• Elastomers and Composites
• /
• v.58 no.1
• /
• pp.32-43
• /
• 2023

The worldwide use of polyurethane foam products generates large amounts of waste, which in turn has detrimental effects on the surroundings. Hence, finding an economical and environmentally friendly way to dispose of or recycle foam waste is an utmost priority for researchers to overcome this problem. In that sense, the glycolysis of waste flexible polyurethane foam (WFPF) from automotive seat cushions using different industrial-grade glycols and potassium hydroxide as a catalyst to produce recovered polyol was investigated. The effect of different molecular weight polyols, catalyst concentration, and material ratio (PU foam: Glycols) on the reaction conversion and viscosity of the recovered polyols was determined. The obtained recovered polyols are obtained as single or split-phase reaction products. Besides, the foaming characteristics and physical properties such as cell morphology, thermal stability, and compressive stress-strain nature of the regenerated flexible foams based on the recovered polyols were discussed. It was observed that the regenerated flexible foams displayed good seating comfort properties as a function of hardness, sag factor, and hysteresis loss compared to the reference virgin foam. With the growing demand for a sustainable and circular economy, a global valorization of glycolysis products from polyurethane scraps can be realized by transforming them into profitable substances.

• Composites Research
• /
• v.19 no.6
• /
• pp.16-22
• /
• 2006

The puncture properties under various conditions were investigated for the optimum conditions to yield the best properties. Fiber aspect ratio(AR: length of fiber/diameter of fiber), interphase condition and fiber content were considered as variables which impact the puncture force and friction force. The puncture force of short-fiber reinforced rubber increases up to 3.4 times compared to the virgin material. The better interphase condition shows the higher puncture force at given fiber AR and fiber content. The friction force of the matrix and reinforced rubber with a fiber AR below 155 does not exist. The friction force of the reinforced rubber with the good interphase condition and high fiber AR is higher than puncture force of matrix. Overall, it was found that the interphase condition, fiber AR and fiber content have an important effect on the puncture properties.

• Journal of the Korean Society for Precision Engineering
• /
• v.3 no.1
• /
• pp.40-49
• /
• 1986

Crack, craze and void are common defects which may be found in the bulk of polymeric materials such as either themoplastics or thermosets. The healing phenomena, autohesion, of these defects are known to be a intrinsic material property of various polymeric materials. However, only a few experimental and theoretical investigations on crack, void and craze healing phenomena for various polymeric materials have been reported up to date [1, 2, 3]. This may be partly due to the complications of healing processes and lacking of appropriate theoretical developments. Recently, some investigators have been urged to study the healing phenomena of various polymenic materials since the significance of the use of polymer based alloys or composites has been raised in terms of specific strength and energy saving. In the earlier published reports [1, 2, 3, 4], the crack and void healing velocity, healing toughness and some other healing mechanical and physical properties were measured experimentally and compared with predicted values by utilizing a simple model such as the reptation model under some resonable assumptions. It seems, however, that the general acceptance of the proposed modeling analyses is yet open question. The crack healing processes seem to be complicate and highly dependent on the state of virgin material in terms of mechanical and physical properties. Furthermore, it is also strongly dependent on the histories of crack, craze and void development including fracture suface morphology, the shape of void and the degree of disentanglement of fibril in the craze. The rate of crack healing may be a function of environmental factors such as healing temperature, time and pressure which gives different contact configurations between two separated surfaces. It seems to be reasonable to assume that the crack healing processes may be divided in several distinguished steps like stress relaxation with molecular chain arrangement, surface contact (wetting), inter- diffusion process and com;oete healing (to obtain the original strength). In this context, it is likely that we no longer have to accept the limitation of cumulative damage theories and fatigue life if it is probable to remove the defects such as crack, craze and void and to restore the original strength of polymers or polymer based compowites by suitable choice of healing histories and methods. In this paper, we wish to present a very simple and intuitive theoretical model for the prediction of healed fracture toughness of cracked or defective polymeric components. The central idea of this investigation, thus, may be the modeling of behavior of chain molecules under healing conditions including the effects of chain scission on the healing processes. The validity of this proposed model will be studied by making comparisons between theoretically predicted values and experimentally determined results in near future and will be reported elsewhere.

