• Title/Summary/Keyword: WCA

Search Result 48, Processing Time 0.022 seconds

Enzymatic Modification of Wool/Polyester Blend Fabrics Using Lipase from Aspergillus Oryzae (리파제에 의한 양모/폴리에스터 혼방직물의 동시 개질)

  • Song, Hyun-Joo;Kim, Hye-Rim;Song, Wha-Soon
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.33 no.7
    • /
    • pp.1121-1127
    • /
    • 2009
  • This study presents an eco-friendly and one-step finishing method for modifying fiber property that reduces fiber damage in wool/polyester blend fabrics. Lipase from aspergillus oryzae is used in this experiment. The enzymatic treatment condition is optimized by measuring the relative activity of lipase depending on pH level, temperature, concentration of lipase, and treatment time. The concentration of $CaCl_2$as an activator is determined by the characteristics including whiteness, water contact angle (WCA), and dyeing property. The modified properties of lipase treated fabrics are tested for pill resistance and surface morphology. The results are described as follows: the optimum condions for lipase treatment constitute a pH level of 8.0, treatment temperature of 40$^{\circ}$$_C$, concentration of lipase at 100% (o.w.f), and a treatment time of 90 minutes. $CaCl_2$helps in raising lipase activation, and the optimum concentration is 50mM. The whiteness, wet ability, and pill resistance of lipase treated fabrics improves as compared to the control. The dyeing property of lipase treated fabrics improved by 53.5% after using the one-bath dyeing method. This means that lipase treatment can save time and cost during the dyeing process since lipase treatment modifies wool and polyester fibers. The surface of lipase treated wool fibers do not exhibit any change, however voids and cracks manifest on the surface of lipase treated polyester fibers.

Studies on the N , $P_2O_5$ and $K_2O$-Application in the Mixed Sward of Alfalfa-Grass II. Effect of Phosphate fertilization levels on dry matter and nutrition yeild of forage in the mixed sward alfalfa-grasses (Alfalfa-Grass 혼파초지에 대한 3요소 시비 연구 II. 인산질비료의 시용수준이 alfalfa-grass 혼파초지의 건물 및 양분수량에 미치는 영향)

  • 박근제;김영진;최기준;이필상
    • Journal of The Korean Society of Grassland and Forage Science
    • /
    • v.16 no.1
    • /
    • pp.47-52
    • /
    • 1996
  • To investigate the effects of phosphate($P_2O_5$) fertilization levels on the dry matter(DM) yield, nutrition yield, and $P_2O_5$ efficiency of forages in mixed sward of alfalfa-grasses, a field experiment arranged by randomized complete block design with five treatments(0, 50, 100, 150 and 200kg $P_2O_5$/ha) was conducted at Livestock Experiment Station in Suwon, September, 1990 to Feb~ary, 1993. During two years, average DM yields of forages increased as $P_2O_5$ fertilization level was increased, but no significant difference was found between DM 10,754kg of $P_2O_5$ 150kg/ha and DM 10,845kg of $P_2O_5$ 200kg/ha. Cmde protein and energy productivity of forages increased as $P_2O_5$ fertilization level was increased, and the increasing degree was highest between $P_2O_5$ l00kg and 150kg/ha feriilization. With increasing $P_2O_5$ fertilization, mineral contents tended to increase in P, K and WCa+ Mg equivalent ratio, but not to be regular in the other elements. Efficiency of $P_2O_5$ was highest at $P_2O_5$ 150kg/ha fertilization, which produced DM 12.8kg. net energy lactation 75.4MJ. starch equivalent 6.lkStE, and total digestible nutrients 8.6kg per Ikg $P_2O_5$.

