• Proceedings of the Korean Ceranic Society Conference
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• 2003.10a
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• pp.189.2-189
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• 2003

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.3
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• pp.54-59
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• 2017

GGBFS (Ground Granulated Blast Furnace Slag) is a byproduct with engineering advantages and HVSC (High Volume Slag Concrete) is widely attempted due to active utilization and reduction of eco-load. In the present work, characteristics of drying shrinkage and early-aged behavior are evaluated for the concrete with 65% replacement ratio of GGBFS and 50MPa of design strength. For the work, 3 different mix conditions are considered and several tests including slump flow, compressive strength, drying and autogeneous shrinkage are performed. From the test, OPC 100 mixture without replacement shows higher strength development before 7 days, however the strength reduction in concrete replaced with GGBFS is not significant due to sufficient free water for cement hydration. OPC 100 mixture also shows significant drying shrinkage due to a great autogeneous shrinkage before 3 days. In the concrete with GGBFS replacement, the drying shrinkage behavior is improved due to relatively small deformation by autogeneous shrinkage. The mixture (OPT BS 65) with lower w/b ratio (0.27) and unit content of water ($160kg/m^3$) shows more improved shrinkage behavior than BS 65 mixture which has simple replacement of GGBFS with 0.30 of w/b and $165kg/m^3$ of water unit content.

• Journal of the Korean Magnetics Society
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• v.5 no.3
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• pp.191-196
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• 1995

NiCuZn ferrites were prepared by a solid-state reaction and sintered at $900^{\circ}C$ for 5 hours. Its properties were investigated by controlling the ferrite composition and processing. NiCuZn ferrite with a composition of ${(Ni_{0.2}Cu_{0.2}Zn_{0.6}O)}_{1.02}{(Fe_{2}O_{3})}_{0.98}$ was found to have the maximum initial permeability as a result of the variation of Cu content and the (Ni+Cu)/Zn ratio. Curie temperature($T_{c}$) of NiCuZn ferrite was decreased with the larger Cu content and increased with the larger Ni content. NiCuZn ferrites of ${(Ni_{0.2}Cu_{0.2}Zn_{0.6}O)}_{1-w}{(Fe_{2}O_{3})}_{1+w}$ composition milled for 20~80 hours had the maximum initial permeability at w=-0.015 and Curie temperature ($T_{c}$) was decreased with the increasing of $Fe_{2}O_{3}$ deficiency(w).

• Journal of Life Science
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• v.9 no.6
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• pp.733-736
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• 1999

The doubly altered mutant tryptophan synthase $\alpha$-subunits, in which Thr 24 was replaced by Ser, Leu or Lys in addition to F139W substitution, were purified. Urea-induced unfolding equilibrium curves of these proteins, monitored by fluorescence intensity of tryptophan, show that the alterations of residue 24 resulted in marked changes in folding properites, suggesting the importance of this residue in folding of this protein.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.07a
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• pp.539-542
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• 2004

전자기기의 발달과 더불어 정보통신분야의 발달로 고주파 대역에서 우수하고 안정적인 Ni-Zn 페라이트를 제조하기 위해, Ni(니켈)의 일부를 코발트(Co)로 치환하여 결정자기이방성 상수 값을 증가시켜, 공명 주파수를 고주파 대역으로 높이고자 하였다. Co 함량이 증가함에 따라 투자율은 감소하는데, 이는 결정자기 이방성 상수를 크게 하여 공명 주파수를 높이는 결과를 보였으며, x=0.05에서 투자율 75, 공명 주파수 20MHz의 특성을 나타내었다.

