 square-shaped ribs with an aspect ratio of 0.2 should be applied in the longitudinal direction relative to the axial direction of the bottle.

Catalytic degradation of waste plastics over solid acid catalysts (고체 산촉매에서 폐플라스틱의 분해 반응)

  • 이경환;전상구;김광호;노남선;신대현;서영화
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2002.11a
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    • pp.185-186
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    • 2002
  • 폐 플라스틱은 석유 물질인 탄화수소로 구성하고 있지만 효과적으로 재활용되지 못하고 대부분 매립, 소각 등의 방법으로 처리하고 있다. 플라스틱은 다양한 용도로 사용되기 때문에 플라스틱의 이용과 소비의 증가는 필연적이다. 예로 미국 가정의 폐 플라스틱은 63% 폴리에틸렌, 11% 폴리프로필렌, 11% 폴리스타이렌, 7% PET 그리고 7% PVC가 발생되는데 이들 화합물 구조가 포화탄화수소형이기 때문에 70% 정도가 방향족 화합물인 석탄에 비해 수소첨가 반응이 요구되지 않는다.(중략)

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Compatibilization of PET/LDPE Blends

  • Park, Young-Ok;Park, Chang-Nam;Lee, Moo-Sung
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.04a
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    • pp.63-66
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    • 1998
  • The steady growth in the use of plastic materials in packaging applications has caused an increasing concern about the environment and the problem of solid waste disposal. Therefore, the recycling of plastics is the very important problem, which must be solved technically and environmentally [1]. It is technically feasible to recycle, recover and reuse all of the plastics discarded, but economics limit the degree of recycling at this time.(omitted)

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