• 대한화학회지
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• 제14권1호
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• pp.45-48
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• 1970

"Significant liquid structure"의 이론과 반응 속도 이론을 이용 WLF점도식 꼴을 도출하였다. 반 실험적 WLF 점도식 내 실험 Parameter와 도출된 이론식 중의 해당된 항을 비교 검토하였다.

• 한국식품과학회지
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• 제27권2호
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• pp.193-198
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• 1995

여러 저장온도($5{\sim}25^{\circ}C$)에서 저장하는 동안의 두부의 물성 변화는 응력완화현상을 이용하여 시간-온도 중첩 이론을 통해 계산하고 분석하였으며 WLF(Williams-Landel-Ferry)식을 이용해서 품질변화를 예측할 수 있는 적용식을 제시하였다. 저장온도가 낮을수록 저장시 두부 조직의 초기응력 및 평형응력(equilibrium stress)이 강하게 나타났고, $15^{\circ}C$ 온도를 기준으로 이동인자를 이용하여 좌우 수평으로 이동시 하나의 중첩곡선(master curve)을 구하였다. 이동인자와 중첩곡선을 이용하여 WLF식에 적용해서 활성화 에너지를 계산하였고 임의 온도에서 저장 시간을 예측하였으며, 실제 두부 조직의 저장성을 논하였다.

• 폴리머
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• 제26권1호
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• pp.88-97
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• 2002

ortho-cresol novolac형 에폭시/페놀 경화제/triphenylphosphine 수지 시스템의 화학 레올로지 특성에 미치는 아민 실록산 개질제의 영향을 검토하였다. DSC측정으로부터 아민 개질제에 의해 경화 속도와 전환량이 증가하였으며 유리전이온도의 증가도 관찰할 수 있었다. 또한, 저장 탄성률과 손실 탄성률의 교차점으로부터 구한 겔화 시간 및 임계 전환량의 감소를 확인할 수 있었다. 이것으로부터 등온 경화반응이 빠르게 진행됨으로써 점도가 상승하는 것을 알 수 있었다. 전환량의 함수로 얻어진 유리전이온도와 측정된 점도로부터 modified WLF 방정식에서의 $C_1$ 및 $C_2$를 온도 함수로써 나타낼 수 있었으며, 유리전이온도와 $C_1$ 및 $C_2$를 modified WLF 방정식에 적용함으로써 등온 경화반응에 따른 점도변화를 정확히 예측할 수 있었다.

• 한국의류학회지
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• 제2권2호
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• pp.245-252
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• 1978

In order to obtain some information for solvent dyeing, polyethylene terephthalate (PET) was treated with water, tetrachloroethylene yarn (TCE), and water/TCE emulsion for three hours at the temperatures from $40^{\circ}$ to $140^{\circ}C$. The change of fine structure of substratum by measuring the shrinkage, the degree of crystallinity, the stress relacxation modulus and Young's modulus. The P.E.T. film was also treated in water (at $140^{\circ}C$) for 4 hours to stabilize the substratum. By means of film roll cyliderical method, the Disperse Blue 27 was diffused. Then, calculated the diffusion coefficient and examined the application of WLF equation. However, the temperature dependence of the shrinkage could be explain with WLF equation, the diffusion coefficient couldn't be applied the WLF equation when the substratum was stabilized. From the result, the effects on shrinkage were in the order of water

• International Journal of Precision Engineering and Manufacturing
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• 제7권4호
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• pp.23-27
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• 2006

Rubber is used in many industrial products, such as hoses, rubber belts, and oil seals. In particular, more than 200 rubber parts are used in automobiles. The design technology of these parts is largely dependent on field experience, which leads to lengthy and expensive developing procedures. However, with the help of recent developments in nonlinear computer analysis, new rubber products can be developed at low cost. In this study, rubber injection molding design variables, such as location and number of gates, were optimized using computer-aided engineering with the cross-WLF equation to produce CLIP rubber products made from ethylene propylene diene monomer(EPDM). The validity of the proposed design was evaluated by comparison with actual forming results.