• Applied Chemistry for Engineering
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• v.3 no.3
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• pp.407-411
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• 1992

The effects of phase transfer catalyst was studied on the substitution of CO ligand of $Mo(CO)_6$ [M=Cr, Mo, W] with two electron-pairs donating ligands, 2, 2'-bipyridine and 2, 2'-biquinoline. The change of product yield, $M(CO)_4(L)_2$, was discussed according to reaction time, mole composition of $M(CO)_6$, and type of ligand.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.533-536
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• 2008

Recently, in Korea, there has been an increasing number of research papers published which are to improve durability of concrete, particularly by analyzing correlation between diffusivity of chloride and porosity/pore size distribution. In these studies, such test methods as mercury intrusion porosimetry(MIP), gas adsorption or image analysis method are used to analyze the microstructure of materials while MIP is most widely used for concrete. This study analyzes the results of porosity and pore size distribution of paste and concrete adding fly ash or blast furnace slag by using MIP equipment which is widely used for determining micro-porosity structure of cementitious materials. A variation in porosity and pore size distribution at the curing day 3, 7 and 28 has been observed by using MIP equipment for cement paste 35%, 40%, 45%, 50%, 55%, 60% of W/C when using $300kg/m^3$ of cement, 35%, 45%, 55% of W/C when replaced 60% with blast-furnace slag, and 35%, 45%, 55% of W/C when replaced 30% with fly ash. For long-term water cured normal OPC concrete and mixed concrete replaced 60% with blast-furnace slag powder, micro-structure of the sample has been analyzed by using MIP equipment when W/C indicated 40%, 45%, 50% respectively and the binder varied $300kg/m^3$, $350kg/m^3$, $400kg/m^3$, and $450kg/m^3$.

• Journal of the Korea Institute of Building Construction
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• v.9 no.5
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• pp.119-125
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• 2009

In this paper, the engineering properties and estimation of drying shrinkage of concrete incorporating fly ash (FA), blast furnace slag (BS) and cement kiln dust (CKD) were discussed. FA, BS and CKD contents ranged from 0% to 20%. Water to binder ratio (W/B) also ranged from 40 to 50 %, with a 5% interval. For estimating drying shrinkage, an exponential model proposed by the author was applied, According to results, the use of FA, BS and CKD resulted in a decrease of flowability and air contents. As expected, the use of admixtures also decreases the early age strength of concrete, while at later age, due to a pozzolanic reaction of FA and BS, the compressive strength was recovered to a value comparable with that of plain concrete. For drying shrinkage, the use of admixtures led to an increase in the drying shrinkage of concrete. The exponential model suggested by the author showed good agreement between the calculated and experimental values both at early age and at later age.

• Korean Journal of Food Science and Technology
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• v.39 no.5
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• pp.584-587
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• 2007

The effect of molar substitution (MS, 0.030-0.118) on the dynamic rheological properties of hydroxypropylated rice starch pastes (5%, w/w) was investigated by small-deformation oscillatory measurements during aging. The magnitudes of storage (G#) and loss (G") moduli measured at $4^{\circ}C$ before aging increased with an increase in MS in the range of 0.030-0.118, while those of tan ${\delta}$ (the ratio of G"/G#) decreased. The G# values of hydroxypropylated rice starches, as a function of aging time (10 hr) at $4^{\circ}C$, increased rapidly at the initial stage, and then reached a plateau region at shorter aging times. However, for the native starch, the plateau values were not observed for G# after a long aging time. Increasing the MS resulted in a decrease in plateau values. The rate constant (K) for structure development during aging was described by first-order kinetics. The K values of hydroxypropylated rice starches at 0.086 and 0.118 MS were much lower than the K value at 0.030 MS.

• Korean Journal of Crystallography
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• v.1 no.2
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• pp.76-83
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• 1990

The structures of dehydrated fully Ca2+ _exchanged zeolite A (a: 12.2a3(2) A and of its iodine sorption complex (a=12.258(2) A) have been determined by single-crystal X-ray diffraction methods in the cubic space group. Pm3m at 21(1)℃.the structures were refined to final R(weighted) indices of 0.081 with 206 reflections and 0.084 with 173 reflections, respectively for which I>3 w (I). In each structure. six divalent cations are located on three different theefold axes associated with 6-ring oxygens. Dehydrated Ca2+_A sorbs ca. 6.0 diiodine molecules per unit cell at 80℃(vapor pressure of I: is ca. 14.3 Torr). Each iodine molecule makes a close approach. along its ahs to framework oxygen atom with I-I distance of 2.71(2) A, I-O distance of 3.32(3) k. and I-I-0=180℃. The result indicates that diiodine molecule forms charge transfer complex with framework oxygen.