• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2016년도 춘계 학술논문 발표대회
• /
• pp.45-46
• /
• 2016

As the demand for super tall buildings is currently increased in domestic and foreign countries, some kinds of ultra-high strength concretes are being developed actively. Since the cross section of concrete becomes smaller thanks to such kinds of ultra-high strength concretes, the concrete structures can be much bigger, more gigantic and much ultra-high. And as another benefit which is generated thanks to the enhancement of the durability performance, the maintenance expenses are also saved. However, since low W/B ultra-high concrete has a high possibility that many cracks can occur in the initial period due to the self-shrinkage caused by the self-desiccation as one of the blending characteristics, the problem becomes bigger by influencing the safety of a structure. Therefore, in this study, it is intended to analyze the effects of substituting some limestone-based ultra-high strength mortar with electric arc furnace oxidizing slag fine aggregates on the self-shrinkage of mortar.

• 한국원자력학회:학술대회논문집
• /
• 한국원자력학회 1995년도 추계학술발표회논문집(2)
• /
• pp.668-673
• /
• 1995

$UO_2$-CeO$_2$ 모의혼합분말에 첨가제를 미량 첨가하여 소결체의 미세구조 변화를 $UO_2$분말의 경우와 비교, 관찰하였다. 소결 첨가제로서 Ta, Ti 및 Nb를 사용하였으며, 이들을 미세한 산화물의 형태로 $UO_2$ 및 $UO_2$-CeO$_2$에 첨가하여 환원성 및 산화성 분위기에서 각각 소결하였다. Ta, Ti 및 Nb는 환원소결에서 $UO_2$의 결정립을 성장시켰으나 산화소결에서는 첨가효과가 크게 나타나지 않았다. $UO_2$-0.lw%TiO$_2$와 $UO_2$-0.6w%Ta$_2$O$_{5}$의 환원소결체에서 eutectic phase가 관찰되었으나 산화소결체에서는 나타나지 않았다. $UO_2$-4wt%CeO$_2$의 환원소결에서는 Ti만이 결정립성장에 기여하는 것으로 나타났으며 Ta, Nb와 같이 $UO_2$에 치환형으로 고유되는 원소는 Ce 이온과 Cluster를 형성함으로 결정립성장에 거의 기여하지 못하고, Ti와 같이 UO2$_2$ 침입형으로 고용되는 원소는 일부가 인접한 Ce$_{U}$' 이온과 cluster를 형성하더라도 나머지가 V$_{U}$'의 형성에 기여하므로서 결정립을 성장시킬 수 있다.

• 한국건설순환자원학회논문집
• /
• 제7권3호
• /
• pp.85-90
• /
• 2012

In this study, temperature profile of the fly ash concrete were studied in accordance with the change of heating curing method combination for the slab concrete in order to develop efficient protection method of the concrete subjected to $-20^{\circ}C$. The slab concretes with the size of $1200mm{\times}600mm{\times}200mm$ were fabricated with W/B of 50% and exposed to $-20^{\circ}C$ for 7 days. Five different combinations of heat curing methods were applied to the slab concrete specimen; two combinations of heat supplying by electrical heater and surface heat insulation material such as polyethylene film and quadrupled layer bubble sheet based on heat enclosure installment; three combinations of heating coil embedment and surface heat insulation materials such as polyethylene film, sawdust and quadrupled layer bubble sheet based on heat enclosure installment. Test results showed that by applying both heating coil and bubble sheet and heat enclosure, the concrete exposed to $-20^{\circ}C$ can be effectively protected from early-age frost damage.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2007년도 추계 학술논문 발표대회
• /
• pp.67-70
• /
• 2007

In this study, the characteristic of strength development of high volume fly ash concrete(HVFAC) was experimentally investigated. The production of one ton of portland cement releases about 0.87ton of CO2 into the atmosphere. HVFAC is an emerging material technology and is environmentally friendly because of its reduced use of portland cement, reduced CO2 emissions. For this purpose, two levels of W/B were selected. Seven levels of fly ash replacement ratios and two levels of silica fume replacement ratios were adopted. In the concrete mix, the water content of 125kg/m3 was used, which is less than that of usual water content. As a result, it was observed that the slump of concrete was increased with the increasing fly ash replacement ratio and when the silica fume was incorporated into the concrete, the slump was significantly decreased at the same condition. It appeared that the compressive strength gradually decreased with increasing fly ash replacement ratio at the early age, but the difference of strength up to replacement ratio of 50% was little at the age of 91 days because of the pozzolanic reaction of fly ash.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2007년도 추계 학술논문 발표대회
• /
• pp.133-136
• /
• 2007

This study investigates mechanical properties of the concrete using fine particle cement which is manufactured by the pulverizing process. The variable factors are 3 types of W/C such as 40, 50, and 60%, 3 types of curing temperature such as 5, 20, and $35^{\circ}C$, and 5types of the replacement of the fine particle cement such as 0, 25, 50, 75, and 100%. The unit water content, S/a and amount of the SP and AE agents to secure the slump and air content is gradually increased in accordance with amount of replacement. It can be confirmed that the delay of the setting time depending on FC content is decreased corresponding to FC content, so the effect of the acceleration to the setting time is expected. The compressive strength corresponding to FC content is proportionally increased, and the growth is confirmed about $30{\sim}40%$ at a day in 50% of FC contents. However, the increase of the strength is gradually decreased in accordance with increasing age.

