• Title/Summary/Keyword: Washing agent

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Effect of Sonication and Reducing Agent Addition on Soil Washing of Heavy Metals-contaminated Soil (초음파 및 환원제 첨가가 중금속 오염토양의 토양세척에 미치는 영향)

  • Hwang, Seon-Suk;Park, Joon-Seok;NamKoong, Wan
    • Journal of Environmental Health Sciences
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    • v.33 no.1 s.94
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    • pp.75-81
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    • 2007
  • This research was conducted to estimate the effect of sonication and reducing agent addition on soil washing of heavy metals-contaminated soil. Sonication trained in soil washing did not significantly increased extraction efficiency of heavy metal compared to soil washing only. The extraction efficiency of sonication trained in soil washing was 12% increased for Pb in 0.01M EDTA leaching solution. Pb and Cd showed higher extraction efficiency in case of reducing agent treatment with mechanical shaking than that with sonication. However, the extraction efficiency of Cu and Zn in case of reducing agent treatment with sonication was over 2 times higher than that in with soil washing. Therefore, application of reducing agent addition with sonication or mechanical shaking should be decided differently for pretreatment of soil washing, according to the kind of heavy metal. It was estimated that sonication after adding reducing agent could increase removal efficiency of Zn or Cu-contaminated soil and shorten the treatment time.

A Study on the Decontamination Performance of Cesium by Soil Washing Process With Flocculating Agent (응집제를 적용한 토양세척 공정에서의 세슘 제염 성능 평가 연구)

  • Song, Jong Soon;Kim, Sun Il
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.1
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    • pp.41-47
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    • 2018
  • Radioactive substances, especially $^{137}Cs$ discharged in the course of Nuclear Power Plant Accident or maintenance of power plants, cause contamination of the soil. For habitation of residents and reuse of industrial land, it is inevitably necessary to decontaminate the soil. This study examines a soil washing process that has actually been used for washing of radioactive-contaminated soil. The soil washing process uses a washing agent to weaken surface tension of the soil and cesium, separating cesium from the soil. In this study, in order to raise the efficiency of the process, a flocculating agent was added to the washing water to remove fine soil and cesium. The cesium concentrations before and after applying the flocculating agent to cesium solution were measured through ICP-OES. When using 0.1 g of J-AF flocculating agent in the experiment, the maximum Cs removal performance was approximately 88%; the minimum value was 67%. Species combinations between cesium and soil were predicted using Visual MINTEQ Code; the ability to reuse the washing water or not, and the removal rate of the fine soil, determined via measurement of the turbidity after applying the flocculating agent, were determined.

Bactericidal Effect of Waterless Alcohol Gel Hand Washing Agent (물 없이 사용하는 알코올 젤의 손소독 효과에 관한 연구)

  • Jeong, Jae-Sim;Kim, Duck-Hee;Kim, Mi-Na;Choe, Myoung-Ae
    • Journal of Korean Biological Nursing Science
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    • v.4 no.2
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    • pp.127-137
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    • 2002
  • The purpose of this study was to compare the hand disinfection effect of waterless alcohol gel hand washing agent with that of soap and water, 4% chlorhexidine gluconate, and 10% povidone-iodine. Hands of fourty subjects were artificially contaminated with Acinetobacter baumannii $5m{\ell}$ and randomly distributed to each hand washing methods. Samples were collected from gloved hand by glove juice sampling procedure. Mean log reduction after hand washing were compared with baseline values. Number of microorganisms were converted to log and tested by ANOVA in SPSSWIN 10.0. Mean log reduction of soap and water, alcohol gel, 4% chlorhexidine gluconate, 10% povidone-iodine were $2.76{\pm}0.62$, $2.97{\pm}0.56$, $4.66{\pm}1.70$, $4.60{\pm}0.91$, respectively. The bactericidal effect of alcohol gel was similar to that of soap and water, but the effect was much less than chlorhexidine gluconate and povidone-iodine(p<0.001). In terms of microorganism reduction, the efficacy of waterless alcohol gel was almost the same as soap and water hand washing. Further evaluation of the bactericidal effect of waterless alcohol gel is needed because waterless alcohol gel is simple, convenient, and non-irritating hand washing agent and also very effective in busy hospital environment.

