• 한국지반공학회:학술대회논문집
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• 한국지반공학회 1999년도 봄 학술발표회 논문집
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• pp.521-528
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• 1999

As the size of our industry and population inclose, the byproducts such as municipal solid wastes, industrial wastes are in the increasing phase. The treatment of such things is rising as a social problem. Today, the final disposal of these wastes depends mostly on the landfill, and the sanitary landfill is required and designed for preventing soil and groundwater contamination. Clays have been used for a liner material of a sanitary landfill, however, the high quality clay is hard to come by and quite expensive as a lining material in our country. Using the waste lime produced abundantly every year from chemical processes was studied here, made from the proper mixing of the bentonite and the waste lime meets the regulations from the USEPA. The soil property index tests (sieve analysis, specific gravity test Atterberg limit test) were performed, and at last to confirm the sorption characteristics of the bentonite and the waste lime the sorption isotherm equilibrium test and the sorption isotherm were performed with Toluene and Ethylbenzene which are the main components of the leachate from the landfill.

• 한국산학기술학회논문지
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• 제7권4호
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• pp.709-714
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• 2006

본 연구는 폐기물로 발생되는 부산석회 Core를 연속식 칼럼에 적용하여 수중의 인산염을 효과적으로 제거할 수 있는 방안을 찾고자 수행되었다. 부산석회와 인산염의 칼럼 반응에서 Hydroxyapatite을 형성하여 수중의 인산염을 제거할 수 있는 것으로 나타났으며 부산석회 Core size 1, 2에서 유입수의 인산염 농도에 관계없이 초기 11시간동안 90% 이상의 높은 제거율을 보였다. 또한 부산석회 Core size와 관계없이 유입수 유량이 증가할수록 파과시간이 줄어드는 것을 알 수 있었다.

• 상하수도학회지
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• 제19권2호
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• pp.125-134
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• 2005

Waste concrete powder was used to remove fluoride ions in highly concentrated fluoride wastewater. 92.6% of fluoride in 100 mg F/L wastewater was removed by 1% dose of the cement paste powder that represents characteristics of waste concrete powder, whereas the removal efficiencies of raw cement and lime were 47.3% and 96.4%, respectively. The cement paste powder was competitive to lime, common fluoride removal agent. Various Ca-bearing hydrates such as portlandite, calcium silicate hydrate, and ettringite in cement paste slurry can remove fluoride by precipitating $CaF_2$ and absorbing $F^-$ ions. In the experiments using both cement paste and lime, 50~67% of lime can be substituted by cement paste to satisfy fluoride effluent limitation of 15 mg/L. Since cement paste has higher acid neutralization capacity than lime, it can be recycled to neutralize more acid and to remove more fluoride. Therefore waste concrete powder can be more economical and viable alternative for lime in fluoride wastewater treatment.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 1997년도 총회 및 춘계 학술발표회 논문집
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• pp.70-73
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• 1997

산업폐기물의 재활용은 정부가 적극적으로 권장하고 있다. 폐석회의 비중, 건조단위중량. 일축 압축강도, pH, 투수계수 등의 지반특성을 실내시험결과를 고찰함으로써 폐석회가 매립장에서 인공차수재 및 복토재로 사용 가능성을 평가한다. 폐석회를 몇가지 환경실험을 통해서 그 결과를 EPA기준과 비교하였다. 본 논문에서는 실내실험을 수행한 결과를 전술하였고, 실험결과 분석에 의하면 혼합토(폐석회/화강풍화토)가 위생매립장의 인공차수재로 가능성이 있다고 판단된다.

• 환경위생공학
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• 제12권1호
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• pp.39-48
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• 1997

The study was conducted to know the possibility that the removal efficiency of organic and suspended solids(SS) could be increased by suppling of sea water and the optimum amount of sea water to be supplied treat bleaching waste water by lime coagulation settlement at pulp mill process. When the lime dosage was increased, the removal efficiency of COD and SS in the waste water was increased based on the removal efficiency of COD and SS. The lime dosage and removal efficiency was increased proportionally with the lime concentration of 4,000 mg/l, but the increase of removal efficiency was presented slightly above the 4,000mg/l. It was evaluated that the removal efficiencies of COD and SS could be increased and the requirement of lime dosage could be decreased by the sea water supplement. The removal efficiency of SS was most increased when the sea water supplement was 10% or more in the waste water. The removal efficiencies of COD was the best at 4% sea water excepting the dilution efficiency by sea water supplement.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
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• pp.48-58
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• 2004

