• Title/Summary/Keyword: WATER CONTACT ANGLE

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Experimental Study on the Hysteresis of Suction Stress in Unsaturated Sand (불포화 모래의 흡입응력 이력현상에 대한 실험적 연구)

  • Song, Young-Suk;Choi, Jin-Su;Kim, Gyo-Won
    • The Journal of Engineering Geology
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    • v.22 no.2
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    • pp.145-155
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    • 2012
  • The matric suction and volumetric water content of Jumunin standard sand with a relative density of 60% were measured using an Automated Soil-Water Characteristic Curve (SWCC) apparatus during both drying and wetting processes. The test time for the drying process was longer than that for the wetting process, because the flow of water is likely to be protected by air trapped in voids within the soils during the drying process. Based on the matric suction and volumetric water content, the SWCC was estimated using the model proposed by van Genuchten (1980). For the drying process, the unsaturated fitting parameters ${\alpha}$, n, and m were 0.399, 8.586, and 0.884, respectively; for the wetting process, the values were 0.548, 5.625, and 8.220, respectively. The hysteresis phenomenon occurred in the SWCCs, which means the SWCC of the drying process is not matched with the SWCC of the wetting process. Using these unsaturated parameters, we estimated the Suction Stress Characteristic Curve (SSCC), based on the relationship between suction stress and the effective degree of saturation. The suction stress showed a rapid decrease when the matric suction exceeds the Air Entry Value (AEV). Therefore, the effective stress of unsaturated soils is different from that of saturated soils when the matric suction exceeds the AEV. The suction stress of the drying process exceeds that of the wetting process for a given effective degree of saturation. The hysteresis phenomenon was also recognized in SSCCs. The hysteresis phenomenon of SSCCs arises from that of SWCCs, which is induced by the ink bottle effect and the contact angle effect. In the case of a sandy slope, the suction stress is positive and acts to enhance the slope stability as the water infiltrates the ground, but is negative when the suction stress exceeds the AEV. The results obtained for the wetting process should be applied in analyses of slope stability, because the process of water infiltration into ground is similar to the wetting process.

High Speed Direct Bonding of Silicon Wafer Using Atmospheric Pressure Plasma (상압 플라즈마를 이용한 고속 실리콘 웨이퍼 직접접합 공정)

  • Cha, Yong-Won;Park, Sang-Su;Shin, Ho-Jun;Kim, Yong Taek;Lee, Jung Hoon;Suh, Il Woong;Choa, Sung-Hoon
    • Journal of the Microelectronics and Packaging Society
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    • v.22 no.3
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    • pp.31-38
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    • 2015
  • In order to achieve a high speed and high quality silicon wafer bonding, the room-temperature direct bonding using atmospheric pressure plasma and sprayed water vapor was developed. Effects of different plasma fabrication parameters, such as flow rate of $N_2$ gas, flow rate of CDA (clear dry air), gap between the plasma head and wafer surface, and plasma applied voltage, on plasma activation were investigated using the measurements of the contact angle. Influences of the annealing temperature and the annealing time on bonding strength were also investigated. The bonding strength of the bonded wafers was measured using a crack opening method. The optimized condition for the highest bonding strength was an annealing temperature of $400^{\circ}C$ and an annealing time of 2 hours. For the plasma activation conditions, the highest bonding strength was achieved at the plasma scan speed of 30 mm/sec and the number of plasma treatment of 4 times. After optimization of the plasma activation conditions and annealing conditions, the direct bonding of the silicon wafers was performed. The infrared transmission image and the cross sectional image of bonded interface indicated that there is no void and defects on the bonded wafers. The bonded wafer exhibited a bonding strength of average $2.3J/m^2$.