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A Study on the Pb-contaminated Soil Remediation by Organic Acid Washing (유기산을 이용한 납 오염토양의 복원에 관한 연구)

  • 정의덕
    • Journal of Environmental Science International
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    • v.9 no.5
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    • pp.437-441
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    • 2000
  • A study on the removal of Pb ion from Pb-contaminated soil was carried out using ex-site extraction process. Tartaric acid (TA) and iminodiacetic acid sodium salt(IDA) as a washing agent were evaluated as a function of concentration reaction time mixing ratio of washing agent and recycling of washing agent. TA showed a better extraction performance than IDA. The optimum washing condition of TA and IDA were in the ratio of 1:15 and 1:20 between soil and acid solution during 1 hr reaction. The total concentrations of Pb ion by TA and IDA at three repeated extraction were 368.8 ppm and 267.5 ppm respectively. The recovery of Pb ion from washing solution was achieved by adding calcium hydroxide and sodium sulfide form the precipitation of lead hydroxide and lead sulfide and optimum amounts of sodium sulfide and calcium hydroxide were 7 g/$\ell$ for the TA washing solution and 4 g/$\ell$, 5g/$\ell$ for the IDA washing solution respectively. The efficiency of recycle for TA and IDA washing solution were 78.8% , 95.1%, and 89.2%, 96.6% at third extractions under $Na_2S$ and $Ca(OH)_2$, respectively.

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The Detergency Improvement and Fabric Damage in the Washing Treatment by Commercial Bleaching Agents (시판표백제에 의한 농축세제의 세척성 향상과 섬유 손상)

  • 배정숙
    • Journal of the Korean Home Economics Association
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    • v.37 no.2
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    • pp.113-126
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    • 1999
  • In order to investigate the detergency effect of stained cotton and PET fabric, respectively, these fabrics stained with solid soils such as carbon black, liquid paraffin, and fat and examined the detergency effect in the optimum washing condition. The evaluation of washing efficiency of washed fabrics studied by using the surface reflectance measurement before and after washing treatment. The maximum detergency effect of stained cotton and PET fabric obtained in the mixed washing liquor-bleachig agen(ml)/concentrated washig agent(g/l). To obtain the excellent detergency effect, 2-step washing treatment, pre-washing by bleaching agent only and washing by concentrated detergent, is preferred. In comparing the detergency of polyester and cotton fabric, the detergency of stained polyester fabric superior than that of stained cotton fabric because of the difference of adhesive force between soil material and fabric in preparing soled stained fabric. In this study, we also studied the degree of fabric damage by the measurement of tensile strength change. From the results of the tensile strength measurement, the damage of washed fabric before and after washing treatment was nearly changed.

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Effect of Added Commercial Bleaching Agent in Detergency of Enzyme Mixed Deterging Agent (시판 표백제가 효소배합 세제의 세척성에 미치는 영향)

  • 배정숙
    • Textile Coloration and Finishing
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    • v.10 no.6
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    • pp.55-66
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    • 1998
  • In order to investigate the detergency effects of various detergents to stained polyester & cotton fabric with solid soils such as carbon black, liquid paraffin and fat, the optimum washing conditions according to the types of washing agent, the assesment of detergency effect by the measurement of reflectance after and before washing were studied. The detergency effect of various detergents to stained polyester and cotton fabric increased by using the mixtures of bleaching and enzyme detergent. In order to obtain the excellent detergency effect, 2-step treatment, the pre-washing with bleaching agent and bleaching-enzyme mixture detergent treatment is preferred. In comparison of the detergency to polyester and cotton fabric, it is assumed that the detergency to polyester stained fabric was superior than that to cotton stained fabric because of the difference of adhesive force between soil material and fabric in preparing solid stained fabric.

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Research with Statistical Model to Analyze Efficiency of Heavy Metal Soil Washing (통계학적 모델을 이용한 중금속 토양 세척의 효율 분석에 관한 연구)

  • Oh, Sangyoung;Yoo, Jongchan;Baek, Kitae;Kim, Hanseung;Park, Jaewoo
    • Journal of Soil and Groundwater Environment
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    • v.23 no.1
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    • pp.14-24
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    • 2018
  • In soil washing, there are many variables including types of reagent and contaminant, washing time, soil-liquid ratio, washing cycles, washing agent concentrations, and etc. To identify the most influencing factors on soil washing process, regression analysis was performed for eight single variables and five combined variables. A quantitative model that employs W/H (molar ratio of washing agent to heavy metal) as a major variable was established based on the regression. The validity of the model was demonstrated by conducting lab experiments with Cu, Pb, Zn, Ni and As-contaminated soils, and various washing reagents including acetic acid, citric acid, malic acid, oxalic acid, ethylenediamine tetraacetic acid (EDTA) and nitriloacetic acid (NTA). The washing efficiencies were compared with the EDTA washing data reported in the literature. The correlation between W/H and removal efficiency was analyzed after dividing data into two groups according to the heavy metal mobility.