• 대한화학회지
• /
• 제34권1호
• /
• pp.85-90
• /
• 1990

Tetrakis(picolinato)tungsten(IV) 착물에 과량의 methylpicolinic acid를 가하여, 무극성 용액에서 얼마나 inert한지를 60 ~ 120$^{\circ}C$ 및 키실렌의 환류조건에서 분광학적 방법을 관찰하였다. 산소접촉 여부에 무관하게 90$^{\circ}C$에서 2일간은 inert하였으나 산소접촉하에서는 존재하는 리간드농도 제곱에 역비례하는 속도상수를 보이며 급격히 산화되며 리간드를 잃었다. Ar기체하에서 sealing한 시료는 반응속도상수 [k($sec^{-1}$)] = $8.8{\times} 10^{-7}$를 보이며 50일까지 반응속도론적으로 안정하였다. 배위된 질소의 인접 양성자($H_6$)의 화학적 이동은 없었으나 리간드를 잃음에 따라 intensity가 감소하였으며 새로운 유리리간드의 $H_6$ peak가 생성됨을 확인하여 치환반응은 일어나지 않고 착물이 산화되며 리간드를 잃고 있음을 확인하였다.

• 전기학회논문지
• /
• 제60권3호
• /
• pp.584-587
• /
• 2011

In this work, the $TiO_2$ and $SnO_2$ thin films as blocking layers were coated directly onto the metal-mesh electrode surface to prevent unnecessary inflow of back-transfer electrons from the electrolyte ($I^-/I_3^-$) to the metal-mesh electrode. The DSCs were fabricated with working electrode of SUS mesh coated with blocking $TiO_2$ and $SnO_2$ layers, dye-attached mesoporous $TiO_2$ film, gel electrolyte and counter electrode of Pt-deposited F:$SnO_2$. From the experimental result, it was ascertained that the efficiency of metal electrode coated with $TiO_2$ by Dip-coating was superior to that of metal electrode coated with $SnO_2$ by Dip-coating and screen printing with the results of experiments. The photo-current conversion efficiency of the cell obtained from optimum fabrication condition was 3% ($V_{oc}$=0.61V, $J_{sc}$=11.64 mA/$cm^2$, ff=0.64) under AM1.5, 100 mW/$cm^2$ illumination.

• 한국전기전자재료학회논문지
• /
• 제29권6호
• /
• pp.332-336
• /
• 2016

In this study, in order to develop the composition ceramics for ultrasonic sensor with high $d_{33}*g_{33}$, $Pb_{1-3x/2}Bix(Mg_{1/2}W_{1/2})_{0.03}(Ni_{1/3}Nb_{2/3})_{0.09}(Zr_{0.5}Ti_{0.5})_{0.88}O_3$(PMW-PNN-PZT) system ceramics were prepared using CuO as sintering aids. And then, their microstructure, piezoelectric and dielectric characteristics were systemetically investigated with bismuth substitution. The PMW-PNN-PZT ceramic specimens could be sintered at sintering temperature of $940^{\circ}C$ by adding sintering aids. At x=0.015 specimen, the density, electromechanical coupling factor($k_p$), dielectric constant, piezoelectric constant($d_{33}$) and piezoelectric figure of merit($d_{33}*g_{33}$) indicated the optimal properties of $7.90g/cm^3$, 0.67, 2,511, 628 pC/N, and $17.7pm^2/N$, respectively, for duplex ultrasonic sensor application.

• 한국전기전자재료학회논문지
• /
• 제28권9호
• /
• pp.577-580
• /
• 2015

In this paper, in order to develop the composition ceramics with the outstanding piezoelectric properties, $Pb(Mg_{1/2}W_{1/2})_{0.03}(Ni_{1/3}Nb_{2/3})_{0.09}(Zr_{0.5}Ti_{0.5})_{0.88}O_3$ ceramics substituted with $BiFeO_3$ were prepared by the conventional solid-state reaction method. The addition of small amount of $Li_2CO_3$ and $CaCO_3$ as sintering aids decreased the sintering temperature of the ceramics. The effects of $BiFeO_3$ substitution on their piezoelectric and dielectric properties were investigated. when 0.015 mol $BiFeO_3$ was substituted, the optimal physical properties of $d_{33}=590pC/N$, $E_c=8.78kV/mm$ were obtained.

• 한국재료학회지
• /
• 제6권11호
• /
• pp.1099-1106
• /
• 1996

니켈-수소화물전지의 음극재료로서 주목을 받고 있는 다원계 Zr기 Laves 합금의 조성에 따른 결정구조, 방전특성등을 조사하였다. 전극은 아크 용해한 합금을 분쇄한 분말과 PVA를 다공성니켈 foam에 충진하여 제작하였고 충방전시험은 6M KOH 용액중에서 수행하였다. 대상 합금은 ZrNi2를 기본조성으로 하여 이중 Ni의 일부를 V, Mn, Cr, Mo 또는 W로 치환한 삼원계 및 사원계 합금이었다. 이들 합금의 충방전 실험결과 ZrV0.5Mn0.5Ni1.0의 경우가 260 mAh/g로 가장 높은 방전용량을 나타내었다. 이 합금의 방전용량은 방전전류밀도의 영향을 크게 받았으며 10 mA/g과 200mA/g의 방전전류에서 각각 300mAh/g와 150mAh/g이었다. 이 합금을 110$0^{\circ}C$에서 열처리한 경우 저율방전시에는 방전용량의 변화가 거의 없었으나 수소의 확산이 율속이 될 것으로 생각되는 고율 방잔시에서는 방전용량이 현저하게 감소하였다. 이러한 현상은 열처리에 의해 수소의확산을 용이하게 해주는 격자결함이 감소하기 때문이 아닌가 생각된다.