Objectives of this research were to reclaim the coal mine overburdens using the lime waste cake from the soda ash production by stabilizing the overburden slopes, introducing neutralizing the AMD from runoff and leachate in an attempt find the sink to dispose the lime wastes and alleviate the environmental problems caused by the closed coal mines. The pH changes of the runoff and leachate collected in the tanks at the end of the experimental plots, averaged over measurements from April to August, indicated that the runoff pH of the coal overburden was 4.3 but increased significantly to the ranges of 6.7 to 7.1 with treatments of tile calcites and lime wastes. This might be related with the decreases in Fe concentrations in the runoff and leachate from the coal overburdens. The Fe concentrations in tile runoff seemed to increase with the amounts of precipitation. Results demonstrated that the amounts of lime wastes at 25% of the lime requirement were sufficient for neutralizing the acidic coal overburden. Either layering between the coal waste and topsoil or mixing with coal overburdens could be adopted as the lime waste treatment method. The lime wastes from the soda ash production might have a potential to be recycled for the reclamation of the abandoned coal mines to alleviate the environmental problems associated with coal mine waste.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2005년도 INTERNATIONAL SYMPOSIUM ON SOIL & GROUNDWATER ENVIRONMENT
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• pp.59-61
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• 2005

In Korea, hundreds of abandoned and closed coal and metallic mines are present in the steep mountain valleys due to the depression of the mining industry since the late 1980s. From these mines, enormous amounts of coal waste were dumped on the slopes, which causes sedimentation and acid mine drainage (AMD) to be discharged directly into streams causing detrimental effects on soil and water environments. A limestone slurry by-product (lime cake) is produced from the Solvay process in manufacturing soda ash. It has very fine particles, low hydraulic conductivities ($10^{-8}{\sim}10^{-9}cm/sec$), high pH, high EC due to the presence of CaO, MgO and $CaCl_2$ as major components, and traces of heavy metals. Due to these properties, it has potential to be used as a neutralizer for acid-producing materials. A field plot experiment was used to test the application of lime cake for reclaiming coal wastes. Each plot was 20 x 5 m (L x W) in size on a 56% slope. Treatments included a control (waste only), calcite ($CaCO_3$), and lime cake. The lime requirement (LR) for the coal waste to pH 7.0 was determined and treatments consisted of adding 100%, 50%, and 25% of the LR. The lime cake and calcite were also applied in either a layer between the coal waste and topsoil or mixed into the topsoil and coal waste. Each plot was hydroseeded with grasses and planted with trees. In each plot, surface runoff and subsurface water were collected. The lime cake treatments increased the pH of coal waste from 3.5 to 6, and neutralized the pH of the runoff and leachate of the coal waste from 4.3 to 6.7.

• 한국지반신소재학회논문집
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• 제21권2호
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• pp.1-9
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• 2022

최근 환경적 문제로 공유수면 매립사업이 감소추세에 있으나 매립사업의 특성상 일률적인 지표로 환경성을 평가하는 데 한계가 있다. 이 연구에서는 공유수면 매립지의 토질역학적 침하거동 인자를 활용하여 폐석회 매립시설의 침하 안정성을 분석하였다. 1차 압밀특성 인자로부터 폐석회는 압밀이 진행중인 점토특성과 유사함을 확인하였다. 매립지 지층을 얇은 토목섬유 보강재로 보강된 층상구조로 가정하고, Westergaard 방법에 따른 응력증가량을 이용하여 침하량을 예측하였다. 압밀도에 따른 침하량을 예측한 결과 연약지반의 표층이 토목섬유로 보강된 경우 보강되지 않은 경우보다 응력증가량이 40% 감소하는 것으로 나타났다. 또한, 폐석회의 소성지수와 내부마찰각의 상관관계를 이용하여 점토와 폐석회의 압밀거동 특성을 비교하였다. 공유수면 매립지내 폐석회는 압밀이 진행중인 상태이므로 장기적으로 침하는 더 증가하는 경향을 보일 것으로 예측되었다.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 1997년도 봄 학술발표회 논문집
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• pp.153-160
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• 1997

• 지질공학
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• 제25권4호
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• pp.547-555
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• 2015

연구에서는 부산물석회 혼합토를 이용하여 조성된 시험성토체에 대한 지반공학적 특성에 대하여 고찰하였다. 연구에 사용한 부산물석회는 인천의 화학공장에서 소다회(Na₂CO₃)를 생산하는 공정에서 부수적으로 발생하는 부산물이다. 현장조성 후 3년이 경과된 후에 시험성토체를 대상으로 현장밀도, 평판재하시험, 동적콘관입시험, 현장 CBR시험을 수행하였다. 시험결과로부터 성토재료로써의 부산물석회 혼합토의 지반공학적 특성이 제시되었다.