• Journal of Environmental Science International
• /
• v.29 no.6
• /
• pp.673-682
• /
• 2020

This study investigates the concentration distribution of aldehydes and volatile organic compounds (VOCs) in the archive of the National Library in Korea and evaluates the health risks to workers from hazardous chemicals. Acetaldehyde had the highest concentration among the nine species of aldehydes present in the archive and the concentration of toluene was the highest among the six species of VOCs. Most of the detected substances showed that their indoor concentrations were higher than the outdoor ones, suggesting the possibility of indoor sources of aldehydes and VOCs. The evaluation of health risks for workers based on these measurement results showed that not all substances were hazardous to the human body. However, considering the possibility of the presence of indoor sources and the potential limits of our study owing its short period, it is necessary to conduct long-term studies on the concentration distribution of indoor pollutants in the archive environment.

• Journal of Environmental Health Sciences
• /
• v.42 no.1
• /
• pp.61-70
• /
• 2016

Objectives: The purpose of this study is to determine the exposure risk to tattoo components by analyzing skin absorption using the in vitro method. Tattoos are commonly used for cosmetic purposes, and the skin of not only the operator but of the people who are undergoing the cosmetic procedure is continuously exposed to hazardous chemicals. Methods: Skin permeation risk determination was conducted by the in vitro Franz diffusion cell method according to the ingredient types of tattoo dyes, such as volatile organic compounds (VOCs), non-volatile organic compounds and heavy metals, using hairless mouse full skin and human cadaver epidermis. Results: The major components with good skin penetration for each type of tattoo dye ingredient were clarified. Among the tatto dye ingredients, 1,2-Dichlorobenzene, Zn, Al, Pb and Ti showed good skin penetration. Most of the skin transmission rates were higher in hairless mouse full skin than in human cadaver epidermis. Conclusion: A possible exposure risk to hazardous substances in tattoo dyes was confirmed from this study. These results are expected to provide a positive contribution to the establishment of management regulations for tattoo dyes.

• Journal of the Korean Society of Safety
• /
• v.21 no.1 s.73
• /
• pp.133-140
• /
• 2006

According to Tokyo protocol which suggests the prevention of global environmental pollution, Korean government establishes the standard of architectural materials emission consistency with best effort to decrease the environmental pollution. But many current architectural materials which are used for constructing and remodeling buildings are composed of a variety of chemicals. These include stimuli bad for the residents' health and safety and harmful discharged air polluting substances such as volatile organic compounds(TVOCs) and formaldehyde(HCHO) that in tern include a variety of carcinogen substances. These discharged substances are also researched into inducing 'sick building syndrome' which induces headache, dizziness, vomiting and concentration failure among residents. But the standard of architectural materials according to the Korean apartment provision is limited to emission factors: HCHO and TVOCs. So the aim of this study is to present a standard of functional material's emission consistency about TVOCs including glues and paints, and a certification grade for green building by instituting a materials standard for green building which has consideration for the residents' safety.

• Proceedings of the SAREK Conference
• /
• 2008.06a
• /
• pp.742-747
• /
• 2008

Formaldehyde(HCHO) and total volatile organic compounds(VOCs) can cause adverse health effects to the building occupants and may contribute to symptoms of 'Sick Building Syndrome'. These chemical contaminants are emitted from furnishings and electronic equipments as well as building materials. The purpose of this study is to measure and analyze VOCs and HCHO emission concentration from furnitures composed of wood materials including various chemicals by the large chamber method. This paper presents experiment results on the emission concentration of TVOCs and HCHO released from furnitures, such as bed, kitchen, sofa and table by a large chamber($24m^3$). The temperature and air humidity in the chamber are controlled to $25{\pm}1{\circ}C$ and $50{\pm}5%$ for this experiment. When the air change rate is $0.5hr^{-1}$, the background concentrations within the large chamber are below $50{\mu}g/m^3$ for TVOC, $5{\mu}g/m^3$ for HCHO and individual VOCs. The study is investigated the characterization of the chemical emission TVOC and HCHO concentrations and unknown VOCs from 6 furnitures.

