• Journal of Powder Materials
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• v.27 no.2
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• pp.103-110
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• 2020

Aluminum (Al) - based powders have attracted attention as key materials for 3D printing because of their excellent specific mechanical strength, formability, and durability. Although many studies on the fabrication of 3D-printed Al-based alloys have been reported, the influence of the size of raw powder materials on the bulk samples processed by selective laser melting (SLM) has not been fully investigated. In this study, AlSi10Mg powders of 65 ㎛ in average particle size, prepared by a gas atomizing process, are additively manufactured by using an SLM process. AlSi10Mg powders of 45 ㎛ average size are also fabricated into bulk samples in order to compare their properties. The processing parameters of laser power and scan speed are optimized to achieve densified AlSi10Mg alloys. The Vickers hardness value of the bulk sample prepared from 45 ㎛-sized powders is somewhat higher than that of the 65 ㎛m-sized powder. Such differences in hardness are analyzed because the reduction in melt pool size stems from the rapid melting and solidification of small powders, compared to those of coarse powders, during the SLM process. These results show that the size of the powder should be considered in order to achieve optimization of the SLM process.

• Journal of Powder Materials
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• v.23 no.3
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• pp.207-212
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• 2016

In this study, Fe-Cu-Ni-Mo-C low alloy steel powder is consolidated by spark plasma sintering (SPS) process. The internal structure and the surface fracture behavior are studied using field-emission scanning electron microscopy and optical microscopy techniques. The bulk samples are polished and etched in order to observe the internal structure. The sample sintered at $900^{\circ}C$ with holding time of 10 minutes achieves nearly full density of 98.9% while the density of the as-received conventionally sintered product is 90.3%. The fracture microstructures indicate that the sample prepared at $900^{\circ}C$ by the SPS process is hard to break out because of the presence of both grain boundaries and internal particle fractures. Moreover, the lamellar pearlite structure is also observed in this sample. The samples sintered at 1000 and $1100^{\circ}C$ exhibit a large number of tiny particles and pores due to the melting of Cu and aggregation of the alloy elements during the SPS process. The highest hardness value of 296.52 HV is observed for the sample sintered at $900^{\circ}C$ with holding time of 10 minutes.

• Journal of Powder Materials
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• v.18 no.2
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• pp.188-195
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• 2011

The aim of this study was to investigate microstructures and mechanical properties of nano-sized Ti-35 wt.%Nb-7 wt.%Zr-10 wt.%CPP composite fabricated by high energy mechanical milling (HEMM) and pulse current activated sintering (PCAS). Grain growth of the mechanically milled powder was prevented by performing PCAS. The principal advantages of calcium phosphate materials include: similarity in composition to the bone mineral, bioactivity, osteoconductivity and ability to form a uniquely strong interface with bone. The hardness and wear resistance property of nano-sized Ti-35 wt.%Nb-7 wt.%Zr-10 wt.%CPP composites increased with increasing milling time because of decreased grain-size of sintered composites.

• Corrosion Science and Technology
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• v.3 no.3
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• pp.112-117
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• 2004

This work investigated the material properties of Ni-P-B alloy electrodeposits obtained from a Ni sulfamate bath as a function of the contents of the P and B sources($H_3PO_3$ and dimethyl amine borane complex(DMAB), respectively) with/without additives. Chemical composition, residual stress, microstructure and micro hardness were investigated using ICP(inductively coupled plasma) mass spectrometer, flexible strip, XRD, TEM and micro Vickers hardness tester, respectively. From the results of the compositional analysis, it was observed that P and B are incorporated competitively during the electrodeposition and the sulfur from the additive is codeposited into the electrodeposit. The measured residual stress value increased in the order of Ni, Ni-P, Ni-B and Ni-P-B electrodeposits indicating that boron affects the residual tensile stress greater than phosphorus. As the contents of the alloying element sources of P and B increased, crystallinity and the grain size of the electrodeposit decreased. The effect of boron on crystallinity and grain size was also relatively larger than the phosphorus. It can be explained that the boron with a smaller atomic radius contributes to the increase of residual stress in the tensile direction and the larger restraining force against the grain growth more significantly than the phosphorus with a larger atomic radius. Introduction of an additive into the bath retarded crystallization and grain growth, which may be attributed to the change of the grain growth kinetics induced by the additive adsorbed on the substrate and electrodeposit surfaces during electrodeposition.