• Elastomers and Composites
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• 제48권2호
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• pp.156-160
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• 2013

자동차 엔진 개스킷용으로 사용되는 아크릴 고무(ACM)의 압축크립 거동을 TMA 열분석기를 이용하여 연구하였다. 160, 180, 200, 및 $220^{\circ}C$의 서로 다른 온도에서 1N의 일정한 힘을 가하고 등온시험을 행한 결과, 시간에 따른 압축크립거동을 얻었고, 이로부터 시간-온도 중첩원리를 이용하여 기준온도 $160^{\circ}C$에서의 이동인자 $a_T$를 실험적으로 결정하고, 고온 데이터의 기준온도로의 평행 이동에 의하여 마스터 곡선을 얻을 수 있었다. 또한 WLF(Williams-Landel-Ferry) plot을 통하여 계산된 $C_1$과 $C_2$는 각각 -1.107 및 11.571로 계산되었으며, WLF식을 이용하는 $120^{\circ}C$에서의 ACM 고무재료의 수명은 약 24,000시간으로 예측되었다.

• 한국정밀공학회지
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• 제23권1호
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• pp.159-165
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• 2006

Many rubber products are used in industrial products such as various hoses, rubber belts and oil seals etc. Especially, more then 200 rubber parts are used in the automobile, but design technology of these is largely dependent on Held experiences. These methods brought about too much time and cost in the developing procedures. However, with the help of recent rapid development of non-liner computer analysis, we can develop new sound products at low cost. Therefore in this study, optimizations of design variables such as location and number of gate in order to develop CLIP rubber product made of EPDM were performed by CAE in which Cross-WLF equations are adopted. The validity of proposed variables is evaluated by comparison with real forming results.

• Bulletin of the Korean Chemical Society
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• 제23권3호
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• pp.413-416
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• 2002

The dielectric responses of 10 and 40 wt% siloxane-epoxy copolymers were investigated in temperature range near the glass transition of polydimethylsiloxane at which the dielectric transitions were also observed. On the other hand, the pure epoxy did not show any dielectric transition in measurement temperature range -90 to 150 $^{\circ}C.$ The experimental data showed that for the copolymer investigated, the temperature-frequency super-position principle could be applied to the dielectric response. From the Cole-Cole equation, the dielectric relaxation of the 10 wt% siloxane near the glass transition temperature resulted in a broad distribution with ${\beta}=$ 0.19 and the relaxation time at -70 $^{\circ}C$ was 5.3 ${\times}$ $10^{-2}$s. The glass transition temperature, 188 K, was estimated by using WLF relation, which was consistent with the data presented in experiment.

• Tribology and Lubricants
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• 제14권1호
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• pp.85-93
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• 1998

The Bair & Winer's limiting shear stress rheological model is incorporated into the Reynolds equation to successfully predict the traction and film thickness for an isothermal line contact using the primary rheological properties. The modified WLF viscosity model and Barus viscosity model are also adapted for the realistic prediction of EHD tractional behavior. The influences of the limiting shear stress and slide-roll ratio on the pressure spike, film thickness, distribution of shear stress and nonlinear variation of traction are examined. A good agreement between the disc machine experiments and numerical traction prediction has been established. The film thickness due to non-Newtonian effects does not deviate significantly from the fdm thicknesss with Newtonian lubricant.

• 한국의류학회지
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• 제3권2호
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• pp.37-41
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• 1979

In order to obtain tasic information for solvent dyeing, polyethylene terephthalate (PET) films was pretreated with water, tetrachloroethylene (TCE) and water/TCE emulsion for three hours at $140^{\circ}C$ for stabilizing the substrate. By film roll cyliderical method, Disperse Red 60, Disperse Yellow 42, and Disperse Blue 27 were diffused in the films and examined dyeing properties. The results are summarized as follows; 1) Diffusion coefficient increases in the order, waterTCE>water/TCE 2) A linear relationship between diffusion coefficient and shrinkage was Observed 3) The temperature dependence of the diffusion coefficient can't be expressed by WLF equation.