• Clean Technology
• /
• v.2 no.1
• /
• pp.32-43
• /
• 1996

The interactions of the societal-industrial system with the environment form one of the most critical issues in today's world. The inadequacy of current environmental regulatory structures and of traditional ways of analyzing environmental issues, together with the continuing need to mitigate the environmental perturbations arising from this complex relationship, have led to the development of a new conceptual framework termed industrial ecology. Industrial ecology (IE), defined by Graedel and Allenby, is the means by which humanity can deliberately and rationally approach and maintain a desirable carrying capacity, given continued economic, cultural and technological evolution. The concept requires that an industrial system be viewed not in isolation from its surrounding systems, but in concert with them. IE is a systems view in which one seeks to optimize the total materials cycle from virgin material, to finished material, to component, to product, to obsolete product, and to ultimate disposal. Factors to be optimized include resources, energy, and capital. In the present paper, the concept of Industrial Ecology and its application through efficient and practical Design for Environment (DFE) methodologies and tools will be introduced to Korea. This paper will also emphasis on the industrial environment within which DFE methodologies must be used, including the fundamentals of industrial design activities, concurrent engineering, constraints on design choices and existing technological infrastructure.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.6 no.2
• /
• pp.112-118
• /
• 2011

The recycled asphalt concrete has gotten increasing attention due to the environmental issues. The volume of reclaimed asphalt has increased significantly for last few years because of city remodeling, pavement maintenance, utility excavation, and road widening. Considering the value of reclaimed asphalt, it is rather used for the recycled asphalt concrete than it is used for fill and cover up material instead of soil. This research will be a supplements incomplete issues from existing research results and suggests the quality control guideline for recycled asphalt concrete and upcoming laws. As the first step of research, the trial construction of RAP(Recycled Asphalt Pavement) performed in expressway construction sites. These trial construction sites have been checked every years. And another construction sites studied and selected for more deeper performance check of RAP. For this checks, we used automatic pavement survey equipment and computerized analysis tools. Also, DSR(Dynamic Shear Rheometer) was used for the fatigue life calculation of binder blends(RAP and virgin binder). As a consequence of this research, the application of recycled asphalt provides good enough quality for highway construction. The preceeding literatures reviewed shows that the asphalt rejuvenator are used in many countries but that type of chemical agent are not used in Korea. By using the data of trial construction and mix design in Chongwon-Sangju construction lane, the surface and base courses consisted with the 10% and 30% rap mix asphalt section maintains good performance for up to 7 years. Through the performance check and laboratory tests(DSR), the quality control and mixture's low temperature prevention are the important factor and chemical agent necessary for increasing the fatigue life of RAP binder.

• Journal of Korean Ophthalmic Optics Society
• /
• v.16 no.1
• /
• pp.13-19
• /
• 2011

Purpose: The purpose of this study was to assess characterize overseas company's Cellulose acetate glasses frame sheets (overseas company's CA sheet) Also, the optimum content of plasticizer and melt extrusion condition of industrial CA resin were established for appropriate glasses frame. Methods: Overseas company's Cellulose acetate glasses frame sheets (overseas company's CA sheet) were characterized by $^1H$-NMR, GPC, and TGA. Also, the optimum content of plasticizer and melt extrusion condition of industrial CA resin were established. Results: The plasticizer of overseas company's CA sheet measured by $^1H$-NMR was diethyl phthalate, and its content was measured 30 wt% by TGA. Also, industrial CA resin showed enough melting behavior in the range of 190~200$^{\circ}C$. Compared to overseas company's CA sheet's tensile strength value of 2.2~2.8 kgf/$mm^2$, industrial CA resin exhibited sufficient tensile strength value of 2.3 kgf/$mm^2$ for glasses frame. Conclusions: Industrial CA resin with 30 wt% plasticizer content would be a promising material for glasses frame prepared by melt extrusion to replace China CA sheet.

• Applied Biological Chemistry
• /
• v.41 no.2
• /
• pp.187-190
• /
• 1998

The cytotoxic activity of MeOH extracts of the freeze-dried silkworm (Bombyx mori)-derived materials (4th instar larvae, female and mate pupae, virgin female and male adult), dried Beauveria bassiana-infected silkworm larvae, dried feces from the 4th instar larvae B. mori, and dried mulberry (Morus alba)-derived materials (leaves, fruits, root barks) in vitro was evaluated by sulforhodamine B assay, using the five human solid A 549 lung, SK-OV-2 ovarian, SK-MEL-2 melanoma, XF-498 CNS and HCT-15 colon tumor cell lines. The responses varied with both cell line and material used. The 70% hot MeOH extract of B. mori feces (BFH) revealed potent cytotoxic activity against model tumor cell lines whereas moderate activity was observed from the MeOH extract of B. mori feces. M. alba root barks, and M. alba fruits. The other test materials were ineffective. Because of its potent cytotoxic activity, the activity of each solvent fraction from the BFH was determined. Chloroform and ethyl acetate fractions showed the most potent cytotoxic activity. In conclusion, our results may be an indication of at least one of the pharmacological actions of B. mori feces. M. alba root barks, and M. alba fruits.