• Journal of Energy Engineering
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• v.5 no.1
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• pp.56-64
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• 1996

The objective of this investigation is to establish the rejection characteristics of caesium and cobalt from radioactive liquid waste by chemical/ultrafiltration process. An extensive experimental investigation was conducted with inactive caesium and cobalt ions, utilizing ultrafiltration stirred cell. Caesium and cobalt could be effectively removed from waste solution using copper ferrocyanide and polyarcylic acid(PAA). The rejection dependence of the caesium was found to be a function of caesiun to potassium copper ferrocyanide feed molar ratio. The binding behavior of caesium on K$_2$Cu$_3$(Fe(CN)$\sub$6/)$_2$, particles was explained in terms of a Langmuir adsorption isotherm. When Cs/K$_2$Cu$_3$(Fe(CN)$\sub$6/)$_2$molar ratio was 1.5, the removal of caesium was the most efficient. The rejection efficiency of cobalt is dependent upon various parameters such as pH, cobalt concentration and PAA concentration. The rejection behavior of cobalt was explained in term of a equilibrium model taking into account the reaction between the ligand group, the proton and the cobalt ion. At the conditions of PAA/Co ratio of 2 and pH of 5.6, the removal of cobalt was over 90%. Also, the effect of chemical addition sequence for the simultaneously removal of caesiun and cobalt was discussed.

• Economic and Environmental Geology
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• v.29 no.1
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• pp.45-55
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• 1996

Although the Dongjin Au-Ag-Cu mine had been abandoned since about forty years ago, the results of this study on the dispersion patterns and contamination level of heavy metals in the hydrologic system flowing via the waste rump show that the environmental impacts from the mine wastes are still significant. The stream water in the vicinity of the waste rump is severely acidified (pH 3.8 to 4.4) and highly enriched in various dissolved heavy metals. The heavy metal contents of the stream water and stream sediments are systematically attenuated with increasing distance from the mine area. However, it is worth to note that continuous attenuation of heavy metal contents in both media were reenriched in downstream area more than 800 m apart from the mine because it can be acted as a secondary source of heavy metal pollution. The heavy metals, especially Cd, Cu and Zn of polluted downstream sediments mainly occur in Fe-Mn oxides and organic materials, which indicates that these elements are the main pollutants from the waste rump of the Dongjin mine. The heavy metal contents of crops, such as sesame, perilla, red Pepper and brown rice, collected from the polluted farm land in the downstream area are lower than those of land plants from stream sides, but significantly higher in Cd, Cr, Cu and Zn than those from the unpolluted farm land. Especially, almost all of the crops in polluted farm land have been severly contaminated by Cd (>0.4 ppm). On the other hand, the heavy metal contents of the crops collected from refreshed farm land by means of a soil addition method shows significantly lowered level comparing with those of polluted area, which indicates that a soil addition method was effective for the refreshment of polluted farm land by toxic metallic pollutants. Wormwoods from this area showed very high contents in a11 the heavy metals even in unpolluted area (Cd > 1 ppm, Cr > 1 ppm, Cu > 11 ppm, Pb> 4 ppm, Zn > 55 ppm), indicating that a special caution must be payed when one takes ingest them.

• Clean Technology
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• v.21 no.2
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• pp.108-116
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• 2015

Hydrogen sulfide and ammonia are one of the common malodorous compounds that can be found in emissions from many sewages treatment plants and industrial plants. Therefore, removing these harmful gases from emissions is of significance in both life and industry because they can cause health problems to human and detrimental effects on the catalysts. In this work, pyrolytic carbon blacks from waste tires were used to develop adsorbent with good adsorption capacity for removal of hydrogen and ammonia. Pellet-type adsorbents were prepared by a mixture of carbon black, metal oxide and sodium hydroxide or hydrochloric acid, and their adsorption capacities were estimated by using breakthrough curve of a continuous fixed bed adsorption column at ambient condition. The adsorbent manufactured with a mixture of carbon black, iron oxide(III) and sodium hydroxide showed the maximum working capacity of hydrogen sulfide. For ammonia, maximum working capacity was obtained by the adsorbent manufactured with a mixture of carbon black, copper oxide(II) and hydrochloric acid.

• Journal of Korea Foresty Energy
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• v.23 no.2
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• pp.29-33
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• 2004

This study was carried out to find out safety disposal methods of waste CCA treated wood. The heavy metals of remnant were analyzed after combustion of CCA treated wood at different temperatures. Arsenic volatilized temperature was detected. The removal rate of heavy metals by acid in the ash were examined. Through this study, we could conclude that in order to protect volatilize arsenic, combustion of CCA treated wood should be do under the $300^{\circ}C$. But when CCA treated wood combustion under $300^{\circ}C$, it's weight-loss rate was $55\%$, so land reclamation dependence will be increased. When CCA treated wood combustion at high temperature, the land reclamation dependence could be reduced, but the arsenic that volatilize into the atmosphere should be captured. When it bums with high temperature, the ash contains lots of copper and chromium, so removal of heavy metals should be conducted.

