• Computers and Concrete
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• v.20 no.1
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• pp.77-84
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• 2017

Shirasu, a pyroclastic flow deposit, showed considerable performance as aluminosilicate source in geopolymer, based on past research. However, the polymerization reactivity was somewhat lower compared to the traditional fly ash based geopolymer even though the long-term strength was fairly good. The present study concentrates on the development of higher initial strength performance of Shirasu based geopolymer by utilizing ground granulated blast furnace slag as an admixture. Mortars with various mix proportions were adopted to study the effect of parametric changes on strength development along with the addition of slag in different percentages. A combination of sodium hydroxide and sodium silicate was used as alkaline activators considering parameters like molar ratios of alkali to geopolymer water and silica to alkali molar ratio. The mortars were cured at elevated temperatures under different curing conditions to analyze the effect on strength development. Compressive strength test, mercury intrusion porosimetry and X-ray powder diffraction were carried out to assess the strength performance and microstructure of slag-Shirasu based geopolymer. Based on the experimental study, it was observed that the initial and long-term strength development of Slag-Shirasu geopolymer were improved by the addition of slag.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2005.11a
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• pp.57-61
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• 2005

Cement paste is originally the basic material and crucial factor consisting concrete. This study investigates the relationship between flow apparatuses, which are ring flow(R-F), flow cone(F-C) and mini slump(M-S), in order to estimate the fluidity of cement Paste. For quantitatively evaluating the measured data this study also investigated the calibration of the rheology consistent, such as yield value and plastic viscosity, of cement paste using viscometer For this purpose the present work discussed the influence of 3 type of ordinary portland cement with different companies, affecting the fluidity of cement paste. and it also demonstrated the influence of the various kinds of mineral admixtures, such as fly ash(FA), blast furnace slag(BS) and silica fume(SF) and that of incorporating ratio. The author concluded that using R-F apparatus is the most effective flow test method of cement paste and it is exactly proportional to other apparatus' rheological properties.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2019.11a
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• pp.21-22
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• 2019

In order to prevent global warming according to fossil fuel use, countries around the world are making efforts through the Kyoto Protocol and the Paris Climate Change Convention. In addition, in order to prepare for high oil prices, researches such as the development of various renewable energy are being conducted. At present, the domestic production rate of energy sources in Korea is low at 18.1%, and power plants using forest biomass are being constructed to meet the domestic situation where 63% of the land is a forest. In 2015, the global production of wood pellets, a raw material for wood-based biomass power generation, was 28 million tons, up 7.7% from 2014, and has increased tenfold over the last decade. This is a result of increased demand for biomass. Korea is also increasing every year. However, biomass fly ash, an industrial by-product generated by biomass energy generation, is now being disposed of entirely, and there is little research to utilize it. Therefore, this paper will use biomass fly ash, an industrial by-product, which is currently being discarded due to a lack of separate treatment methods, as an admixture concept to contribute to solving environmental problems, developing new admixtures, improving quality, and seeking recycling plans.

• Advances in concrete construction
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• v.11 no.2
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• pp.99-109
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• 2021

Slag blended concrete is widely used as a mineral admixture in the modern concrete industry. This study shows an optimization process that determines the optimal mixture of air-entrained slag blended concrete considering carbonation durability, frost durability, CO2 emission, and materials cost. First, the aim of optimization is set as total cost, which equals material cost plus CO2 emission cost. The constraints of optimization consist of strength, workability, carbonation durability with climate change, frost durability, range of components and component ratio, and absolute volume. A genetic algorithm is used to determine optimal mixtures considering aim function and various constraints. Second, mixture design examples are shown considering four different cases, namely, mixtures without considering carbonation (Case 1), mixtures considering carbonation (Case 2), mixtures considering carbonation coupled with climate change (Case 3), and mixtures of high strength concrete (Case 4). The results show that the carbonization is the controlling factor of the mixture design of the concrete with ordinary strength (the designed strength is 30MPa). To meet the challenge of climate change, stronger concrete must be used. For high-strength slag blended concrete (design strength is 55MPa), strength is the control factor of mixture design.

• Geomechanics and Engineering
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• v.31 no.4
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• pp.409-422
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• 2022

The use of calcium sulfoaluminate (CSA) cement as a rapid-hardening cement admixture or eco-friendly alternate for ordinary Portland cement (OPC) has been attempted over the years, but the cost of CSA cement and availability of suitable aluminium resource prevent its wide practical application. To propose an effective ground improvement design in sandy soil, this study aims at blending a certain percentage of CSA with OPC to find an optimum blend that would have fast-setting behavior with a lower carbon footprint than OPC without compromising the mechanical properties of the cemented sand. Compared to the 100% CSA case, initial speed of strength development of blended cement is relatively low as it is mixed with OPC. It is found that 80% OPC and 20% CSA blend has low initial strength but eventually produces equivalent ultimate strength (28 days curing) to that of CSA treated sand. The specific OPC-CSA blend (80:20) exhibits significantly higher strength gain than using pure OPC, thus allowing effective geotechnical designs for sustainable and controlled ground improvement. Further parametric studies were conducted for the blended cement under various curing conditions, cement contents, and curing times. Wet-cured cement treated sand had 33% lower strength than that of dry-cured samples, while the stiffness of wet-cured samples was 25% lower than that of dry-cured samples.

• Journal of the Korea institute for structural maintenance and inspection
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• v.10 no.4
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• pp.153-159
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• 2006

Recently, the polymer is used as an admixture in the repair mortar, which contains various admixtures and mineral admixtures. In this study, the fresh and mechanical properties of repair mortar influenced by the types of polymers(classified as E.V.A.) and the range of polymer ratio were investigated. It was found that with increasing the ratio of polymer, mechanical properties(compressive strength, flexural strength, adhesive strength) of repair mortar is improved and drying shrinkage is increased.