• Journal of the Korean Ceramic Society
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• v.23 no.6
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• pp.37-44
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• 1986

Yttria-antimonia-stabilized zirconia was investigated with respect to the amount of $Sb_2O_3$ addition in the range of 0.5~5mole% to the base composition of $(ZrO)_{0.92}(Y_2O_3)_{0.08}$ The sinterbility modulus of rupture Vickers hardness evaporation of components phase form-tion and mcicrostructure were evaluated with antimonia content. Also two probe A. C conductivity measurement was subjected to all specimens and the best results are achieved with 1mol% $Sb_2O_3$ as a sinter agent and relative density of~98% obtained at 140$0^{\circ}C$ and this composition has a maximum electrical conductivity due to the possible substition of $Sb^{3+}$ for $Zr^{4+}$ site. The effect of $Sb_2O_3$ on the electrical conductivity of th bulk and the grain boundaries has on investigated using frequency dispersion analysis (5~106 Hz) Antimonia addition has a negative in-fluence on both the bulk and the grain boundary conductivity except for a 1 mon% addition. The additive antimonia has improve a modulus of rupture to 60~MPa due to metastable-tetragonal phase apparence and decrease the hardness with increasing the $Sb_2O_3$ content.

• Journal of the Korean Society for Nondestructive Testing
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• v.22 no.2
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• pp.132-139
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• 2002

The grain size of aluminum alloy was refined to the submicrometer level by using equal-channel angular pressing(ECAP). The effect of grain size refinement was evaluated by the tensile test, micro-hardness test, microstructure observations, ultrasonic test and acoustic emission test. The strength and the Vickers hardness were increased significantly according to grain size refinement after equal-channel angular pressed. The ultrasonic velocity was faster after equal-channel angular pressed, and the high frequency range appeared. The results of the ultrasonic velocity and the frequency range are expected to be basic data that can prove the grain size refinement

• Proceedings of the KWS Conference
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• 2010.05a
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• pp.18-18
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• 2010

최근에 건조되는 선박이나 구조물들은 점차 대형화 되어가고, 이에 사용되는 판재들은 점차 고강도 극후판재화 되어가고 있다. 극후판재의 용접성을 향상시키기 위해서는 대입열 용접이 주로 적용되고 있는 실정인데, 30 mmt 이상의 후판을 1 pass로 용접하기 위해서는 EGW(Electro-gas welding) 기법을 사용한다. 대입열 용접은 용접입열(heat input)이 매우 높아 용착금속과 열영향부의 냉각속도가 매우 느려 용접열영향부에서 특히 fusion line 근처의 열영향부는 결정립 조대화 및 취약한 미세조직을 형성함으로서 저온인성을 크게 저하시키고, 연화 현상(softening effect)을 발생시켜 강도가 저하되는 문제점이 주로 발생하였다. 하지만 이런 문제점을 해결하기 위해 대입열용접에 사용된는 강재의 미세조직을 제어하여 AlN, TiN, $TiO_2$ 등의 석출물을 이용한 용접열영향부의 저온인성을 향상시켰다. 이러한 문제점이 발생하는 대입열용접에서 저온인성 시험은 주로 fuison line + 1, 2mm에서 수행한다. 하지만 대입열 용접시 용착금속의 냉각속도도 매우 느리기 때문에 용착금속의 위치에 따라 저온 인성 특성이 다르게 나타날 수 있다. 본 연구에서는 EGW 용착금속의 위치에 따른 저온인성 특성을 평가하기 위해 EH-36N, 40mmt 판재를 사용하여 1pole EG 용접 하였다. 용착금속의 저온인성 특성을 평가하기위해 충격 시편의 노치 위치가 fusion line - 2mm와 용접부 중앙을 기준으로 4곳을 선정하여 충격시험을 수행하였다. 또한 용착금속의 경도 분포를 알아보기 위해 micro vickers hardness tester(mitutoyo UR-501)을 사용해 hardness mapping 시험을 하였다. 용착금속의 저온인성은 미세조직과, 산소량에 따라 변화 할 수 있기 때문에 용착금속 위치를 달리하여 미세조직과 산소량도 각각 분석하였다. 용착금속의 저온인성을 향상시킬 수 있는 침상형페라이트와 비금속개재물의 상관관계에 관해 검토 하였다.

