• 제목/요약/키워드: W-Ni

검색결과 865건 처리시간 0.028초

디젤엔진용 소결(W/C35%Ni) 태핏의 마멸거동에 관한 연구 (A Study on Friction and Wear Characteristics of Sintered W/C-35%Ni Tappets for Diesel Engine Application)

  • 류병진;오세일;박맹로;양승호
    • Tribology and Lubricants
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    • 제16권1호
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    • pp.33-38
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    • 2000
  • Abstract- In this paper tribological characteristics of solid and liquid phase sintered W/C-35%Ni tappets were investigated. Three test methods were performed to investigate the wear and surface damage mechanism of sintered tappets. First, block-on-ring wear test was performed to investigate the wear characteristics under pure sliding condition. Second, simplified cam and tappet tests (called component wear test hereafter) were carried out to simulate the real contact history of cam and tappet. Also, after the test, contact surfaces were analyzed with scanning electron microscope to study the wear mechanism. As a final screening, engine dynamo tests were performed. Results showed that in the block on ring sliding wear test, solid phase sintered specimens showed superior wear resistance to liquid phase sintered specimens. The component wear tests and engine dynamo tests also showed the same results. Therefore, in these tests, solid phase sintered tappet material revealed superior wear resistant properties to liquid phase sintered one.

$Ni-W/TiO_2-ZrO_2$ 촉매상에서 Thiophene의 수첨탈황반응 (Hydrodesulfurization of Thiophene over $Ni-W/TiO_2-ZrO_2$ catalysts)

  • 전광승;김문찬;김경림
    • 한국대기환경학회지
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    • 제8권1호
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    • pp.84-91
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    • 1992
  • Hydrodesulfurization of thiophene was studied over $Ni-W/TiO_2-ZrO_2$ catalysts in a fixed bed flow reactor. The ranges of experimental conditions were at the temperatures between 200$^\circ$C and 360$^\circ$C, the pressures between 20 X $10^5$ Pa. The catalysts were reduced with the flow of 10 L/hr of $H_2$ at the temperature of 350$^\circ$C. It was found that $TiO_2-ZrO_2$ supported catalysts had similar activity to $\gamma-Al_2O_3$ supported. The largest surface areas and the highest acidity occured as the binary oxides were mixed with equal molar ratios. The HDS increased with increasing temperatures, pressures and contact times.

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금속 염 첨가 방법을 이용하여 사출성형된 텅스텐 중합금의 소결거동 (Sintering Behavior of the Injection Molded W-Ni-Fe Heavy Alloy by Addition of Metallic Stat)

  • 김대건;류성수;김은표;이정근;김영도;문인형
    • 한국분말재료학회지
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    • 제6권4호
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    • pp.294-300
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    • 1999
  • This study was carried out to investigate the possibility whether Metal Injection Molding (MIM) process could be applied to 95wt.%W-3.5wt.%Ni-1.5wt.%Fe heavy alloy in order to obtain an intricate shape. Methylcellulose was used in the injection molding for binder. $FeCl_2-4H_2O$ was added in solvent substituting Fe powder and $FeCl_2$ was doped on W-Ni premixed powder. When $FeCl_2-4H_2O$ was added in solvent, the binder separation occurred for injection molding so that the matrix content was changed. Such problem was solved when $FeCl_2$ was doped. In this study. the debinding process did not affect residual carbon content. The sintered microsouctures as addition methods of Fe element and the sintering temperature from $1420^{\circ}C$ to $1470^{\circ}C$, which are around the temperature of liquid phase formation, were observed.

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황화 $Ni-W/\gamma-Al_2O_3$ 촉매에 의한 Dibeenzothiophene의 수첨탈황반응 (Hydrodesulfurization of Dibenzothiophene by Sulfided $Ni-W/\gamma-Al_2O_3$ Catalyst)

  • 김경림;정지원
    • 한국대기환경학회지
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    • 제2권2호
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    • pp.51-59
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    • 1986
  • Hydrodesulfurization of dibenzothiophene (DBT) dissolved in n-heptane was studied over sulfided $Ni - W/\gamma - Al_2O_3$ catalyst at temperature ranges from 513 to 573 K and at pressure ranges from 20 to 60 x $10^5$ Pa. Hydrogenation of biphenyl (BP) and cyclohexylbenzene (CHB) observed in products were also run. The products were almost biphenyl and cyclohyxylbenzene, and the conversion of DBT was very sensitive to temperature. Concerning the products distribution while the formation of biphenyl decreased, the formation of cyclohexylbenzene increased in the range of high pressure. The reaction network was found to be sequential reaction which formed cyclohexybenzent through the intermediate of biphenyl. The disappearances of DBT and biphenyl were the first order with respect to DBT and biphenyl and their activation energys were 24.3 and 13.6 Kcal/mol, respectively.

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Ni-W 합금도금용 불용성 양극의 제조 및 특성 연구 (Preparation and Characterization of Insoluble Anodes for Electrodeposition of Ni-W Alloys in Ammoniacal Citrate Bath)

  • 장도연;강성군
    • 한국표면공학회지
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    • 제32권6호
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    • pp.686-694
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    • 1999
  • Insoluble anodes of the Ta/Ir mixed metal oxide for electrodeposition of Ni-W alloy in ammoniacal citrate bath were prepared by thermal decomposition method. Ti plate was etched in boiling oxalic acid solution and coated with ethanol solution of $TaCl_{5}$ and $IrCl_4$ mixed in a fixed ratio, followed by drying and treating at various temperatures. The coating layer of these insoluble anode was characterized by SEM, EDX, XRD and DSC. The decomposition rate of citric acid in plating bath was determined by measuring the $CO_2$ gas evolved at the anodes with Gas Chromatography. Evolution of $CO_2$ gas from Ta/Ir oxide anodes decreased about 5% compared with that of Pt. The $CO_2$ gas evolution was increased with the amount of Ir-oxide in the coatings. The coatings which have more than 40% ratio of Ta content and heat-treated at the temperature higher than $400^{\circ}C$ showed better efficiency

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