• Applied Biological Chemistry
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• v.37 no.2
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• pp.124-129
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• 1994

The rate of hydrolysis of insecticidal $O,O-diethyl-{\alpha}-cyanobenzylideneamino-oxyphosphorothioate\;(Volaton^{\circledR})$ has been studied in 25% (v/v) aqueous dioxane. On the basis of solvent effect (pH 6.0; m=0.21, n=1.55, pH 12.0; m=0.42, n=3.14 & $|m|{\ll}|l|$), general base catalysis, hydrolysis product analysis, calculation of molecular orbital (MO) and rate equation, it may be concluded that the hydrolysis of Volaton proceeds through the $A_{AC}2$ mechanism via trigonal bipyramidal $(sp^3d^2)$ intermediate below pH 7.0, while above pH 9.0 the hydrolysis proceeds through the $B_{AC}2$ mechanism. Hydrolysis reactivity of Volaton depends on positive charge strength $(p{\gg}{\alpha}C_2)$ rather than steric hindrance. In the range between pH 7.0 and pH 9.0, these two reactions occur competitively.

• Korean journal of applied entomology
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• v.19 no.4 s.45
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• pp.243-248
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• 1980

Experiments were conducted to study on bionomics and control of cutworms; Agrotis tokionis, A. ipsilon, A. fucosa in Suweon, 1978-1979. A. ipsilon and A. fucosa had two or three generations and A. tokionis had one generation a year. A large number of A. toikonis occured at the end of September, and the major peaks of the first generation of A. tokionis and A. fucosa were in mid-June, the second generation in mid-August, and the third generation was at the end of September. These cutworms laid many eggs on the lower surface of curved downward leaf of Chinese cabbage and the larvae later than 3rd instar began to cut the basal part of stem and then pulled into the soil. A parasite of A. tokionis, a braconid wasp, Meteorus rubens, and two unidentified Ichneumnid wasps were found. Mocap and Volaton gave effective control to the cutworms but Volaton should be applied not to contact with plant.

• Korean journal of applied entomology
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• v.19 no.2 s.43
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• pp.79-83
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• 1980

The toxicities of some soil insecticides were evaluated in terms of the tolerance to various larval-ins tars of the common cutworm (Agrotis fucosa Butler) using topical application method in the laboratory. $LD_{50}$ values(ug/larva) were determined by the probit analysis and the tolerance-values were obtained with '$LD_{50}$ values for from 2nd-to 6th-instars/$LD_{50}$ values for first-instars.' The relative toxicities of the insecticides were 31so compared with the $LD_{50}$ values for the instars. The degree of tolerance was greatly increased as the larval instar advanced; the ranges of tolerance between the first-and 6th-instar larvae to the insecticides phoxim (Volaton), diazinon, chlorpyrifos (Dursban), carbofuran (Curaterr) and Mocap were 251.6, 126.6, 97.5, 44.3, and 18.7 times, respectively. The average relative toxicities of the insecticides for the instars indicated that the toxicity of phoxim was the greatest and following carbofuran, chlorpyrifos, Mocap and diazinon.