• Proceedings of the KSME Conference
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• 2000.11a
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• pp.105-110
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• 2000

The Micromechanics test is new test method which uses comparatively smaller specimen than that required in conventional material tests. There are several methods, such as small-specimen creep test, the continuous indentation test, and small punch(SP) test. Among them, the small punch(SP) test method has been applied to many evaluation fields, such as a ductile-brittle transition temperature, stress corrosion cracking, hydrogen embrittlement, and fracture properties of advanced materials like FGM or MMC. In this study, the small punch(SP) test is performed to evaluate the mechanical properties at high/low temperature from $-196^{\circ}C$ to $650^{\circ}C$ and the material degradation for virgin and aged materials of 9Cr1MoVNb steel which has been recently developed. The ${\Delta}P/{\Delta}{\delta}$ parameter defined a slope in plastic membrane stretching region of SP load-displacement curve decreases according to the increase of specimen temperature, and that of aged materials is higher than the virgin material in all test temperatures. And the material degradation degrees of aged materials with $630^{\circ}C$ -500hrs and $630^{\circ}C$ -1000hrs are $36^{\circ}C$ and $38^{\circ}C$ respectively. These behaviors are good consistent with the results of hardness($H_v$) and maximum displacement(${\delta}_{max}$).

• Journal of the Korean institute of surface engineering
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• v.41 no.4
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• pp.147-155
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• 2008

The dental orthodontic wire provides a good combination of strength, corrosion resistance and moderate cost. The purpose of this study was to investigate the effects of TiN and ZrN coating on corrosion resistance and physical property of orthodontic wire using various instruments. Wires(round type and rectangular type) were used, respectively, for experiment. Ion plating was carried out for wire using Ti and Zr coating materials with nitrogen gas. Ion plated surface of each specimen was observed with field emission scanning electron microscopy(FE-SEM), energy dispersive X-ray spectroscopy(EDS), atomic force microscopy(AFM), vickers hardness tester, and electrochemical tester. The surface of TiN and ZrN coated wire was more smooth than that of other kinds of non-coated wire. TiN and ZrN coated surface showed higher hardness than that of non-coated surface. The corrosion potential of the TiN coated wire was comparatively high. The current density of TiN coated wire was smaller than that of non-coated wire in 0.9% NaCl solution. Pit nucleated at scratch of wire. The pitting corrosion resistance $|E_{pit}-E_{rep}|$ increased in the order of ZrN coated(300 mV), TiN coated(120 mV) and non-coated wire(0 mV).

• Journal of Powder Materials
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• v.17 no.4
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• pp.302-311
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• 2010

In this research, the refinement behavior of the coarse magnesium powders fabricated by gas atomization was investigated as a function of milling time using a short duration high-energy ball milling equipment, which produces fine powders by means of an ultra high-energy within a short duration. The microstructure, hardness, and formability of the powders were investigated as a function of milling time using X-ray diffraction, scanning electron microscopy, Vickers micro-hardness tester and magnetic pulsed compaction. The particle morphology of Mg powders changed from spherical particles of feed metals to irregular oval particles, then platetype particles, with increasing milling time. Due to having HCP structure, deformation occurs due to the existence of the easily breakable C-axis perpendicular to the base, resulting in producing plate-type powders. With increasing milling time, the particle size increased until 5 minutes, then decreased gradually reaching a uniform size of about 50 micrometer after 20 minutes. The relative density of the initial power was 98% before milling, and mechanically milled powder was 92~94% with increase milling time (1~5 min) then it increased to 99% after milling for 20 minutes because of the change in particle shapes.