• Journal of Biosystems Engineering
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• v.25 no.3
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• pp.221-226
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• 2000

Hot air heater with light oil burner is the most common heater for greenhouse heating in the winter season in Korea. However, since the thermal efficiency of the heater is about 80∼85%, considerable unused heat amount in the form of exhaust gas heat discharges to atmosphere. In order to capture this exhaust heat a heat recovery system for plant bed heating in the greenhouse was built and tested in the hot air heating system of greenhouse. The heat recovery system is made for plant bed or soil heating in the greenhouse. The system consisted of a heat exchanger made of copper pipes, ${\Phi}12.7{\times}0.7t$ located in the rectangular column of $330{\times}330{\times}900mm$, a water circulation pump, circulation plastic pipe and a water tank. The total heat exchanger area is 1.5$m^2$, calculated considering the heat exchange amount between flue gas and water circulated in the copper pipes. The system was attached to the exhaust gas path. The heat recovery system was designed as to even recapture the latent heat of flue gas when exposing to low temperature water in the heat exchanger. According to the performance test it could recover 45,200 to 51,000kJ/hr depending on the water circulation rates of 330 to $690\ell$/hr from the waste heat discharged. The exhaust gas temperature left the heat exchanger dropped to $100^{\circ}C$ from $270^{\circ}C$ by the heat exchange between the water and the flue gas, while water gained the difference and temperature increased to $38^{\circ}C$ from $21^{\circ}C$ at the water flow rate of $690\ell$/hr. By the feasibility test conducted in the greenhouse, the system did not encounter any difficulty in operations. And, the system could recover 220,235kJ of exhaust gas heat in a day, which is equivalent of 34% of the fuel consumption by the water boiler for plant bed heating of 0.2ha in the greenhouse.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.13 no.3
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• pp.201-209
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• 2015

Currently, 23 nuclear power plants are in operation at Kori, Uljin, Younggwang and Wolsong site and a reference deep geological disposal system has been developed for the spent fuels generated by them. The reference spent fuel for this disposal system has 4.5wt% of initial enrichment, 55 GWd/MtU of burn-up, and 40 years of cooling time. In this paper, to improve disposal efficiency and economic feasibility, the characteristics of spent fuels from nuclear power plants, such as type and burn-up, were reviewed. A disposal canister concept for shorter length and relatively lower burn-up spent fuels than the reference spent fuels was developed. Based on this canister concept, thermal analyses were carried out and a deep geological disposal concept was proposed. Measures of disposal efficiency such as unit disposal area and disposal density were compared between this disposal system and the reference disposal system. Also, economic feasibility, such as the volume reduction of copper, cast iron, and bentonite, was analyzed and the results of these analyses showed that the disposal system proposed in this paper has an efficiency of at least 20%. These results could be used for establishing spent fuel management policy and designing practical disposal systems for spent fuels.

• Resources Recycling
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• v.10 no.5
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• pp.29-35
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• 2001

This study was carried out to recover gold, silver and valuable metals from the printed circuit boards (PCBs) of waste computers. PCBs samples were crushed under 1 mm by a shredder and separated into 30% conducting and loft nonconducting materials by an electrostatic separator. The conducting materials contained valuable metals which were then used as feed materials for magnetic separation. 42% of magnetic materials from the conducting materials was removed by magnetic separation as nonvaluable materials and the others, 58% of non magnetic materials, was used as leaching samples containing 0.227 mg/g Au and 0.697 mg/g Ag. Using the materials of leaching from magnetic separation, more than 95% of copper, iron, zinc, nickel and aluminium was dissolved in 2.0M sulfuric acid solution, added with 0.2M hydrogen peroxide at $85^{\circ}C$. Au and Ag were not extracted in this solution. On the other hand, more than 95% of gold and 100% of silver were leached by the selective leaching with a mixed solvent (0.2M($NH_4$)$_2$$S_2$$O_3$,0.02M $CuSO_4$,0.4M $NH_4$OH). Finally, the residues were reacted with a NaCl solution to leach Pb whereas sulfuric acid was used to leach Sn. Recoveries reached 95% and 98% in solution, respectively.