• Resources Recycling
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• v.25 no.3
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• pp.37-42
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• 2016

Highly efficient and environmentally friendly mechanical process was developed for the higher recovery rate and productivity in the recycling of waste jelly-filled communication cables. Only the simplest mechanical method was designed and built for a continuous process, further proved experimentally along with the addition of several parts such as brush-type rollers and scrappers. In this process, the recovery rate and productivity were 98% and 55 Kg/hr respectively. This process is thought to be simple but highly advanced method for the commercialization of green process.

• Resources Recycling
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• v.26 no.2
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• pp.33-38
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• 2017

Waste can be utilized as secondary or alternative fuel. Solid recovered fuel (SRF) and dried sewage sludge were combusted to investigate heavy metal emissions from their combusiton in this study. Content of copper (Cu), chromium (Cr), cadmium (Cd), nickel (Ni), zinc (Zn), lead (Pb), arsenic (As) and mercury (Hg) of coal, SRF and dried sewage sludge were determined, respectively. Concentrations of these heavy metals in the combustion flue gas were also determined. As a result, emissions of gas-phase Cu, Cr, Cd, Ni, Zn, Pb and As compounds were found to be little. However, a significant amount of gas-phase Hg was emitted from combustion of coal, SRF and dried sewage sludge. While SRF showed a high mercury oxidation percentage in its combustion flue gas, dried sewage sludge showed a high level of gaseous mercury emission.

• Korean Journal of Soil Science and Fertilizer
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• v.33 no.2
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• pp.109-113
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• 2000

The purpose of this study was conducted to develop the slow-released N fertilizer(SRNF) using of waste paper cellulose. Properties of trial product was investigated. Contents of nitrogen, phosphorus, and potassium in trial product were showed 26%, 0.04 and 0.01%, respectively. The contents of Cr, Cu, Pb and Zn were showed 17.4ppm. 259ppm, 12.2ppm and 60.0ppm in the trial product, respectively. However, As and Cd was not detected. Nitrogen of SRNF could be released 60.4% within 12hr after dissolution in water. However, the releasing velocity was thereafter remarkably delayed, showing 75% after dissolution for 72hr.

• Resources Recycling
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• v.26 no.4
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• pp.9-18
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• 2017

Recently, the amount of electronic scrap is rapidly increasing due to the rapid growth of the electronics industry. Among the components of electronic scrap, the printed circuit board(PCB) is an important recycling target which includes common metals, precious metals, and rare metals such as gold, silver, copper, tin, nickel and so on. In Korea, however, PCB recycling technologies are mainly commercialized by some major companies, and other process quantities are not accurately counted. According to present situation, several urban mining companies, research institutes, and universities are conducting research on recovery of valuable metals from PCBs and/or reusing them as raw materials that is different from existing commercialization process developed by major companies. In this study, we analyzed not only current status of collection/disposal process and recycling of waste PCBs in Korea but also the trend of recycling technologies in order to help resource circulation from waste PCBs become more active.

• Resources Recycling
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• v.28 no.5
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• pp.30-41
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• 2019

Global production of zinc is about 13 million tons and zinc is the fourth-most widely used primary metal in the world following iron, aluminum and copper. When zinc is recycled to produce secondary zinc, it can save about 75 % of the total energy that is needed to produce the primary zinc from ore, and in therms of $CO_2$ emissions reduced by about 40 %. However, since zinc is mainly used for galvanizing of steel, the recycling rate of zinc is about 25 %, which is lower than other metals. The raw materials for recycling of zinc include dusts generated in the production of steel and brass, sludge in the production process of non-ferrous metals, dross in the melting of zinc ingots or hot dip galvanizing, waste batteries, and metallic scrap. Among them, steelmaking dust and waste batteries are most actively recycled up to now. Most of the recycling process uses pyrometallurgical methods. Recently, however, much attention has been given to a combined process of pyrometallurgical and hydrometallurgical processes.

• Clean Technology
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• v.29 no.4
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• pp.321-326
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• 2023

Recently, there has been a growing interest in clean hydrogen energy that does not emit carbon dioxide during combustion due to the increasing focus on carbon neutral. Research related to hydrogen production continues, and in this study, we applied waste-derived synthesis gas to the water-gas shift reaction to simultaneously treat waste and produce high-purity hydrogen. To enhance catalytic activity in the high-temperature water-gas shift (HT-WGS) reaction, magnesium was used as a support material alongside cerium. Cu-CeO₂-MgO catalysts were synthesized, with copper acting as the active component for the HT-WGS reaction. A study on the catalytic activity based on the preparation method was conducted, and the Cu-CeO₂-MgO catalyst prepared by impregnation method exhibited the highest activity in the HT-WGS reaction. The observed superior performance of the Cu-CeO₂-MgO catalyst prepared through the impregnation method can be attributed to its significantly higher oxygen storage capacity and amount of active Cu species.