• Journal of Environmental Health Sciences
• /
• v.37 no.3
• /
• pp.201-208
• /
• 2011

Objective: Emissions of volatile organic compounds (VOCs) from municipal wastewater treatment plants and industrial wastewater are often overlooked as sources of exposure to toxic chemicals. VOCs from such sources evaporate readily into the air and may have significantly adverse impacts on public health. The present study aimed to establish the concentration of VOCs released from Jangrim-sinpyoeng Municipal and Industrial Wastewater Treatment plant (JWTP) in Busan, South Korea and assess the causes of the odor/stench in the surrounding residential facilities. Stench intensity, frequency and release time, and wind direction were also monitored. Methods: Onsite data were collected on a daily basis from a laboratory located on the JWTP premises through a period spanning 2006 to 2010. A second set of data was obtained in 2006 by conducting a questionnaire survey with 210 respondents living near JWTP. The experimental and survey data were analysed statistically using the SPSS package. Results: The survey results showed that people residing around JWTP strongly perceive a stench from the plant. The intensity of the stench was influenced significantly by wind direction and the location of the apartments facing the JWTP. Public participation formed a significant step in determining the quality of the study environment. Conclusion: Onsite data and survey data obtained in 2006 indicate that the nature of the odor experienced by residents is due to the intensity of total VOCs released by JWTP. However, additional research is needed to determine the effects of the VOC pollution on public health and quality of life.

• Korean Journal of Food Science and Technology
• /
• v.16 no.1
• /
• pp.71-77
• /
• 1984

A study on the stability of chlorophyll a in Undaria pinnatifida during blanching, salting and storage was carried out. Raw Undaria pinnatifida was blanched for 25 seconds in the temperature range of 70 to $100^{\circ}C$. To stabilize the chlorophyll a some chemicals such as 1% solutions of $Ca(CH_3CO_2)_2,{\;}Ca(OH)_2,{\;}MgCO_3,{\;}0.5%{\;}Ca(CH_3CO_2)_2$ with $0.5%{\;}MgCO_3$, and reed ash solution were used during/after blanching. The blanched product was salted with table salt after centrifuging for 2 minutes at 1500 rpm, and then again centrifuged after 48 hours for dewatering. The product which was mixed with 8% of table salt was sealed in a polyethylene film bag and stored at 10, 20, 30 and $40^{\circ}C$. The most effective blanching temperature for maximal residual amount of chlorophyll a was $85^{\circ}C$. The quantities of total organic and volatile acids were not significantly changed by the blanching temperature. Blanching in 1% chemical solutions showed bitter results than soaking in 1% chemical solutions for 20 minutes after blanching without chemicals. Reed ash and 0.5% $Ca(CH_3CO_2)_2$ with 0.5% $MgCO_3$ solutions were more effective than the 1% solutions of other chemicals, but the effect was not significant, compared with the group not treated with chemicals. The most reasonable ratio of added salt to dewater the product for 48 hours was 30% in w/w. The amount of total organic and volatile acids revealed no correlation with the amount of added salt. Color and odor of salted product was not severely changed during the storage of 77 days at $10^{\circ}C$. But the changes were accelerated with increasing storage temperatures. The degradation of chlorophyll a in salted product during storage could be interpreted as a first order reaction, and the rate constants at 10, 20, 30 and $40^{\circ}C$ were 0.1289, 0.1028, 0.0770 and 0.0550, respectively. $Q_{10}$ and the activation energy were 1.33 and 5.01 Kcal/g mole.

• Food Science of Animal Resources
• /
• v.33 no.5
• /
• pp.646-654
• /
• 2013

In this study, quantitative analysis of major volatile flavor compounds from yogurt was conducted using headspace-solid phase microextraction (HS-SPME) GC-FID analysis technique, and the changes of volatile aroma compounds during the storage period were evaluated. The yogurt was prepared with the addition of 2% cereals, such as, white rice (WR), brown rice (BR), germinated brown rice (GBR) and saccharified germinated brown rice (SGBR). After fermentation, the products were stored at $5^{\circ}C$for 15 d. The major volatile aroma compounds in yogurt, such as acetaldehyde, acetone, diacetyl and acetoin were able to be extracted using HS-SPME technique efficiently. The regression ($r^2$) value of standard curve prepared with various concentrations of individual flavor chemicals was analyzed over 0.9975, and reproducibility was acceptable to apply quantitative analysis. The analysis of volatile components of control sample during storage showed that the acetaldehyde on 0 d was 10.83 ppm, and that contents were increased to 15.67 ppm after 15 d of storage. However, addition of BR, GBR and SGBR decreased the acetaldehyde contents during storage periods. The acetone content of all treatments during storage was not significantly different. The diacetyl content of all treatments were increased during storage and the addition of SGBR showed the highest amount of diacetyl (0.84 ppm) among treatments on 15 d of storage. The acetoin content of yogurt added with grains was higher than that of control during storage. As a result, the content of volatile aroma compounds in yoghurt during storage period could be analyzed HS-SPME extraction technique effectively, and HS-SPME/GC analysis can be considered for quality control of fermented milk products.