Assessment of Wicking and Fast Dry Properties According to Moisture Transport Measurement Method of Knit and Woven Fabrics for Garment (의류소재용 직·편물의 수분이동 특성 측정 방법에 따른 흡한속건성 평가)

  • Kim, Hyun-ah;Kim, Seung-jin
    • Science of Emotion and Sensibility
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    • v.20 no.2
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    • pp.117-126
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    • 2017
  • In this study, moisture transport characteristics for the woven and knitted fabrics made of 8 kinds of fiber materials using MMT (moisture management tester) were measured and discussed with the Bireck bt MMT and water evaporating rate (WER) measuring methods, which are vertical moisture transport methods. In addition, the drying property by MMT of the eight kinds of specimens was compared and discussed with the results measured by the vertical drying measurement. MMT experimental result which is horizental moisture transport appeared to be similar to the result of the Bireck method, which is the vertical moisture transport experiment. Absortion time measured from drip method of the fabrics made of the bamboo, linen, and cotton/nylon composite fabrics was short and thus they showed best wicking property, which was attributed to the low contact angle on the fabric surface and high porosity of the fabrics due to the staple yarn structure composed of the hydrophilic staple fibers. In drying property of the fabric specimens by MMT, maximum absorption radius of the dry-zone knit and bamboo woven fabrics were the highest and they showed the best drying property, which was a little different result compared with vertical drying measurement method. Half time of the drying rate in the MMT method was highly correlated with the fabric thickness and saturated moisture absortion rate and their regression coefficients were 0.9 and 0.88, respectively. This means that the knitted and woven fabric design technology for retaining good wicking and drying properties of the fabrics with thin fabric thickness is very important for obtaining high functional wear comfort fabrics. In addition, wicking and drying properties of the fabrics made of different fiber materials and with different yarns and fabric structures showed different results according to the measuring methods.

Analysis of Capillary Flow in Open-Top Rectangular Microchannel (상판이 없는 직사각형 단면의 미세채널에서 모세관 유동 분석)

  • Park, Eun-Jung;Cho, Ji-Yong;Kim, Jeong-Chul;Hur, Dae-Sung;Chung, Chan-Il;Kim, Jung-Kyung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.1
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    • pp.77-82
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    • 2010
  • Our study aims to understand the flow of liquid in an open-top rectangular microchannel that can be used in micro total analysis systems ($\mu$-TAS) because it has advantages in terms of light transmission and energy efficiency. We measured the liquid velocity using particle tracking technique and conducted a simulation with computational fluid dynamics by altering the area of channel cross section and channel length for the capillary-driven flow in the open-top rectangular microchannel. When liquid water drops to an entrance of the fabricated microchannel with a height of 20 μm and a width of 20 ${\mu}m$, it flows along the microchannel by only capillary force. In the wetting behavior of the liquid, important parameters of this flow are channel size, contact angle and liquid properties such as surface tension and viscosity, which are used to control the flow of liquid in the microchannel.

Field Case Study for the Productivity Analysis of B2 Reservoir, Donghae-1 Gas Field (동해-1 가스전 B2 저류층의 생산성 분석에 관한 Field Case Study)

  • Kwon Sun-Il;Ryou Sangsoo;Kwon Oukwang;Sung Wonmo
    • Journal of the Korean Institute of Gas
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    • v.5 no.1
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    • pp.60-72
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    • 2001
  • This paper presents the user-interactive productivity analysis model based on material balance as well as deliverability equations equipped with EOS model to perform a productivity analysis for Gorae V structure, Donghae-1 gas field. This model is designed to be able to analyse the productivity in the case of reservoir contacting with the aquifer. Also, in order to investigate the effect of condensation on productions, condensation phenomenon is considered as an apparent skin effect in the computation of bottomhole pressure from average reservoir pressure. By utilizing the developed model, we investigate the productivity analysis for B2 layer of Garae V structure with the various production cases in volumetric and non­volumetric reservoirs that contact with aquifer. From the results in the case of 5500 MMSCF/year of production and reservoir-aquifer contacting angle 270$^{\circ}C$ with aquifer size of 10 times greater than reservoir, B2 layer could maintain peak production rate even after 8.5 years of production by considering the bottomhole pressure which is estimated above the operating pressure of 1298 psia. It is also found that condensate will be formed after 1100 days of production and existed throughout the reservoir at 1270 days. Note that the computed reservoir pressure of B2 layer is maintained sufficiently high enough for production due to the water influx into the reservoir, and skin effect caused by condensation is not significant.

