• Title/Summary/Keyword: Viscosity Effect

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Effect of Solvents on the Structure of Electrospun PVP Fiber (PVP의 전기방사 섬유 제조에서 용매에 따른 구조 변화)

  • Park, Ju-Young;Lee, In-Hwa
    • Applied Chemistry for Engineering
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    • v.19 no.5
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    • pp.484-490
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    • 2008
  • Electrospun of PVP (polyvinylpyrrolidone) ultra fine fibers were fabricated using various solvents including methanol, ethanol, 2-propanol, butanol, acetone, methylene chloride, and DMF, which possess different properties such as boiling point, dielectric constant, and dipole moment. Electrospun PVP fiber was influenced by viscosity, conductivity, and surface tension of spinning solution. Therefore, the electrospun PVP fiber was successfully prepared under critical conditions of viscosity > $0.114kg/m{\cdot}s$, conductivity > 1.02 mS/m, surface tension < 30.0 mN/m. In case of an ethanol solvent system, average diameter of PVP fiber increased from 1701 nm to 5454 nm as increased the applied voltage from 10 kV to 20 kV.

The Effect of Turbulence Model on the Flow Field and the Spray Characteristics (유동장 및 분무특성에 미치는 난류모델의 영향)

  • 양희천;유홍선
    • Transactions of the Korean Society of Automotive Engineers
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    • v.5 no.1
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    • pp.87-100
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    • 1997
  • The ability of turbulence model to accurately describe the complex characteristics of the flow field and the fuel spray is of great importance in the optimum design of diesel engine. The numerical simulations of the flow field and the spray characteristics within the combustion chamber of direct injection model entgine are performed to examine the applicability of turbulence model. The turbulence models used are the RNG $\varepsilon$ model and the modified $\varepsilon$ model which included the compressibility effect due to the compression/expansion of the charges. In this study, the predicted results in the quiescent condition of direct injection model engine show reasonable trends comparing with the experimental data of spray characteristics, i. e., spray tip penetration, spray tip velocity. The results of eddy viscosity obtained using the $\varepsilon$ model in the spray region is significantly larger than that obtained using the RNG $\varepsilon$ model. The application of the RNG model seems to have some potential for the simulations of the spray characteristics, e. g., spray tip penetration, spray tip velocity, droplets distribution over the $\varepsilon$ model.

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Preparation and Properties of Waterborne Poly(urethane-urea) Ionomers -Effect of the Type of Neutralizing Agent-

  • Yang, Jung-Eun;Lee, Young-Hee;Koo, Young-Seok;Jung, Young-Jin;Kim, Han-Do
    • Fibers and Polymers
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    • v.3 no.3
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    • pp.97-102
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    • 2002
  • A series of waterbome poly(urethane-urea) anionomers were prepared from isophorone diisocyanate (IPDI), polycaprolactone diol (PCL), dimethylol propionic acid (DMPA), ethylene diamine (EDA), and triethylamine (TEA), NaOH, or Cu($(COOCH_3)_2$) as neutralizing agent. This study was performed to decide the effect of neutralizing agent type on the particle size viscosity, hydrogen bonding index, adhesive strength, antistaticity, antibacterial and mechanical properties. The particle size of the dispersions decreased in the following order: TEA based samples (T-sample), NaOH based samples (N-sample), and Cu($(COOCH_3)_2$) based sample (C-sample). The viscosity of the dispersions increased in the order of C-sample, N-sample, and T-sample. Metal salt based film samples Of and C-sample) had much higher antistaticity than TEA based sample. By infrared spectroscopy, it was found that the hydrogen bonding index (or fraction) of samples decreased in the order of T-sam-pie, N-sample, and C-sample. The adhesive strength and tensile modulus/strength decreased in the order of T-sample, N-sam-pie, and C-sample. The C-sample had strong antibacterial halo, however, T- and N-samples did not

A Study on a Concept and Basic Design of a Small-Scaled LSM for Ultra-High Speed Railway Transit (초고속열차용 축소모델 선형동기전동기의 개념 및 기본설계 연구)

