• Title/Summary/Keyword: Volatile matter

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Effect of Coal Properties on Combustion Characteristics in a Pulverized Coal Fired Furnace (미분탄 연소로에서 연소특성에 미치는 석탄특성에 관한 연구)

  • Lee, Byoung-Hwa;Song, Ju-Hun;Lee, Cheon-Sung;Chang, Young-June;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.10
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    • pp.737-747
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    • 2009
  • This study is to investigate the effect of the moisture, volatile matter and particle size in the coal on the pulverized coal combustion characteristics using CFD. The results show that as the moisture content in coal increases, flame temperature decreases because of heat loss driven from latent heat of vaporization and reduction of heating value. As the volatile matter content in the coal increases, the temperature in the region near the burner increases, while the temperature in rear region of boiler decreases. The solution to keep the temperature in the rear region of boiler is suggested that particle size is needed to be larger. As the particle size increases, the temperature in the rear region of boiler show tendency to increase, for combustion burning time of coal could be extended.

Effect of volatile matter and oxygen concentration on tar and soot yield depending on low calorific coal in Laminar Flow Reactor (저열량탄의 휘발분과 산소농도가 Tar와 Soot의 발생률에 미치는 영향)

  • Jeong, Tae Yong;Kim, Jin Ho;Lee, Byoung Hwa;Song, Ju Hun;Jeon, Chung-Hwan
    • 한국연소학회:학술대회논문집
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    • 2012.04a
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    • pp.209-212
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    • 2012
  • This study was performed to analyze coal flames and measure tar and soot yields and structures of chars for two coals depending on the volatile content by the LFR(Laminar Flow Reactor) which can be applied to a variety of coal researches. The results show that volatile contents and oxygen concentration have significant influence on length and width of the soot cloud and it also indicate that the length and width of the cloud in condition of combustion decrease than those of pyrolysis atmosphere. Until the sampling height reach at 50 mm, the tar and soot yields of Berau (Sub-bituminous) coal contained relatively lots of volatile matters are less than those of Glencore A.P. (Bituminous) coal. On the other hand, tar and soot yields of Berau coal are higher than those of Glencore A.P. coal by reacted residual volatile matter. In addition, the images of samples obtained from the particle separation system of the sampling probe support for above results with the yields, and the pore development of char surface by devolatilization.

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Volatile compounds and some physico-chemical properties of pastırma produced with different nitrate levels

  • Akkose, Ahmet;Unal, Nazen;Yalinkilic, Baris;Kaban, Guzin;Kaya, Mukerrem
    • Asian-Australasian Journal of Animal Sciences
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    • v.30 no.8
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    • pp.1168-1174
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    • 2017
  • Objective: The aim of the study was to evaluate the effects of different nitrate levels (150, 300, 450, and 600 ppm $KNO_3$) on the volatile compounds and some other properties of pastırma. Methods: Pastırma samples were produced under the controlled condition and analyses of volatile compounds, and thiobarbituric acid reactive substances (TBARS) as an indicator of lipid oxidation, non-protein nitrogenous matter content as an indicator of proteolysis, color and residual nitrite were carried out on the final product. The profile of volatile compounds of pastırma samples was analyzed by gas chromatography/mass spectrometry using a solid phase microextraction. Results: Nitrate level had a significant effect on pH value (p<0.05) and a very significant effect on TBARS value (p<0.01). No significant differences were determined in terms of $a_w$ value, non-protein nitrogenous substance content, color and residual nitrite between pastırma groups produced by using different nitrate levels. Nitrate level had a significant (p<0.05) or a very significant (p<0.01) effect on some volatile compounds. It was determined that the amounts and counts of volatile compounds were lower in the 450 and especially 600 ppm nitrate levels than 150 and 300 ppm nitrate levels (p<0.05). While the use of 600 ppm nitrate did not cause an increase in residual nitrite levels, the use of 150 ppm nitrate did not negatively affect the color of pastırma. However, the levels of volatile compounds decreased with an increasing level of nitrate. Conclusion: The use of 600 ppm nitrate is not a risk in terms of residual nitrite in pastırma produced under controlled condition, however, this level is not suitable due to decrease in the amount of volatile compounds.