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Preparation of superhydrophilic coating solutions containing fluorosurfactants and characterization of their antifogging and antifouling properties (불소계면활성제를 함유한 초친수 코팅액의 제조 및 방담 방오 특성)

  • Lee, Soo;Im, Sun Moon;Hwang, Heon
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.3
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    • pp.525-535
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    • 2017
  • In order to produce hydrophilic coating solution, which has superior antifogging and antifouling effect on the glass surface of solar cell module as well as improving photovoltaic efficiency, nanosilica was dispersed in an aqueous solution of Tween 20 and fluorosurfactant composed of decafluorobutane and polyethylene glycol. The antifogging effect at high temperature was excellent for all the coating solutions containing nanosilica, but the antifouling effect was observed when the content of nanosilica was over 6 wt%. As the content of fluorosurfactant increased, the initial water contact angle slightly increased and the antifogging effect remained well until 500 wiping with wet $Wipeol^{(R)}$. The antifouling effect was also excellent regardless of the content of fluorosurfactant, thus 0.1 wt% of the fluorosurfactant was enough for a coating solution production. From the AFM results, when 0.1 wt% to 0.3 wt% of the fluoro surfactant was added, the fractal structure of the coated glass surface was clearly existed and contributed to the better antifouling effect. The transmittance of coated glass surface was highest in TL-1 coating solution containing 0.1 wt% of fluorosurfactant, and the addition of fluorosurfactant in a larger amount than 0.1 wt% did not improve the transmittance. This result is in good agreement with the previous AFM result which shows a high surface roughness as well as a fractal structure formation for the TL-1 coating solution.

Synthesis and characterization of hydrophobic and hydrophilic cellulose derivative by esterification (친수성과 소수성을 동시에 가지는 아세틸화 셀룰로스 에테르의 합성 및 특성 평가)

  • Kim, Taehong;Lee, Sangku;Son, Byunghee;Paik, Hyun-Jjong;Yoon, Sanghyeon;Lee, Heesoo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.1
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    • pp.31-36
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    • 2013
  • Acetylated Cellulose Ether (ACE), cellulose-based amphiphilic polymer with hydrophilic and hydrophobic, was synthesized and investigated in terms of its solubility and wettability for organic solvents and water. Acetyl group was substituted to the cellulose ether in a hydrophilic polymer by esterification. As a result of FT-IR, the peak corresponding to the hydroxyl group decreased and carboxyl acid peak increased with increasing reaction time and temperature, which signified the increase in the degree of acetylation of the ACE. There were similar thermal decomposition behaviors before and after esterification reaction until $800^{\circ}C$ so that the reaction occurred without significant structural changes of cellulose backbones. The solubility parameter of the ACE had a range of 18.5~26.4, and its viscosity and turbidity were controlled according to the solubility parameter of organic solvents. The ACE showed the hydrophilicity because the contact angle of the ACE was higher than the cellulose ether. These results confirmed that the ACE had the hydrophobicity and hydrophilicity due to the ether which was glucosidic bonding between the glucose units and un-reacted hydroxyl functional groups in the ACE.

Water Repellent Finishes of Polyester Fiber Using Glow Discharge (글로우방전을 이용한 폴리에스테르섬유의 발수가공)

  • Mo, Sang Young;Kim, Gi Lyong;Kim, Tae Nyun;Chun, Tae Il
    • Textile Coloration and Finishing
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    • v.5 no.4
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    • pp.29-41
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    • 1993
  • In order to surface Hydrophobilization of Poly(ethylene terephthalate) (PET) fiber samples were treated in the atmosphere of CF$_{4}$ or $C_{2}$F$_{6}$glow discharge. The sample used in this study was PET film which is 75$\mu$m thick made by Teijin, O-Type(Japan). The cleaned samples were placed in plasma reactor made of pyrex glass cylinder, and plasma processing was carried out by glow discharge of CF$_{4}$ or $C_{2}$F$_{6}$ gas, being continuously fed by gas flow and continuously pumped out by a vacuum system. Electric power source for generate plasma state was sustained alternating current(60Hz) and voltage was sustained 600 volt. The duration of plasma treatment varied from 15 to 120 seconds except special case, the monomer gase pressure varied from 0.02 to 0.3 Torr and power range was 10 to 90 watts. The hydrophobic features of changed PET surface were evaluated by contact angle measurement and surface chemical characteristics were analyzed by ESCA. Results can be summerized as follows. 1. The most favorable setting position of substrate was the center area between the two electrodes. 2. $C_{2}$F$_{6}$ discharge current was lower than that of CF$_{4}$ when same voltage was sustained. Treated efficiency between CF$_{4}$ and $C_{2}$F$_{6}$ did not revealed significant differences under same electric power(wattage). 3. When monomer pressure is very low below 0.02 torr, as though substrate is exposed to CF$_{4}$ or $C_{2}$F$_{6}$ plasma, it tend to be hydrophilic through a little of fluorine bond and a great deal of oxidizing reaction. 4. There brought good hydrophobilization when monomer pressure was more 0.1 torr and duration of glow discharge treatment was over 45 seconds. When monomer pressure was too high, discharge current became low. Although prolong the duration, there was no more high hydrophobilization. 5. According to ESCA analysis, there were a little CF bond and a prevailing CF$_{2}$ bond in CF$_{4}$-treated substrate. There were CF$_{3}$, a little CF and a prevailing CF$_{2}$ bond in $C_{2}$F$_{6}$-treated substrate.d substrate.