  • PDF

Fabrication Thermal Responsive Tunable ZnO-stimuli Responsive Polymer Hybrid Nanostructure

  • Lee, Jin-Su;Nam, Sang-Hun;Yu, Jung-Hun;Hwang, Ki-Hwan;Ju, Dong-Woo;Jeon, So-Hyoun;Seo, Hyeon-Jin;Yun, Sang-Ho;Boo, Jin-Hyo
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2014.02a
    • /
    • pp.429.2-429.2
    • /
    • 2014
  • ZnO nanowire is known as synthesizable and good mechanical properties. And, stimuli-responsive polymer is widely used in the application of tunable sensing device. So, we combined these characteristics to make precise tunable sensing devise. In this work, we investigate the dependence of ZnO nanowire alignment and morphology on si substrate using nanosphere template with various conditions via hydrothermal process. Also, pH-temperature dependant tuning ability of nanostructure was studied. The brief experimental scheme is as follow. First, Zno seed layer was coated on a si wafer ($20{\times}20mm$) by spin coater. And then $1.15{\mu}m$ sized close-packed PS nanospheres were formed on a cleaned si substrate by using gas-liquid-solid interfacial self-assembly method. After that, zinc oxide nanowires were synthesized using hydrothermal method. Before the wire growth, to specify the growth site, heat treatment was performed. Finally, NIPAM(N-Isopropylacrylamide) was coated onto as-fabricated nanostructure and irradiated by UV light to form the PNIPAM network. The morphology, structures and optical properties are investigated by FE-SEM(Field Emission Scanning electron Microscopy), XRD(X-ray diffraction), OM(Optical microscopy), and WCA(water contact angle).

  • PDF

Synthesis of Pd-decorated SiO2 layers with superhydrophobic and oleophilic micro-nano hierarchical (초소수성 및 친유성을 갖는 마이크로-나노 계층구조의 Pd 금속입자 기능화된 SiO2층 합성)

  • Kim, Jae-Hun;Lee, Jae-Hyeong;Kim, Jin-Yeong;Kim, Sang-Seop
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2017.05a
    • /
    • pp.67.2-67.2
    • /
    • 2017
  • 본 연구에서는 $SiO_2$ 미세구조 상에 Pd 나노입자(NPs)를 증착하여, 불소화된 마이크로-나노 계층구조를 갖는 Pd-decorated $SiO_2$($Pd/SiO_2$)를 제작하였다. 마이크로 크기의 거칠기를 갖는 $SiO_2$ 층은 졸-겔 공정을 사용해서 제조된 용액을 전기분사함으로써 제조되었다. 이어서, 자외선(UV)을 이용한 광 환원법을 이용해 Pd 나노입자를 $SiO_2$ 층에 형성했다. 생성된 표면은 마이크로-나노의 계층구조 형태를 보여주었다. 해당 시편의 불소화 처리 후, 마이크로-나노의 계층구조 표면은 $170^{\circ}$ 이상의 물 접촉각(water contact angle; WCA) 및 $5^{\circ}$ 이하의 슬라이딩 각(sliding angle)을 보여줌으로써 물에 대해 탁월한 소수성을 나타내었다. 또한, 커피($CA=161^{\circ}$), 우유($CA=162^{\circ}$), 쥬스($CA=163^{\circ}$), 그리고 글리세롤($CA=165^{\circ}$)에 대해서도 우수한 소수 특성을 보여주었다. 또한, 이들 $Pd/SiO_2$ 층은 우수한 장기내구성 및 자외선 저항성을 보여주었다. 그리고 이어진 기름에 대한 접촉각 측정을 통해 해당 시편이 소유 특성이 아닌 친유 특성을 보여준다는 것을 확인할 수 있었고, 기름에 대한 CA는 약 ${\sim}10^{\circ}$로 매우 우수한 친유 특성을 나타내었다. 이와 같은 결과는 자체세정이 가능한 표면 및 지능형 물/기름 분리 시스템과 같은 스마트 장치에서 초소수성-친유성 특성을 갖는 계층구조의 $Pd/SiO_2$ 층을 사용할 가능성을 명확하게 보여준다고 판단된다.