  • Park, Chan-Bae;Lee, Hyung-Woo;Lee, Byung-Song;Park, Hyun-June
    • Proceedings of the KSR Conference
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    • 2009.05a
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    • pp.905-911
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    • 2009
  • The viscosity drive method by the wheel which is widely used in the conventional railway systems needs a large friction force between the wheel and the guide-rail, which brings on a thrust force for a quick acceleration and a high-speed travelling. In addition, the viscosity drive method needs an increase of the vehicle weight for a large friction force. However, a maglev train is possible to be driven by the electro-magnet instead of the wheel, which produces a levitation and thrust force without any contact. In general, low-speed maglev train uses a linear induction motor(LIM) for propulsion that is operated under 300[km/h] due to the power-collecting and end-effect problems of LIM. In case of high-speed maglev train, a linear synchronous motor(LSM) is more suitable than LIM because of a high-efficiency and high-output properties. LSM has a driving principle as same as a conventional rotary synchronous motor(RSM), and the torque of RSM becomes the thrust force of LSM. A conventional LSM has relatively large air-gap compared with a conventional RSM. So, it must be achieved a design that is considered normal force by finite-asymmetric structure, end-effect on the entry and exit part, and support structure of a moving part. Therefore, in this research, authors accomplish a conceptualizing and basic design of a small-scaled LSM, and characteristics analysis using FEM.

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Centrifuge Modeling of Soft Clay with Vertical Drains Considering the Centrifuge Similarity (상사성을 고려한 배수재 설치 연약점토 지반의 원심모델링)

  • Yoo, Nam-Jae;Hong, Young-Kil;Jeong, Gil-Soo;Cho, Han-Ki
    • Journal of Industrial Technology
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    • v.27 no.A
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    • pp.111-120
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    • 2007
  • This paper is results of experimental research on the effect of application of similarity related to permeability of soil on the consolidation behavior as centrifuge modeling of consolidation is performed with the centrifuge model facility. In this research, the permeability of soil was controlled by changing the viscosity of porewater as the mixed water with glycerin was used during the centrifuge model experiments. The effect of drainage path on consolidation was investigated by installing the vertical drains. A serise of centrifuge model tests with conditions of single vertical and radial horizontal drainage were carried out. Kaolinite and Jumunjin standard sand were used as soft clay and surcharges respectively during tests. For testing condition of single vertical drainage considering similarity of permeability, it was found that consolidation with mixed porewater with glycerin was delayed in comparisons sons with test results with water only. For conditions of horizontal drainage with vertical drains, a low permeability by changing the viscosity of pore water resulted in delayed degree of consolidation at an initial stage of consolidation. But, it predicted not much differences in settlement as long as the consolidation time was sufficiently long enough to finish consolidation. Consequently, it was found that similarity in permeability should be considered to be critical for the case of centrifuge model experiments related to consolidation with long drainage path.

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Effect of Ultra Fine Precipitated Calcium Carbonate on the Quality of Coated Paper (초미립 경질탄산칼슘이 도공지 품질에 미치는 영향)

  • Kim, Sun-Kyung;Won, Jong-Myoung;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.4
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    • pp.91-98
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    • 2012
  • This study was carried out in order to evaluate the effects of ultra fine precipitated calcium carbonate (UFPCC) on properties of coating color, coated paper and off-set printability. It was found that blending of UFPCC increased the low-shear viscosity and water retention of coating color. The smaller the particle size, the more significant the effect of it. When the blending ratio of UFPCC was increased, brightness, whiteness and opacity of the coated paper were improved, while paper gloss was decreased due to the increase in roughness. When the UFPCC with the average particle size of $0.12{\mu}m$ was used, the ink receptivity during off-set printing was improved while print gloss was maintained or a little decreased. It was also observed that the dry-pick and wet-pick strength of coated paper were improved by the use of UFPCC. In conclusion, it is possible to produce the low gloss matt paper with the use of UFPCC since it could improve the optical properties and ink receptivity of coated paper.

Effect of Talc on Gravure Printability(I) -Effect of talc on gravure printability of matt and grade coated papers- (탈크가 그라비어 인쇄적성에 미치는 영향 제1보 - 탈크가 무광택 및 광택 도공지 그라비어 인쇄적성에 미치는 영향 -)

  • Cheong, Hee-Seok;Kim, Chang-Keun;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.41 no.3
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    • pp.1-7
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    • 2009
  • Talc as a coating pigment has been developed in order to replace GCC and clay for matte grade and has received much attention due to various advantages including good gravure printability. In order to elucidate the effects of talc on gravure printability, model papers were produced with three kinds of coating talc whose particle size and brightness are different. Physical properties related to surface and structure and the gravure printability of the sample were tested. Coating color with talc showed lower viscosity than that with clay. For both matte and art grades, talc tended to give lower gloss than day. The smaller the particle size of talc, the better properties in the coating color viscosity and water retention. When the particle size of talc was small enough, the surface roughness of the coated paper produced with talc was similar to that with clay while larger talcs produced rougher surface than clay. On top of that, application of talc improved compressibility and gravure printability of coated paper.