Remediation of Oil Contaminated Soils by Rice Straw Ash (Rice Straw Ash를 이용한 유류오염토양 정화)

  • 정경원;장성호
    • Journal of Environmental Science International
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    • v.12 no.7
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    • pp.783-789
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    • 2003
  • This study was conducted to reuse the rice straw ash as washing agent for oil contaminated soils. The results are summarized as follows. The physical characteristics of rice straw before and after burning were as follows ; In case of burning rice straw 1g, the rice straw ash was generated 0.14g and pH was changed neutrality into alkali(pH 10.9) and specific surface area was increased to five times and particle distribution was corresponded to fine silt.(under 0.05mm) The physical characteristics of rice straw ash were Carbon 10.9%, Hydrogen 1.5%, Oxygen 23.4%, Nitrogen 5.2%, Sulfate 1.2% and chemical characteristics were Si 189.2ppm, Ca 10.2ppm, Mg 4.7ppm. Oil cleanup ratio by pH variation were about 40∼50% of initial concentration of oil by pH 10∼11. As the result of cleanup comparative experiment, the rice straw ash was about 20∼30%, the tritonX-100 about 40∼50% of washing efficiency, and then in the future it will be possibility of substitute washing agent.

Characteristics of Agricultural Paddy Soil Contaminated by Lead after Bench-scale In-situ Washing with FeCl3 (납 오염 논토양의 원위치 세척을 위한 FeCl3의 Bench-scale 적용성 평가: 세척전후 토양 특성변화)

  • Koh, Il-Ha;Kim, Gi Suk;Chang, Yoon-Young;Yang, Jae-Kyu;Moon, Deok Hyun;Choi, Yulim;Ko, Myoung-Soo;Ji, Won Hyun
    • Journal of Soil and Groundwater Environment
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    • v.22 no.1
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    • pp.18-26
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    • 2017
  • In a previous study, we assessed the feasibility of ferric chloride ($FeCl_3$) as a washing agent in bench-scale in-situ soil washing to remove Pb from agricultural paddy soil. Herein is a subsequent study to evaluate variations in soil properties after $FeCl_3$ soil washing in terms of fractionation and bioavailability of Pb and chemical properties of the soil. After soil washing, the soil pH decreased from 4.8 to 2.6 and the exchangeable fractions of Pb in the soil increased from 12 mg/kg to 15 mg/kg. Variations in the Pb fractionation of the soil increased Pb bioavailability by almost three-fold; however,the base saturation decreased by 75%. The concentrations of total nitrogen and available phosphate were similar before and after soil washing. The available silicate concentration significantly increased after soil washing but was two times lower than that of soil washed with HCl, which is widely used as a washing agent. This indicates that $FeCl_3$ can be an acceptable washing agent that protects the soil clay structure. The results suggest that soil amendment, such as liming, is needed to recover soil pH, reduce mobility of Pb, and provide exchangeable bases of Ca, Mg, and K as essential elements for the healthy growth of rice plants in reused soil that has been washed.

Effects of pH Control Agent and Co-Precipitate Washing Agent on Nickel Ferrite Preparation by Co-Precipitation Method (공침법에 의한 Nickel Ferrite의 분말제조에서 pH-조절제 및 공침물-세척제의 영향)

  • Jeong, Hong-Ho;Seong, Gi-Ung
    • Korean Journal of Materials Research
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    • v.10 no.6
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    • pp.445-449
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    • 2000
  • Nickel ferrite $(Ni_{0.75}Fe_{2.25}O_4$ was synthesized by co-precipitation method in order to investigate its behavior under conditions of the reactor coolant system in pressurized light water nuclear power plants. Ammonia or potassium carbonate was used as a solution pH control agent, and aqueous ammonia or potassium carbonate solution or secondary distilled water was used as a co-precipitate washing agent. The effects of the pH control agent and the co-precipitate washing agent on the production yield on the basis of the Ni/Fe molar ratio and the particle characteristics of final products were investigated by XRD, SEM, EDX and XPS. The production yield was almost congruent with that of the initial aqueous mixture in case of using potassium carbonate as a pH control agent, while in case of using ammonia, it was quite changed. The difference seemed to be due to the effects of $Ni^{2+}{\leftarrow}NH_3$complexation in the aqueous solution and of the pH of co-precipitate washing agent.

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