• Economic and Environmental Geology
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• v.33 no.2
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• pp.91-100
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• 2000

It has been more than ten years since Dukun mine was abandoned. Tailings of waste deposits and slime dumps in the abandoned Dukum mine have been left to be deserted for fifty years. The results of fifty years of neglecting are nothing short of major environmental problems. Slime dumps have been exposed to air and water in the mine over ten years and then soil profile has been formed well. Soil in the upper layer (A horizon) is the light gray color due to the leaching of cations. Soil in the lower layer (A2 horizon, 0.2∼0.3m)is tinted with reddish brown and yellowish brown color due to the development of iron oxides and iron hydroxides. Soil in the lower part of B horizon of (1.0∼3.0m) with the growth of copper and zinc oxides exposes to the bluish green, light blue, and dark gray. Ranging from 3m to 8m in depth, 85 samples were taken from 22 sampling sites with 50m intervals located on the slime dump area with hand auger and trench (open cut). As tailings was distributed, heavy metal elements extracted by the process of surface water and ground water move and disperse in to the hydrosphere. Waste dumps were distributed in and around the mine and water draining from those dumps be a potential source of contamination. Soils, thus, can be dispersed into downslope and downstream through wind and water by clastic movement. These materials may be deposited in another horizon if the water is withdrawn, or if the materials are precipitated as a result of differences in pH, or other conditions in deeper horizons. These were primarily associated with acid mine drainage. The characteristics and rate of release of acid mine drainage are influenced by various chemical and biological reactions at the source of acid generations. Prolonged extration of heavy metal elements has a detrimental effect on the agricultural land and residental area. Twenty soil samples were collected from the agricultural land in the area (0∼30 cm). Seventeen samples were also taken from the sediment in the stream running alongside the dumps. The dispersion patterns of heavy metal elements are as follows: The content of As ranged 2∼6 ppm in a horizon, 20∼125 ppm in B horizon with large amount of clay mineral is concentrated and the content of Cd ranged 1∼2 ppm in A horizon, 4∼22 ppm in B horizon. Like Cd, the content of As, Cu, Zn, Pb in B horizon is higher than that in A horizon (approximately 5∼100 times). When soil formation proceeds in stages, it is necessary to investicate the B horizon with the concentration of heavy metal and preventive measures will have to established.

• Journal of the Korean Society of Marine Environment & Safety
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• v.22 no.5
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• pp.583-592
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• 2016

IMO (International Maritime Organization) in the UN (United Nations) set up that aim at reducing $CO_2$ emission from ship by up to 30 percent until 2030. The final purpose of this study is the development of marine thermoelectric generation system using waste heat from vessel of internal combustion engines. Before the development of marine thermoelectric generation system, this paper carried out the fundamental heat analysis of marine thermoelectric generation system. It was able to obtain the valuable results about the efficiency improvement of the thermoelectric generation system. The results is as follows : 1) It was confirmed that the efficiency of thermoelectric generation system improves to 8.917 % with increasing the temperature difference of peltier module by reducing the temperature difference between peltier module and heat source at the hot side. 2) System efficiency according to change in the external load resistance was confirmed that the change width of about 6 % which does not significantly occur. 3) System efficiency in the case stainless steel at the same condition is 8.707 %. System efficiency could be confirmed that the stainless steel is higher than duralumin (8.605 %), copper (8.607 %).

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.3 no.4
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• pp.329-333
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• 2005

To identify the effect of engineered barriers on the leach rate of cesium from spent PWR fuel under a synthetic granitic groundwater, the related leach tests with and without bentonite or metals have been performed up to about 6 years. The leach rates were decreased as a function of leaching time and then became a constant after a certain period. The period in a bare spent fuel was much longer than that with bentonite or metal sheets. The cumulative fraction of cesium released from the spent fuel with bentonite or with copper and stainless steel sheets was steadily increased, but the fraction from bare fuel was rapidly and then sluggishly increased. However, the values deducted its gap inventory from the cumulative fraction of cesium released from the bare fuel was almost very close to the others. These suggest that the initial release of cesium from bare fuel might be dependant on its gap inventory and the effect of engineered barriers on the long-term leach rate of cesium would be insignificant but the rate with engineered barriers could be reduced in the initial transient period due to their retardation effect. And the long-term leach rate of cesium from spent fuel in a repository would be approached to a constant rate of $2\times10^{-2}g/m^2-day$.

• International Journal of Industrial Entomology and Biomaterials
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• v.18 no.2
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• pp.97-103
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• 2009

Sericulturists in the vicinity of Bangalore city irrigate their mulberry gardens with Vrishabhavathy stream water, which is polluted with domestic and industrial wastes from the city. To investigate the effect of pollutants on silkworm crops, a detailed field survey was conducted to study the cocoon yield pattern of the crops raised on mulberry irrigated with wastewater as against irrigation by bore/open wells. The villages along the stream were grouped into five test batches at about a distance of $5{\sim}8$ km from each other. The seasonal yield data with relevant information were collected through questionnaires from 117 rearers using stream water and 35 rearers using bore/open wells, the latter serving as control group. The average yield for 100 layings was 46 to 57 kg in the control group whereas in test groups, it ranged between 34 to 51 kg in the first test group and 22 to 38 kg in the rest. The difference in yield was $9{\sim}19$ kg depending on the season between control and test batches. In summer, this difference was higher, with high co-efficient of variation in test groups ($33{\sim}52$%). Further, water, soil and leaf samples were collected from selected rearers and were analyzed for zinc, copper, iron, lead and nickel. Results indicated significantly higher contents of these metals in samples from gardens using wastewater when compared control samples. Significantly (p<0.05 & p<0.01)) higher levels of zinc ($24{\sim}122$ ppm) and iron ($208{\sim}683$ ppm) were noticed in mulberry leaves during summer followed by winter and rainy season. The significance of high content of heavy metals in mulberry leaves and cocoon yield pattern of this area in relation to the quality of irrigation water is discussed.

