• Title/Summary/Keyword: W-Ni

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Stable Blue Electroluminescence from Fluorine-containing Polymers (불소 함유된 고분자를 이용한 안정한 청색 발광 유기 EL)

  • Kang In-Nam
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.6
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    • pp.568-573
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    • 2006
  • We have synthesized new blue light emitting random copolymers, poly(9,9'-n-dioctylfluorene-co-perfluorobenzene-1,4-diyl)s (PFFBs), via Ni(0)-mediated coupling reactions. The weight-average molecular weights ($M_w$) of the PFFB copolymers ranged from 9,000 to 15,000. The PFFB copolymers dissolved in common organic solvents such as THF and toluene. The PL emission peaks of the PFFB copolymers were at around 420, 440, and 470 nm. EL devices were fabricated in ITO/PEDOT/polymer/Ca/Al configurations using these polymers. These EL devices were found to exhibit pure blue emission with approximate CIE coordinates of (0.15, 0.11) at $100cd/m^2$. The blue emissions of these devices might be due to the restriction of the polymer chains to aggregation by introducing of the highly electronegative fluorine moieties. The maximum brightnesses of the PFFB copolymer devices ranged from 140 to $3600cd/m^2$ with maximum efficiencies from 0.2 to 0.6 cd/A. The enhanced efficiency of the PFFB (8/2) copolymer device results from the inhibition of excimer formation by the introduction of the electronegative fluorine moieties into the copolymers.

Anode-supported Type SOFCs based on Novel Low Temperature Ceramic Coating Process

  • Choi, Jong-Jin;Ahn, Cheol-Woo;Kim, Jong-Woo;Ryu, Jungho;Hahn, Byung-Dong;Yoon, Woon-Ha;Park, Dong-Soo
    • Journal of the Korean Ceramic Society
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    • v.52 no.5
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    • pp.338-343
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    • 2015
  • To prevent an interfacial reaction between the anode and the electrolyte layer during the conventional high-temperature co-firing process, an anode-supported type cell with a thin-film electrolyte was fabricated by low-temperature ceramic thick film coating process. Ni-GDC cermet composite was used as the anode material and YSZ was used as the electrolyte material. Open circuit voltage and maximum power density were found to strongly depend on the surface uniformity of the anode functional layer. By optimizing the microstructure of the anode functional layer, the open circuit voltage and maximum powder density of the cell increased to 1.11 V and $1.35W/cm^2$, respectively, at $750^{\circ}C$. When a GDC barrier layer was applied between the YSZ electrolyte and the LSCF cathode, the cell showed good stability, with almost no degradation up to 100 h. Anode-supported type SOFCs with high performance and good stability were fabricated using a coating process.

Comparative study of microstructure and mechanical properties for films with various deposition rate by magnetron sputtering

  • Nam, Kyung H.;Jung, Yun M.;Han, Jeon G.
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2000.11a
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    • pp.12-12
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    • 2000
  • This paper investigated the effect of the film deposition rate for $CrN_x$ microstructure and mechanical properties. For these purpose, pure Cr an stoichiometric CrN films were deposited with various target power density on Si hardened M2 tool steel. The variation of ni trogen concentration in $CrN_x$ f analyzed by AES and deposition rate was calculated by measuring of thickness using ${\alpha}-step$ profilometer. The microstructure was analyzed by X-Ray Diffract and Scanning Electron Microscopy(SEM), and mechanical properties were evalua residual stress, microhardness and adhesion tests. Deposition rate of Cr and CrN increased as an almost linear function of target power density from $0.25\mu\textrm{m}/min$ and $0.15\mu\textrm{m}/min$ to $0.43\mu\textrm{m}/min$. Residual stresses of Cr and CrN films were from tensi Ie to compressive stress with an increase of deposi tion rate a compressive stresses were increased as more augmentation of deposition r maximum hardness value of $2300kg/\textrm{mm}^2$ and the best adhesion strength correspond HF 1 were obtained for CrN film synthesized at the highest target densitY($13.2W/\textrm{mm}^2$) owing to high residual compressive stress and increasing mobility.