  • PDF

Studies on the N , $P_2O_5$ and $K_2O$-Application in the Mixed Sward of Alfalfa-Grass III. Effect of potassium fertilization levels on dry matter and nutrition yeild of gorage in the mixed sward of alfalfa-grasses (Alfalfa-Grass 혼파초지에 대한 3요소 시비 연구 III. 가리질시료의 시용수준이 alfalfa - grass 혼파초지의 건물 및 양분수량에 미치는 영향)

  • 박근제;이필상;최기준;김영진
    • Journal of The Korean Society of Grassland and Forage Science
    • /
    • v.16 no.2
    • /
    • pp.121-126
    • /
    • 1996
  • To investigate the effects of potassium($K_2O$) fertilization levels on the dry matter(DM) yield, nutrition yield, and $K_2O$ efficiency of forages in mixed sward of alfalfa-grasses, a field experiment arranged by randomized complete block design with five treatments(0, 60, 120, 180 and 240kg $K_2O$/ha) was conducted at National Livestock Research Institute in Suwon, September, 1990 to February, 1993. During two years, average DM yields of forage increased as $K_2O$ fertilization level was increased, but no significant difference was found between DM 10,617kg of $K_2O$180kgha and DM 10,845kg of $K_2O$ 240kg/ha. Crude protein and energy productivity of forages increased as $K_2O$ fertilization level was increased, and the increasing degree was highest between $K_2O$ 120kg and 180kg/ha fertilization. With increasing $K_2O$ fertilization, mineral contents tended to increase in K and WCa+Mg equivalent ratios, to decrease in Mg, but not to be regular in the other elements. Efficiency of $K_2O$ was relatively high at $K_2O$ 180kgha fertilization, which produced DM 12.2kg, net energy lactation 67.3M.J, starch equivalent 6.2kStE and total digestible nutrients 7.6kg per Ikg $K_2O$. Therefore, potassium($K_2O$) fertilization levels must be applied with I8Okg/ha for a reasonable management in mixed sward of alfalfa-grasses.

  • PDF

Preparation of highly hydrophobic PVDF hollow fiber composite membrane with lotus leaf-like surface and its desalination properties

  • Li, Hongbin;Zi, Xingchen;Shi, Wenying;Qin, Longwei;Zhang, Haixia;Qin, Xiaohong
    • Membrane and Water Treatment
    • /
    • v.10 no.4
    • /
    • pp.287-298
    • /
    • 2019
  • Lotus leaf has a special dual micro and nano surface structure which gives its highly hydrophobic surface characteristics and so-called self cleaning effect. In order to endow PVDF hollow fiber membrane with this special structure and improve the hydrophobicity of membrane surface, PVDF hollow fiber composite membranes was obtained through the immersion coating of poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) dilute solution on the outside surface of PVDF support membrane. The prepared PVDF composite membranes were used in the vacuum membrane distillation (VMD) for the desalination. The effects of PVDF-HFP dilute solution concentration in the dope solution and coating time on VMD separation performance was studied. Membranes were characterized by SEM, WCA measurement, porosity, and liquid entry pressure of water. VMD test was carried out using $35g{\cdot}L^{-1}$ NaCl aqueous solution as the feed solution at feed temperature of $30^{\circ}C$ and the permeate pressure of 31.3 kPa. The vapour flux reached a maximum when PVDF-HFP concentration in the dilute solution was 5 wt% and the coating time was kept in the range of 10-60 s. This was attributed to the well configuration of micro-nano rods which was similar with the dual micro-nano structure on the lotus leaf. Compared with the original PVDF membrane, the salt rejection can be well maintained which was greater than 99.99 % meanwhile permeation water conductivity was kept at a low value of $7-9{\mu}S{\cdot}cm^{-1}$ during the continuous testing for 360 h.

