• Title/Summary/Keyword: Waste Alkali

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Decomposition Characteristics of Non-Degradable Liquid Waste under High Temperature and High Pressure Conditions (고온 고압 조건에서의 난분해성 액상폐기물 분해 특성)

  • Lee, Gang-Woo;Shon, Byung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.8 no.6
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    • pp.1572-1578
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    • 2007
  • The specified wastes consist of waste acid, waste alkali, waste oil, waste organic solvent, waste resin, dust, sludge, infectious waste, and others. Among these specified wastes, a great portion is liquid phase wastes. The purpose of this study is to develop the high temperature and high pressure (HTHP) treatment system for decomposition of the liquid phase specified waste (LPSW). For this, we analyzed the physical and chemical properties of the LPSW such as density, proximate analysis, ultimate analysis, heating values, and designed 0.3 ton/day HTHP treatment system. The LPSW tested in this experiment were prepared by adding TCE(trichloroethylene) and toluene to liquid phase waste which was brought into the commercial waste treatment company. The average density of waste oil (25 samples), waste resin (5 samples), and waste solvent (12 samples) was 0.99 g/mL, 0.91 g/mL, and 0.93 g/mL, respectively. And the average lower heating value of waste oil, waste resin, and waste solvent was 8,294 kcal/kg, 5,809 kcal/kg, and 7,462 kcal/kg, respectively. The DRE (Destruction & Removal Efficiency) of TCE and toluene were 99.95% and 99.73% at atmospheric pressure conditions and that were 99.99% and 99.82% at pressurized conditions, respectively. These results showed that TCE/toluene mixtures were properly decomposed over about 99.73% of DRE by the HTHP treatment system and pressurized conditions were more effective to destroy those pollutants than atmospheric pressure conditions. Also these systems could be directly applied to industries which try to treat the liquid phase specified waste within the regulation limit.

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A Study on Development of a Liner Manufactured by Mine Wastes and Polymer (광산폐기물과 폴리머를 이용한 Liner 개발에 관한 연구)

  • 진호일
    • Economic and Environmental Geology
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    • v.33 no.2
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    • pp.139-146
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    • 2000
  • Development of an effective liner by utilization of the tailings frm the Imcheon mine and polymer has been tried. The tailings piled in the Imcheon mine, whose true specific gravity is about 2.86, are composed mainly of quartz, alkali-feldspar, muscovite and pyrite, and mostly (93.7% in volume) coarser than sand grain size (50${\mu}{\textrm}{m}$). Strength, leaching and permeability tests have been performed on the test specimens of polymer concrete manufactured with various mixing proportions of tailings, unsaturated polyester resins(UPR), calcium carbonates, stone powder sludges and granite soils. Polymer concrete specimens with stone powder sludges or granite soils as fillers and aggregates indicate 2.5 to 3 fold higher flexural and compressive strengths and lower permeabilities than those with calcium carbonates, which shows their usability as a waterproof liner. Also, the polymer concrete liner with stone powder sludge fillers is more advisable in aspects of utilization of waste sludges than that with other fillers.

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Chemical resistance of Non-Sintered Cement Mortar using Inorganic Industrial Wastes as activator (무기계 산업폐기물을 자극제로 이용한 비소성 시멘트 모르타르의 내화학성)

  • Mun Kyoung Ju;Lee Chol Woong;Park Won Chun;Soh Yang Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.607-610
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    • 2005
  • If cement can be manufactured with industrial byproducts such as granulated blast furnace slag(GBFS), phosphogypsum(PG), and waste lime(WL) instead of clinker as its counterproposal, there would be many advantages, including maximum use of these industrial byproducts for high value-added resources, conservation of natural resources and energy by omitting the use of clinker, minimized environmental pollution problems caused by $CO_2$ discharge, and reduction of the production cost. This research investigates the chemical resistance of NSC mortar added PG and WL to GBFS as sulfate and alkali activators. The result of experiment of chemical resistance, showed that NSC is very excellent in acid resistance and seawater resistanc. Such a reasons are that the hydrate like CSH gel and ettringite formed dense pore structure of NSC matrix.

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Chloride ion Permeability of Non-Sintered Cement Concrete using Inorganic Industrial Wastes as activator (무기계 산업폐기물을 자극제로 이용한 비소성 시멘트 콘크리트의 염소이온 침투 저항성)

  • Mun, Kyoung-Ju;Lee, Chol-Woong;Park, Won-Chun;So, Seung-Young;Soh, Yang-Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.453-456
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    • 2006
  • If cement can be manufactured with industrial byproducts such as granulated blast furnace slag(GBFS), phosphogypsum(PG), and waste lime(WL) instead of clinker as its counterproposal, there would be many advantages, including maximum use of these industrial byproducts for high value-added resources, conservation of natural resources and energy by omitting the use of clinker, minimized environmental pollution problems caused by CO2 discharge, and reduction of the production cost. This research investigates the chloride ion permeability of NSC concrete added PG and WL to GBFS as sulfate and alkali activators. The result of experiment of chloride ion permeability, showed that NSC is very excellent in seawater resistance. Such a reasons are that the hydrate like CSH gel and ettringite formed dense pore structure of NSC matrix.