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Characterization and Analysis of Integrated RF Ferromagnetic Spiral Inductors (자성물질을 이용한 나선형 인덕터의 고주파 특성 분석)

  • Cha, S.Y.;Kim, G.B.;Jung, Y.C.;Choi, Y.S.;Cho, K.H.;Rieh, J.S.;Hwang, S.W.;Hyun, E.K.;Lee, S.R.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.12a
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    • pp.109-111
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    • 2006
  • This paper presents characterization and analysis of integrated ferromagnetic inductors in RF regime. Two different materials (CoFe/NiFe) are used as ferromagnetic material. Systematic studies of the inductance (L), the Q-factor (Q) and the structure of the inductor have been performed.

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Study on CeO2 Single Buffer on RABiTS for SmBCO coated Conductor (SmBCO 초전도 층착을 위한 RABiTS상의 CeO2 단일 버퍼 연구)

  • Kim, Tae-Hyung;Kim, Ho-Sup;Lee, Nam-Jin;Ha, Hong-Soo;Ko, Rock-Kil;Ha, Dong-Woo;Song, Kyu-Jeong;Oh, Sang-Soo;Park, Kyung-Chae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.6
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    • pp.546-549
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    • 2007
  • As a rule, high temperature superconducting coated conductors have multi-layered buffers consisting of seed, diffusion barrier and cap layers. Multi-buffer layer deposition requires longer fabrication time. This is one of main reasons which increases fabrication cost. Thus, single buffer layer deposition seems to be important for practical coated conductor process. In this study, a single layered buffer deposition of $CeO_2$ for low cost coated conductors has been tried using thermal evaporation technique. 100 nm-thick $CeO_2$ layers deposited by thermal evaporation were found to act as a diffusion layer. $1\;{\mu}m-thick$ SmBCO superconducting layers were deposited by thermal co-evaporation on the $CeO_2$ buffered Ni-5%W substrate. Critical current of 90 A/cm was obtained for the SmBCO coated conductors.

Microstructure and Piezoelectric Properties of PMW-PNN-PZT Ceramics with Bismuth Substitution (PMW-PNN-PZT 세라믹스의 Bismuth 치환에 따른 미세구조 및 압전 특성)

  • Kim, Yong-Jin;Yoo, Ju-Hyun;Shin, Dong-Chan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.6
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    • pp.332-336
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    • 2016
  • In this study, in order to develop the composition ceramics for ultrasonic sensor with high $d_{33}*g_{33}$, $Pb_{1-3x/2}Bix(Mg_{1/2}W_{1/2})_{0.03}(Ni_{1/3}Nb_{2/3})_{0.09}(Zr_{0.5}Ti_{0.5})_{0.88}O_3$(PMW-PNN-PZT) system ceramics were prepared using CuO as sintering aids. And then, their microstructure, piezoelectric and dielectric characteristics were systemetically investigated with bismuth substitution. The PMW-PNN-PZT ceramic specimens could be sintered at sintering temperature of $940^{\circ}C$ by adding sintering aids. At x=0.015 specimen, the density, electromechanical coupling factor($k_p$), dielectric constant, piezoelectric constant($d_{33}$) and piezoelectric figure of merit($d_{33}*g_{33}$) indicated the optimal properties of $7.90g/cm^3$, 0.67, 2,511, 628 pC/N, and $17.7pm^2/N$, respectively, for duplex ultrasonic sensor application.

Ferroelectric and Piezoelectric Properties of PMW-PNN-PZT Ceramics as a Function of BiFeO3 Substitution (BiFeO3 치환에 따른 PMW-PNN-PZT세라믹스의 강유전 및 압전 특성)

  • Ra, Cheol-Min;Yoo, Ju-Hyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.9
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    • pp.577-580
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    • 2015
  • In this paper, in order to develop the composition ceramics with the outstanding piezoelectric properties, $Pb(Mg_{1/2}W_{1/2})_{0.03}(Ni_{1/3}Nb_{2/3})_{0.09}(Zr_{0.5}Ti_{0.5})_{0.88}O_3$ ceramics substituted with $BiFeO_3$ were prepared by the conventional solid-state reaction method. The addition of small amount of $Li_2CO_3$ and $CaCO_3$ as sintering aids decreased the sintering temperature of the ceramics. The effects of $BiFeO_3$ substitution on their piezoelectric and dielectric properties were investigated. when 0.015 mol $BiFeO_3$ was substituted, the optimal physical properties of $d_{33}=590pC/N$, $E_c=8.78kV/mm$ were obtained.