Effect of Gum Addition on the Rheological Properties of Rice Flour Dispersions

  • Chun, So-Young;Kim, Hyung-Il;Yoo, Byoung-Seung
    • Food Science and Biotechnology
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    • v.15 no.4
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    • pp.589-594
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    • 2006
  • The effect of five commercial gums (carboxylmethylcellulose, CMC; guar gum, GG; hydroxypropylmethyl-cellulose, HPMC; locust bean gum, LBG; and xanthan gum) at a concentration of 0.25% on the rheological properties of rice flour (RF) dispersions was investigated in steady and dynamic shear. The steady shear rheological properties showed that RF gum mixture dispersions (5%, w/w) at $25^{\circ}C$ had high shear-thinning flow behavior (n=0.20-0.31) exhibiting a yield stress. Magnitudes of consistency index (K), apparent viscosity (${\eta}_{a,100}$), and Casson yield stress (${\sigma}_{oc}$) of RF-gum mixtures were much higher than those of RF dispersion with no added gum (control). Activation energy values (6.67-10.8 kJ/mole) of RF-gum mixtures within the temperature range of $25-70^{\circ}C$ were lower than that (11.9 kJ/mole) of the control. Dynamic rheological data of log (G', G") versus log frequency (${\omega}$) of RF-gum mixtures had positive slopes (0.15-0.37) with G' greater than G" over most of the frequency range (0.63-63 rad/sec), demonstrating a frequency dependency. Tan ${\delta}$ (G"/G') values of RF-gum mixtures, except for xanthan gum, were much higher than that of the control.

Effect of Concentration of Carboxymethycellulose on Degradation by Radiation (Carboxymethycellulose의 농도에 따른 방사선 분해 연구)

  • Kim, Jeongsoo;Sung, Nak-Yun;Kim, Jae-Hun;Kim, Tae-woon;Lee, Ju-Woon;Choi, Jong-il
    • Journal of Radiation Industry
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    • v.4 no.4
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    • pp.385-389
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    • 2010
  • In this study, the effect of the concentration of carboxymethylcellulose (CMC) solution on the degradation by irradiation was investigated. The CMC solutions with different concentrations of 3%, 4%, 5%, 6% and 7% were irradiated at the doses of 5, 10, 15, 20, 25 and 30 kGy with gamma ray or electron beam, and the viscosity of CMC solution was measured. The viscosity of the CMC solutions was decreased with an increase in the irradiation dose, but the extent of the degradation by an irradiation was found to be decreased with an increase of the CMC concentration in the solution. The dependency of the irradiation sources showed that an electron beam radiation had degraded the CMC less severely than gamma ray.

Contents of $\beta$-Glucan in Various Cereals and Its Functional Properties

  • Whang, Key
    • Preventive Nutrition and Food Science
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    • v.3 no.4
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    • pp.382-386
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    • 1998
  • A soluble dietary fiber, $\beta$-glucan, contained in oat and barley has nutritional benefits such as hypocholesterolemic effects and influences blood glucose regulation. The contents of $\beta$-glucan in both cereals range from 3 to 7% with the exception of a certain barley genotype which contains up to 16% $\beta$-glucan. $\beta$-Glucan is distributed mainly in the cell walls of endosperm and the distal (bran) portion of kernel. Various procedures have been developed for increasing the extraction yield of $\beta$-glucan. Oat gum prepared with weak alkali extractionand alcohol proecipitation following protein removal usually contains 80% $\beta$-glucan.The most commonly used method for $\beta$-glucan quantitiation is an enzymatic procedure combining lichenase plus $\beta$-glucosidase followed by measuring the amount of glucos released by glucose oxidase-peroxidase treatment. The increase in foam-and emulsion-stabilizing capacity of $\beta$-glucan is due to the increase in viscosity of the aqueous phase. Therefore, $\beta$-glucan shows great potentials as a thickener and a stabilizer.

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