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Neutralization and removal of heavy metal ions in Plating wastewater utilizing Oyster Shells (굴껍질을 이용한 도금폐수의 중화 및 중금속 이온 제거)

  • 성낙창;김은호;김정권;김형석
    • Journal of Environmental Health Sciences
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    • v.22 no.3
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    • pp.81-87
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    • 1996
  • The purpose of this research is to examine the utilization of oyster shells for neutralization and removal of heavy metal ions in plating wastewater, because oyster shells have been known to be very porous, to have high specific surface area and to have alkaline minerals such as calcium and magnesium. The results obtianed from this research showed that oyster shells had a buffer capacity to neutralize an acidic.alkali system in plating wastewater. Generally, it could be showed that the removal efficiencies of heavy metal ions were very influenced by reaction times and oyster shell dosages. In point of ocean waste, if oyster shells substituted for a valuable adsorbent such as actviated carbon, they could look forward to an expected economical effect.

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Extraction and Degradation of Alginate from Brown Seaweed Stem Using Microorganism (미생물을 이용한 미역줄기에서 알긴산염 추출 및 저분자화)

  • Ahn Seong-Jun;Kim Young-Sook;Park Kwon-Pil
    • Journal of Environmental Science International
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    • v.13 no.12
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    • pp.1139-1144
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    • 2004
  • We studied a extraction and degradation of alginate from seaweed-stems using microorganism DS-02. DS-02 has a maximum growth rate at $30^{\circ}C$ and the enzyme has a maximum activity of alginate extraction at $35^{\circ}C.$ The yield of alginate extraction using DS-02 is about $16.0{\%}$ for 3.0 hour and molecular weight of the alginate decreased to about 1/8 of initial value after 24 hour extraction. Alginate extraction method by DS-02, compared with general alkali-extraction method, has an advantage of decreasing the molecular weight of alginate during extraction.

Study on Mock-up test for field application of High Strength Concrete using Non-Sintered Cement (비소성시멘트를 사용한 고강도 콘크리트의 현장적용을 위한 모의부재에 관한 연구)

  • Kim, Han-Sik;Han, Da-Hee;Kim, Kwang-Ki;Paik, Min-Su;Mun, Kyoung-Ju;Jung, Sang-Jin
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.11a
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    • pp.33-36
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    • 2006
  • This Study is based on manufacture non-sintering cement(NSC) by adding phosphogysum and waste lime to GBFS as sulfate and alkali activators. This study also investigates the basic physical properties and duality of NSC, and evaluates its reusing possibility as construction materials. Therefore, we design 40MPa and 60MPa for compressive strength using OPC and NSC by binder. And There is a purpose to present fundamental data, applying in field and analyzing quality control of concrete using NSC according to rate of replace between OPC and NSC.

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Pore Structure of Non-Sintered Cement Matrix (비소성 시멘트 경화체의 공극구조)

  • Mun Kyoung-Ju;Park Won-Chun;Soh Yang-Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.329-332
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    • 2004
  • This study aims to manufacture non-sintering cement(NSC) by adding phosphogypsum(PG) and waste lime(WL) to granulated blast furnace slag(GBFS) as sulfate and alkali activators. This study also investigates the pore structure of NSC Matrix. The result of experiment of pore structure properties, showed no considerable difference for total pore volume by cement mixing ratio but shows a large distinction in distribution of pore diameter. On the whole, pore-diameter of paste of NSC show that occupation ratio of pore diameter below 10mm is larger and is smaller than OPC and BFSC at pore diameter of over 10nm. Such a reason is that the hydrate like CSH gel and ettringite formed dense pore structure of NSC matrix.

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pH Characteristics of the Recycled Aggregate Being carbonated by Dry Ice (드라이아이스로 탄산화 처리한 순환골재의 pH 특성)

  • Hong, Sung-Rog;Bok, Young-Jae;Sung, Jong-Hyun;Lee, Il-Sun;Kim, Jin-Man
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.05a
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    • pp.337-338
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    • 2013
  • Recent research is needed for the reduction of the pH of the recycled aggregates, recycled aggregates for alkali social problems have emerged. This was confirmed through preliminary experiments using a self-made reactor with dry ice, the possibility of reducing the pH of the recycled aggregates. The pH reduction of coarse recycled aggregates plant was made to apply the field to the middle of construction waste treatment process to reduce the pH of the plant room, and measured the pH change with time. The measurement results showed that dry ice after the reaction, the pH of the aggregate 5% reduction than untreated recycled aggregates.

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Preparation and Evaluation of Chitin Derivatives and Their Utilization for Waste-water Treatement

  • Aly, Aly Sayed;Jeon, Byeong-Dae;Kim, Young-Jun;Park, Yun-Heum
    • Proceedings of the Korean Fiber Society Conference
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    • 1996.10a
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    • pp.53-58
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    • 1996
  • The Chitin Thiocarbonate-Fe(II)-H2O2 redox initiator system was investigated for the graft copolymerization of acrylonitrile(AN) and acrylic acid(AA) monomers onto chitin powder. The reactions with vinyl monomers onto chitin were carried out under various the graft copolymerization conditions to elucidate the polymerization behavior in terms of graft yield. Reactions of chitin-acrylonitrile graft copolymer with hydroxyl amine hydrochloride and those with sodium hydroxide were conducted in order to obtain chitin-(amidoxime-co-acrylonitrile) and chitin-(acrylate-co-acrylamide) graft copolymers, respectively. The reaction efficiency was observed to depend on the alkali concentration, time, temperature, and the reactant concentrations. The prepared chitin derivatives were evaluated to find potential applications for use in wastewater treatments for adsorption and desorption of heavy metal ions as well as acidic and basic dyes.

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