Regional Difference in Distribution of Glycoconjugates in Mouse Epididymis (생쥐 부정소 부위별 당쇄 분포의 차이)

  • 계명찬
    • Development and Reproduction
    • /
    • v.5 no.2
    • /
    • pp.167-173
    • /
    • 2001
  • To characterize the difference in glycoconjugates of mouse epididymis, lectin labeling of the tissue section was conducted using Ulex europaeus agglutinin I(UEA I), succinylated wheat germ agglutinin(sWGA), and Griffonia simplicifolia lectin-I(GSL-I). UEA I which binds to outer $\alpha$-L-fucose residue that is a terminal sugar of the side chain branched from oligosaccharide chain gave the labeling in the proximal caput epithelia exclusively. Lumen was commonly labeled in all of the organ. It suggested that the glycoconjugates bearing outer $\alpha$ -L-fucose residue were largely expressed in the initial segments ot epididymis and subjected to secretion. GSL-I which binds to terminal $\alpha$ -D-galactosyl residue of glycoconjugates gave the labeling in the cytoplasm of clear cells and basal cells, and cilia in corpus and cauda regions but not in the caput region. There was no vast difference in labeling pattern by sWGA which binds to N-acetyl-glucosamine residue among the epididymal regions. Clear cells in corpus and cauda epithelia showed more intense labeling by sWGA compared to principal cells, suggesting the functional specialization of this type of cells. The labeling intensities of luminal content by UEA I and sWGA decreased in cauda region compared to corpus region suggesting the presence of enzymatic activities responsible for processing the $\alpha$-L-fucose and N-acetyl-glucosamine residues from secreted glycoconjugates. In summary, the difference in glycoconjugates bearing the $\alpha$-L-fucose, $\alpha$-D-galactose, and N-acetyl-glucosamine residues according to the type of epithelial cells and epididymal segments suggests functional specialization and different roles of each segment in the processing of sperm surface antigens during the epididymal transit.

  • PDF

Estimate on the Crustal Thickness from Using Multi-geophysical Data Sets and Its Comparison to Heat Flow Distribution of Korean Peninsula (다양한 지구물리 자료를 통해 얻은 한반도의 지각두께 예측과 지열류량과의 비교)

  • Choi, Soon-Young;Kim, Hyung-Rae;Kim, Chang-Hwan;Park, Chan-Hong;Suh, Man-Chul
    • Economic and Environmental Geology
    • /
    • v.44 no.6
    • /
    • pp.493-502
    • /
    • 2011
  • We study the deep structure of Korean Peninsula by estimating Moho depth and crustal thickness from using land and oceanic topography and free-air gravity anomaly data. Based on Airy-Heiskanen isostatic hypothesis, the correlated components between the terrain gravity effects and free-air gravity anomalies by wavenumber correlation analysis(WCA) are extracted to estimate the gravity effects that will be resulted from isostatic compensation for the area. With the resulting compensated gravity estimates, Moho depth that is a subsurface between the crust and mantle is estimated by the inversion in an iterative method with the constraints of 20 seismic depth estimates by the receiver function analysis, to minimize the uncertainty of non-uniqueness. Consequently, the average of the resulting crustal thickness estimate of Korean Peninsula is 32.15 km and the standard deviation is 3.12 km. Moho depth of South Korea estimated from this study is compared with the ones from the previous studies, showing they are approximately consistent. And the aspects of Moho undulation from the respective study are in common deep along Taebaek Mountains and Sobaek Mountains and low depth in Gyeongsang Basin relatively. Also, it is discussed that the terrain decorrelated free-air gravity anomalies inferring from the intracrustal characteristics of the crust are compared to the heat flow distributions of South Korea. The low-frequency components of terrain decorrelated Free-air gravity anomalies are highly correlated with the heat flow data, especially in the area of Gyeongsang basin where high heat flow causes to decrease the density of the rocks in the lower crust resulting in lowering the Moho depth by compensation. This result confirms that the high heat sources in this area coming from the upper mantle by Kim et al. (2008).