• Korean Journal of Soil Science and Fertilizer
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• v.47 no.6
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• pp.391-397
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• 2014

Acid mine drainage occurrence is a serious environmental problem by mining industry; it usually contain high levels of metal ions, such as iron, copper, zinc, aluminum, and manganese, as well as metalloids of which arsenic is generally of greatest concern. It causes mine impacted soil pollution with mining and smelting activities, fossil fuel combustion, and waste disposal. In the present study, three bacterial strains capable of producing urease were isolated by selective enrichment of heavy metal contaminated soils from a minei-mpacted area. All isolated bacterial strains were identified Sporosarcina pasteurii with more than 98% of similarity, therefore they were named Sporosarcina sp. KM-01, KM-07, and KM-12. The heavy metals detected from the collected mine soils containing bacterial isolates as Mn ($170.50mg\;kg^{-1}$), As ($114.05mg\;kg^{-1}$), Zn ($92.07mg\;kg^{-1}$), Cu ($62.44mg\;kg^{-1}$), and Pb ($40.29mg\;kg^{-1}$). The KM-01, KM-07, and KM-12 strains were shown to be able to precipitate calcium carbonate using urea as a energy source that was amended with calcium chloride. SEM-EDS analyses showed that calcium carbonate was successfully produced and increased with time. To confirm the calcium carbonate precipitation ability, urease activity and precipitate weight were also measured and compared. These results demonstrate that all isolated bacterial strains could potentially be used in the bioremediation of acidic soil contaminated by heavy metals by mining activity.

• Environmental Engineering Research
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• v.10 no.5
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• pp.205-212
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• 2005

The study was conducted to investigate the removal of heavy metals by using Hydroxyapatite(HAp) made from waste oyster shells and wastewater with high concentration of phosphorus. The maximum calcium concentration for the production of HAp in this study was released up to 361 mg/L at pH of 3 by elution experiments. When the pH was at adjusted 6, the maximum calcium released concentration was 41 mg/L. During the elution experiment, most of the calcium was released within 60 minutes. This reaction occurred at both pH levels of 3 and 6. The result of the XRD analysis for the HAp product used in this study shows the main constituent was HAp, as well as OCP. The pH was 8.6. As the temperature increased, the main constituent did not vary, however its structure was crystallized. When the pH was maintained at 3, the removal efficiency decreased as the heavy metal concentration increased. The order of removal efficiency was as follows: $Fe^{2+}$(92%), $Pb^{2+}$(92%) > $Cu^{2+}$(20%) > $Cd^{2+}$(0%). Most of these products were dissolved and did not produce sludge in the course of heavy metals removal. As the heavy metal concentration increased at pH of 6, the removal efficiency increased. The removal efficiencies in all heavy metals were over 80%. From the analysis of the sludge after reaction with heavy metals, the HAp was detected and the OCP peak was not observed. Moreover, lead ion was observed at the peaks of lead-Apatite and lead oxidant. In the case of cadmium, copper and iron ions, hydroxide forms of each ion were also detected.

• Environmental Analysis Health and Toxicology
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• v.28
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• pp.17.1-17.3
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• 2013

The fact that hazardous metals do not bio-degrade or bio-deteriorate translates to long-lasting environmental effects. In the context of evidently rapid global industrialization, this ought to warrant serious caution, particularly in developing countries. In the Republic of Fiji, a developing country in the South Pacific, several different environmental studies over the past 20 years have shown levels of lead, copper, zinc and iron in sediments of the Suva Harbor to be 6.2, 3.9, 3.3 and 2.1 times more than the accepted background reference levels, respectively. High levels of mercury have also been reported in lagoon shellfish. These data inevitably warrant thorough assessment of the waste practices of industries located upstream from the estuaries, but in addition, an exposure and health impact assessment has never been conducted. Relevant government departments are duty-bound, at least to the general public that reside in and consume seafood from the vicinities of the Suva Harbor, to investigate possible human effects of the elevated hazardous metal concentrations found consistently in 20 years of surface sediment analysis. Furthermore, pollution of the intermediate food web with hazardous metals should be investigated, regardless of whether human effects are eventually confirmed present or not.