A Study on Combustion Characteristics of Pulverized Fuel Made from Food Waste (음식물쓰레기로 부터 제조한 분체연료 연소특성)

  • Son, Hyun-Suk;Park, Yung-Sung;Kim, Sang-Guk
    • New & Renewable Energy
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    • v.4 no.4
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    • pp.37-43
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    • 2008
  • Three properties of food waste are water 80%, ash 3%, volatile matter 17%. When food waste goes through treatment process such as removal of foreign substances, removal of water as well as sodium, dryness, and pulverization, it transforms into 4,000 Kcal/kg purverized fuel if moisture content is below 13%. Fuel ratio (fixed carbon/volatile matter) of purverized fuel is low compared with bituminuous coal. Ignition temperature measured by thermogravimetry analyzer is about $460^{\circ}C$. Combustion test of purverized fuel have been performed using energy recovery facility which include storage tank of dewatered cake, dryer, hammer mill, combuster including burner, boiler, flue gas treatment equipment. When 160-180 kg/hr of fuel is steadily supplied to burner for 3 hours, combustor temperature reaches about $1000^{\circ}C$ and CO is 77-103 ppm at 1.55 excess air ratio and SOx and Cl are under 2 ppm and 1ppm, respectively. This experiment demonstrate that purverized fuel made from food waste could be an alternative clean energy at the age of high oil price.

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A Study on Combustion Characteristics of Purverized Fuel Made from Food Waste (음식물쓰레기로부터 제조한 분체연료 연소특성)

  • Son, Hyun-Suk;Park, Yung-Sung;Yun, Jong-Deuk;Lee, Ho-Nam;Lee, Seung-Hoon;Kim, Sang-Guk
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.149-152
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    • 2008
  • Three properties of food waste are water 80%, ash 3%, volatile matter 17%. When food waste goes through treatment process such as removal of foreign substances, removal of water as well as sodium, dryness, and pulverization, it transforms into 4,000Kcal/kg purverized fuel if moisture content is below 13%. Fuel ratio(fixed carbon/volatile matter) of purverized fuel is low compared with bituminuous coal. Ignition temperature measured by thermogravimetry analyzer is about $460^{\circ}C$. Combustion test of purverized fuel have been performed using energy recovery facility which include storage tank of dewatered cake, dryer, hammer mill, combuster including burner, boiler, flue gas treatment equipment. When 160-180 kg/hr of fuel is steadily supplied to burner for 3 hours, combueter temperature reaches about $1000^{\circ}C$ and CO is 77-103ppm at 1.55 excess air ratio and SOx and Cl are under 2ppm and 1ppm, respectively. This experiment demonstrate that purverized fuel made from food waste could be an alternative clean energy for high oil price era

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Influence of Organic Matter and Temperature on the Sorption of Volatile Organic Compounds on Soil (토양 흡착에 대한 유기탄소와 온도의 영향)

  • 김희경
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1998.11a
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    • pp.57-59
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    • 1998
  • The headspace method has been acknowledged as a cost-effective and convenient method to analyze volatile organic compounds(VOCs) in soil. The headspace analysis is based on equilibrium partitioning of VOCs among water, air and soil in a closed system. However, the headspace method cannot be applied to soils where most of the VOCs remain sorbed even at high temperature. In this study, it was investigated how the sorption characteristics of VOCs varied with soil with different organic carbon contents and temperature. This study showed that all the VOCs were volatilized, not sorved, only in the soil with 5% organic carbon at 45$^{\circ}C$ or higher. Some fraction of VOCs remained in soil with 8% organic carbon at $65^{\circ}C$ of higher. Most of the VOCs remained sorbed in soil with 12% organic content even at 95$^{\circ}C$. This result suggested that the headspace method can be applied only to soils with little organic carbon content (less than 5%). In this case, 45$^{\circ}C$ seems to be high enough to volatilize all the VOCs from soil. Large particles still showed a significant sorption capacity for VOCs from soil. Large Particles still showed a significant sorption capacity for VOCs despite of their low level of organic carbon content. It was also shown that the organic carbon sorption coefficients (Koc) of VOCs varied with soils with different organic carbon content. This suggests that not only the organic matter content of soil but also the property of the organic matter in soil influence the sorption of VOCs to soil.

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Effect of Several Native Moss Plants on Particulate Matter, Volatile Organic Compounds and Air Composition