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Formation of Size-controllable Ag Nanoparticles on Si Substrate by Annealing (크기 조절이 가능한 은 나노입자 형성을 위한 박막의 열처리 효과)

  • Lee, Sang Hoon;Lee, Tae Il;Moon, Kyeong-Ju;Myoung, Jae Min
    • Korean Journal of Materials Research
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    • v.23 no.7
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    • pp.379-384
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    • 2013
  • In order to produce size-controllable Ag nanoparticles and a nanomesh-patterned Si substrate, we introduce a rapid thermal annealing(RTA) method and a metal assisted chemical etching(MCE) process. Ag nanoparticles were self-organized from a thin Ag film on a Si substrate through the RTA process. The mean diameter of the nanoparticles was modulated by changing the thickness of the Ag film. Furthermore, we controlled the surface energy of the Si substrate by changing the Ar or $H_2$ ambient gas during the RTA process, and the modified surface energy was evaluated through water contact angle test. A smaller mean diameter of Ag nanoparticles was obtained under $H_2$ gas at RTA, compared to that under Ar, from the same thickness of Ag thin film. This result was observed by SEM and summarized by statistical analysis. The mechanism of this result was determined by the surface energy change caused by the chemical reaction between the Si substrate and $H_2$. The change of the surface energy affected on uniformity in the MCE process using Ag nanoparticles as catalyst. The nanoparticles formed under ambient Ar, having high surface energy, randomly moved in the lateral direction on the substrate even though the etching solution consisting of 10 % HF and 0.12 % $H_2O_2$ was cooled down to $-20^{\circ}C$ to minimize thermal energy, which could act as the driving force of movement. On the other hand, the nanoparticles thermally treated under ambient $H_2$ had low surface energy as the surface of the Si substrate reacted with $H_2$. That's why the Ag nanoparticles could keep their pattern and vertically etch the Si substrate during MCE.

Interaction of Schwann Cells with Various Protein- or Polypeptide-Coated PLGA Surfaces (다양한 단백질과 폴리펩타이드로 코팅된 PLGA 표면과 슈반세포와의 상호관계)

  • Park Ki-Suk;Kim Su-Mi;Kim Moon-Suk;Lee Il-Woo;Rhee John-M.;Lee Hai-Bang;Khang Gil-Son
    • Polymer(Korea)
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    • v.30 no.5
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    • pp.445-452
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    • 2006
  • In this study, we investigated interaction of Schwann cells (SCs) with various cell-adhesive coated polymer surface. We used cell-adhesives that like a fibronectin (FN), fibrinogen(FG), laminin(LM), vitronectin (VN), poly-D-Iysine (PDL), and poly-L-Iysine (PLL) to coat PLGA film surface and evaluated the surface property of coated or not PLGA films by measurement of water contact angle and ESCA. SCs were cultured on coated or non-coated PLGA film surface, and then examined the cell adhesion and proliferation by cell count and SEM observation. Cell count results revealed initial cell adhesion related to protein adsorption on PLGA surface. In addition, serum content in media related to cell proliferation rate. In this result, we recognized that adhesion and proliferation of SCs were affected by specific cell-adhesives. In these results, we recognized that is important to provide the suitable surface environment according to cell types and culture condition for improvement of cell adhesion and proliferation.