• 보존과학연구
• /
• s.21
• /
• pp.5-55
• /
• 2000

The cultural properties are damaged by various causes according to the characteristics of material, the condition of preservation, and the period of time. Especially, biodeterioration makes lots of damages in organic properties than inorganic ones. The damages of wooden cultural properties by insects usually are caused by the three orders; Isoptera, Coleoptera, and Hymenoptera. As the result of investigation on the state of 141 buildings of wooden cultural properties in 1999, some of them were damaged by many kinds off actors; wasp, powder post beetle, cigarette beetle, termite, decay, and physical cracking. And it was found that the patterns of damages were related to species-specific habits of insects. There are several methods of pest control for the prevention of wooden cultural properties from damages caused by insects. Those are as follows; physical control, chemical control, biological control, and integrated pest management. When insects and fungi were detected at the wooden buildings, the fumigation is best treatment to stop biodeterioration. And then, wood materials also need to be treated with insecticidal and antiseptic chemicals to avoid a reinfestation, because the fumigant is volatile. The six commercial chemicals which are applied to the insecticidal and antiseptic treatment of wooden cultural properties were purchased to test their abilities. According to the comparative results of efficacy of them in laboratory, chemical D showed excellent efficacy in all items, including antiseptic and termiticidal items. The goal of these pest controls is to protect wooden buildings from insects and microorganisms. The most effective method used currently is chemical control(fumigation, insecticidal and anticeptic chemical treatment), but it has to be treated periodically to control pest effectively. Recently environmentally-friendly control methods such as bait system or biological treatments are replacing traditional barrier treatments using large amounts of chemicals. Especially, termite is a social insect which makes a colony. Although a building with fumigation treatment is safe for a while, once attacked building has a risk of damage by reinfestation of termite. Therefore, to control termites from damaged building, the entire colony including reproductives(queen and king) and larvae around buildings must beeliminated. Bait system can be used as a preventive measure in early detection of them through termites colony monitoring and baiting. It would be the most effective for termite control if bait system would be used together with the chemical controls.

• Applied Chemistry for Engineering
• /
• v.27 no.2
• /
• pp.221-226
• /
• 2016

Production of eco-friendly and biologically harmless materials is strongly required in all industries. In particular, reducing volatile organic compounds in coating processes is extremely important to secure worker's safety. During recent two decades, extensive research works on water-borne polyurethane dispersion (PUD) have been continuously developed as an alternative to solvent-borne polyurethane. However, PUD was shown inferior mechanical properties to the organic solvent-borne polyurethane due to a limit to the molecular weight increase, which resulted in the limit of applications. To overcome this drawback, several approaches have been examined such as polymer blends and thermal/radiation induced crosslinking. Among these methods, the radiation curing system was suitable for industrialization because of the high crosslinking density and fast curing speed. In this study, we overcame the drawback for PUD via introducing benzophenone radiation curable units to PUD. We synthesized PUD films which possessed good dispersion in water for 30 days, increased Tg and Td more than $5^{\circ}C$ after UV curing film as well as improved young's modulus more than double.

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.47 no.4
• /
• pp.317-331
• /
• 2021

Essential oil is a volatile substance obtained by physically obtaining fragrant plant materials made by one single plant and plant species, and is widely used for cosmetics, fragrances, and aroma therapy due to its excellent preservation, sterilization, and antibacterial effects. When essential oil would undergo the extraction and concentration processes, the agricultural chemicals thereof would be extracted and concentrated only to be harmful to the human body. This study analyzes 320 residual agricultural chemicals concentrated in the essential oil, and to this end, LC-MS/MS and GC-MS/MS are used, while the freezing process is applied instead of the conventional refining process hexane, to improve the preprocessing method. As a result of analyzing the essential oil, such ingredients as chlorpyrifos, piperonyl butoxide and silafluofen have been detected in Basil oil and Clove leaf oil. Hence, it is perceived that the residual agricultural chemicals should continue to be monitored for the essential oil.