• Journal of Korean Neurosurgical Society
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• v.57 no.4
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• pp.235-241
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• 2015

Objective : Magnetic resonance imaging (MRI) of chronic subdural hematoma (CSDH) detects various patterns, which can be attributed to many factors. The purpose of this study was to measure the level of interleukin-6 (IL-6), interleukin-8 (IL-8), and highly specific protein [beta-trace protein (${\beta}TP$)] for cerebrospinal fluid (CSF) in CSDHs, and correlate the levels of these markers with the MRI findings. Methods : Thirty one patients, treated surgically for CSDH, were divided on the basis of MRI findings into hyperintense and non-hyperintense groups. The concentrations of IL-6, IL-8, and ${\beta}TP$ in the subdural fluid and serum were measured. The ${\beta}TP$ was considered to indicate an admixture of CSF to the subdural fluid if ${\beta}TP$ in the subdural fluid $({\beta}TP_{SF})/{\beta}TP$ in the serum $({\beta}TP_{SER})>2$. Results : The mean concentrations of IL-6 and IL-8 of the hyperintense group (n=17) of T1-WI MRI were $3975.1{\pm}1040.8pg/mL$ and $6873.2{\pm}6365.4pg/mL$, whereas them of the non-hyperintense group (n=14) were $2173.5{\pm}1042.1pg/mL$ and $2851.2{\pm}6267.5pg/mL$ (p<0.001 and p=0.004). The mean concentrations of ${\beta}TP_{SF}$ and the ratio of ${\beta}TP_{SF}/{\beta}TP_{SER}$ of the hyperintense group (n=13) of T2-WI MRI were $7.3{\pm}2.9mg/L$ and $12.6{\pm}5.4$, whereas them of the non-hyperintense group (n=18) were $4.3{\pm}2.3mg/L$ and $7.5{\pm}3.9$ (p=0.011 and p=0.011). Conclusion : The hyperintense group on T1-WI MRI of CSDHs exhibited higher concentrations of IL-6 and IL-8 than non-hyperintense group. And, the hyperintese group on T2-WI MRI exhibited higher concentrations of ${\beta}TP_{SF}$ and the ratio of ${\beta}TP_{SF}/{\beta}TP_{SER}$ than non-hyperintense group. These findings appear to be associated with rebleeding and CSF admixture in the CSDHs.

• Clean Technology
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• v.6 no.1
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• pp.61-69
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• 2000

In this study, generation process and properties of inorganic industrial waste which can be used in cement industry were investigated. The scheme of recycling to use the selected waste as raw materials, mineralizer and flux, admixture and raw materials for special cement was decided and then various experiments were carried out. The experimental results were as follows ; In the use of industrial waste as raw materials, ferrous materials could be substituted by Cu-slag, Zn-slag, electric arc furnace or convertor furnace slag etc., and a siliceous material could be substituted by sand from cast-iron industry. By-products from sugar or fertilizer industry, which has $CaF_2$ as the main component, and jarosite from Zn refinery enabled clinker phases to be formed at lower temperature by $100{\sim}150^{\circ}C$. Adding Cu slag and STS sludge in proper proportion to cement improved properties of cement. Fly ash and limestone powder as admixture had the same effect on cement. As a raw material for special cement, aluminium waste sludge could be used in making ultra early strength cement, which had the compressive strength of $300kg/cm^2$ within 2hours. And two different ashes from municipal incinerator could be raw materials of the cement which was mainly composed of $C_3S$ and $C_{11}A_7{\cdot}CaCl_2$ as clinker phases.

• Journal of the Korea institute for structural maintenance and inspection
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• v.8 no.2
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• pp.185-194
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• 2004

In recent years, construction company makes inroads into the world construction market, and receives the order of extra-large concrete structure under marine environment in south-east asia specially. At this point of time, to enhance the quality of concrete, we research the High Strength Concrete (HSC) containing mineral admixtures. In this study, therefore, HSC with various combination of ordinary portland cement(OPC), blast-furnace slag(SG), silica fume(SF), and expansion admixture(SS) are cured 23 and $35^{\circ}C$ considering the site weather, and are cured in water for 3, 7 or 56 days respectively. Test results show that the HSC cured at $35^{\circ}C$ gains higher early-age strength but eventually gains lower later-age strength compare with the HSC cured at $23^{\circ}C$. Especially, HSC with combination of OPC+SG+SF+SS or OPC+SG+SF show very excellent resistance of chloride penetration. The permeability of HSC was therefore enhanced as because of containing the proper content of SG, SF, and SS and making dense micro-structure of HSC.

• Journal of the Korea Concrete Institute
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• v.24 no.1
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• pp.37-44
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• 2012

Recently, due to developments in construction technology, the use of high-performance concrete became popular. High-performance concrete when compared to the ordinary concrete can better satisfy required performances by using mineral admixture and superplasticizer. Various studies on the effect of admixture materials on the quality of high-performance concrete have been reported. But there exist limited number of reported results on the effect of cement qualities, which is the most important constituent material in concrete. Therefore, in this study, the relationship between the quality of cement and the flowability of high flowing concrete is investigated. Qualities of domestically produced cement were identified, and then the influence of the qualities of cement on the flowability of high flowing concrete is evaluated. The result showed that the dosage of required superplasticizer was dependent on cement fineness, to brain, free-CaO, and interstitial phase, which all trigger initial hydration process of cement. Particularly, the results showed that fineness of cement has a high impact on the dosage of the superplasticizer. For strength property of concrete, the dosage of superplasticizer had a significant effect on the early age strength, but had negligible effect in the long term strength.