  • Gong, Gyeong Yeop;Kang, Ji Su;Jeong, Kyeong Jin;Jeong, Jun Ho;Yun, Jae Gill
    • Journal of People, Plants, and Environment
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    • v.22 no.1
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    • pp.31-38
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    • 2019
  • Experiments were carried out to investigate the effects of mosses on the removal of particulate matter (PM 10) and volatile organic compounds (VOCs) in an indoor space and on the composition of air. For particulate matter removal experiments, 0.2 g mosquitto coil was burned in a glass chamber, where three kinds of mosses (Plagiomnium cuspidatum, Myuroclada maximowiczii, Etodon luridus) were placed. For VOCs removal experiments, 1 mL paint thinner was volatilized in a glass chamber, where Plagiomnium cuspidatum and Myuroclada maximowiczii were used. As a result, it was found that particulate matter was effectively removed by the three mosses, and the removal efficiency of particulate matter increased as the amount of mosses increased. The amount of VOCs was similar to the level in the control when a low amount of mosses (2 and 4 plates) was used. However, the removal efficiency of VOCs was significant when 6 plates of mosses were used. On the other hand, formaldehyde concentration was 40 times more than the control and carbon monoxide 30 times, when 0.2 g of mosquito repellent was completely burned in a glass chamber. Also formaldehyde removal effect was significant when 6 plates of mosses were placed. However, there was no change in the concentration of indoor oxygen, temperature and humidity by moss plants. In conclusion, the moss plants were effective in removing particulate matter and VOCs, and they are expected to be used for indoor decoration and landscape in order to improve indoor air quality in the future.

Experimental and Numerical Study on the Gas Mixing and Reaction in the Freeboard of a Fluidized Bed Incinerator for Sludge Treatment (슬러지 유동층 소각로의 프리보드 내 가스 혼합 및 반응 특성에 대한 실험 및 해석적 연구)

  • Kim, Young-Min;Shin, Dong-Hoon;Hwang, Seung-Sik
    • Journal of the Korean Society of Combustion
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    • v.16 no.4
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    • pp.8-15
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    • 2011
  • The present study investigates the combustion phenomena in a sludge incinerator using experimental and numerical method. The temperature and gas concentration were measured at 33 points during operation of the incinerator in order to assess the mixing and combustion characteristics. Numerical simulation was also carried out using a commercial CFD code. Simplified inlet conditions were introduced in oder to predict the bulk solid combustion and the diffusion of the volatile matter released by pyrolysis of sludge. The experimental results showed that the combustion process is extremely inhomogeneous. Large variations were observed in the temperature and gas concentrations in the freeboard of the incinerator due to poor mixing performance between the air and the combustibles, which is caused by massive and bulk generation of volatile matter by fast pyrolysis of sludge particles. The boundary condition of the CFD simulation was found effective in predicting the poor mixing and combustion performance of the reactor.

Numerical Study on the Devolatilization models of Pulverized Coal in DTF (DTF 내 미분탄 휘발화 모델에 관한 수치적 연구)

  • Kim, Jin-Nam;Kim, Ho-Young
    • 한국연소학회:학술대회논문집
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    • 2002.11a
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    • pp.173-184
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    • 2002
  • In order to evaluate the devolatilization models of pulverized coal, various devolatilization models are examined for the numerical analysis of Drop Tube Furnace.The results of analysis are compared with the experimental results. A numerical study was conducted to explore the sensitivities of the predictions to variation of the model parameters. It helps to elucidate the source of the discrepancies. Three different wall temperature conditions of the DTF, 1100, 1300 and $1500^{\circ}C$ were considered in this analysis. Two fuels are U.S.A. Alaska coal and Australia Drayton coal. The results of analysis with constant rate model, single kinetic rate model and two competing rate modes well presented fast volatile matter release in the early devolatilization. However, in the latter devolatilization they did not coincide with experimental results which presented tardy volatile matter release on account of pyrolysis of high molecular substance. On the other hand, the results of analysis with DAEM(Distribute Activation Energy Model) coincided with experiment al results in overall devolatilization.

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Optimization of Process Parameters for Dry Film Thickness to Achieve Superior Water-based Coating in Automotive Industries

  • Prasad, Pranay Kant;Singh, Abhinav Kr;Singh, Sandeep;Prasad, Shailesh Kumar;Pati, Sudhanshu Shekher
    • Corrosion Science and Technology
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    • v.21 no.2
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    • pp.121-129
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    • 2022
  • A study on water-based epoxy coated on mild steel using the electroplating method was conducted to optimize the process parameters for dry film thickness to achieve superior paint quality at optimal cost in an automotive plant. The regression model was used to adjust various parameters such as electrode voltage, bath temperature, processing time, non-volatile matter, and surface area to optimize the dry film thickness. The average dry film thickness computed using the model was in the range of 15 - 35 ㎛. The error in the computed dry film thickness with reference to the experimentally measured dry film thickness value was - 0.5809%, which was well within the acceptable limits of all paint shop standards. Our study showed that the dry film thickness on mild steel was more sensitive to electrode voltage and bath temperature than processing time. Further, the presence of non-volatile matter was found to have the maximum impact on dry film thickness.