Geochemical Study on Heavy Metal Pollution of Plants at Dalseong Abandoned Mine (달성폐광산 주변 식물의 중금속 오염에 대한 지화학적 연구)

  • Lee, Jae Yeong;Lee, In Ho;Kim, Suk Ki
    • Economic and Environmental Geology
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    • v.31 no.3
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    • pp.223-233
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    • 1998
  • The environments in the vicinity of the Dalseong mine has been much contaminated by heavy metals related to CuW ore deposit, which is of hydrothermal pipe type mineralized by quartz monzonite in the andesitic rocks. Chalcopyrite and wolframite are major ore minerals and sphalerite, galena and others are associated. To investigate the contamination of heavy metals in plants, samples of plants and soils were analysed by ICP for Fe, Mn, Cu, Pb, Zn, Ni, Co, Cd and Cr. Most of ore-related heavy metals are anomalously high in plants and soils, which were contaminated by the development of Taehan Tungsten Mining Company. The mine produced 48,704 tons (M/T) of 4 wt.% Cu and 1,620 tons (S/T) of 70 wt.% of $WO_3$ during active mining activity from 1961 to 1971 but was closed in 1975. Wild plants growing at the mine area may be used to remove heavy metals form soils, which cause contaminations of plants, stream waters and groundwaters in the vicinity of the mine.

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A Study on the Electrical Characteristics of Battery Capacitor Applied to Photovoltaic Power System (태양광 시스템에 적용한 배터리 커패시터의 전기적 특성에 관한 연구)

  • Mang, Ju-Cheul;Yoon, Jung-Rag
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.66 no.12
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    • pp.1740-1744
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    • 2017
  • This paper describes the preparation and characteristics of a battery capacitor and module for solar power system. A cylindrical 30,000F battery capacitor ($60{\times}138mm$) was assembled by using the $LTO(Li_4Ti_5O_{12})$ electrode as an anode and $NMC(LiNiMnCoO_2)-LCO(LiCoO_2)$ as a cathode. The battery capacitor has reduced energy density and power density under high CC(constant current) and CP(constant power) conditions. Battery capacitor module (16V, 11Ah) was fabricated using an asymmetric hybrid capacitor with a capacitance of 30,000F. In order to determine the characteristics of the battery capacitor Module for solar power system, battery capacitor cells were connected in series with active balancing circuit. As a result of measuring the 100w LED lamp, it was discharged at the voltage of 15V~10V, and the compensation time at discharge was measured to be about 4979s. Experimental results show that it can be applied to applications related to solar power system by applying battery capacitor module.

MEMS-based Micro Fluxgate Sensor Using Solenoid Excitation and Pick-up Coils (MEMS 공정 제작방법에 의한 솔레노이드형 여자 코일과 검출코일을 사용한 마이크로 플럭스게이트 센서)

  • 나경원;박해석;심동식;최원열;황준식;최상언
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.2
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    • pp.120-124
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    • 2003
  • This paper describes a MEMS-based micro-fluxgate magnetic sensing element using Ni$\_$0.8/Fe$\_$0.2/ film formed by electroplating. The micro-fluxgate magnetic sensor composed of a thin film magnetic core and micro-structure solenoids for the pick-up and the excitation coils, is developed by using MEMS technologies in order to take advantage of low-cost, small size and lower power consumption in the fabrication. A copper with 20${\mu}$m width and 3${\mu}$m thickness is electroplated on Cr (300${\AA}$) / Au (1500${\AA}$) films for the pick-up (42turn) and the excitation (24turn) coils. In order to improve the sensitivity of the sensing element, we designed the magnetic core into a rectangular-ring shape to reduce the magnetic flux leakage. An electroplated permalloy film with the thickness of 3${\mu}$m is obtained under 2000 gauss to induce magnetic anisotropy. The magnetic core has the high DC effective permeability of ~1,100 and coercive field of ~0.1 Oe. The fabricated sensing element using rectangular-ring shaped magnetic film has the sensitivity of about 150 V/T at the excitation frequency of 2 MHz and the excitation voltage of 4.4 V$\_$p p/. The power consumption is estimated to be 50mW.