• Title/Summary/Keyword: Vapor pressure of water

Search Result 422, Processing Time 0.029 seconds

Proton Conduction in Y2O3-doped SrZrO3 (Y2O3가 도핑된 SrZrO3에서의 프로톤전도도)

  • 백현덕
    • Journal of the Korean Ceramic Society
    • /
    • v.39 no.7
    • /
    • pp.635-641
    • /
    • 2002
  • Electrical conduction of $SrZrO_3$ doped with $Y_2O_3$ was measured as a function of gas atmosphere and temperature by impedance spectroscopy. Hydrogen dissolution, due to an enhanced driving force in the presence of oxygen, results in protonation by water incorporation. Proton conductivity increased with water vapor pressure, ${P_w}^{1/2}$. In the pure hydrogen atmosphere, the dissolution of hydrogen,$H_2(g)=2H_{i}$ +2e', is supposed to be driven by a reduced activity of electrons, ascribable to their trapping in oxygen vacancies. The activation energy of electrical conductivity was 50 kJ/mol, in wet argon atmosphere in the temperature range of $600~900^{\circ}C$, similar to those reported for proton conduction in the literature. Grain boundary effect in proton conduction was substantial in the 10% doped case at temperatures lower than $700^{\circ}C$.

Evaporation Heat Transfer and Pressure Drop Characteristics of R-134a in the Oblong Shell and Plate Heat Exchanger

  • Park, Jae-Hong;Kim, Young-Soo
    • Journal of Mechanical Science and Technology
    • /
    • v.18 no.12
    • /
    • pp.2284-2293
    • /
    • 2004
  • The evaporation heat transfer coefficient h$\_$r/ and frictional pressure drop Δp$\_$f/ of refrigerant R-134a flowing in the oblong shell and plate heat exchanger were investigated experimentally in this study. Four vertical counterflow channels were formed in the oblong shell and plate heat exchanger by four plates of geometry with a corrugated sinusoid shape of a 45 chevron angle. Upflow of refrigerant R-134a boils in two channels receiving heat from downflow of hot water in other channels. The effects of the refrigerant mass flux, average heat flux, refrigerant saturation temperature and vapor quality of R-134a were explored in detail. Similar to the case of a plate heat exchanger, even at a very low Reynolds number, the flow in the oblong shell and plate heat exchanger remains turbulent. The results indicate that the evaporation heat transfer coefficient h$\_$r/ and pressure drop Δp$\_$f/ increase with the vapor quality. A rise in the refrigerant mass flux causes an increase in the h$\_$r/ and Δp$\_$f/. But the effect of the average heat flux does not show significant effect on the h$\_$r/ and Δp$\_$f/. Finally, at a higher saturation temperature, both the h$\_$r/ and Δp$\_$f/ are found to be lower. The empirical correlations are also provided for the measured heat transfer coefficient and pressure drop in terms of the Nusselt number and friction factor.

Simulation of Pervaporation Process Through Hollow Fiber Module for Treatment of Reactive Waste Stream from a Phenolic Resin Manufacturing Process (페놀수지 생산공정에서 배출되는 반응성 폐수처리를 위한 중공사막 모듈 투과증발 공정모사)

  • C. K Yeom;F. U. Baig
    • Membrane Journal
    • /
    • v.13 no.4
    • /
    • pp.257-267
    • /
    • 2003
  • For the treatment of reactive phenolic resin waste, a simulation model of pervaporative dehydration process has been developed through hollow fiber membrane module. Some of basic parameters were determined directly from dehydration of the waste liquid through a flat sheet membrane to get realistic values. The simulation model was verified by comparing the simulated values with experimental data obtained from hollow fiber membrane module. Hollow fiber membranes with active layer coated on inside fiber were used, and feed flew through inside hollow fiber. Feed flow rate affected membrane performances and reaction by providing a corresponding temperature distribution of feed along with fiber length. Feed temperature is also a crucial factor to determine dehydration and reaction behavior by two competing ways; increasing temperature increases permeation rate as well as water formation rate. Once the permeate pressure is well below the saturated vapor pressure of feed, permeate pressure had a slightly negative effect on permeation performance by slightly reducing driving force. As the pressure approached the vapor pressure of feed, dehydration performances declined considerably due to the activity ratio of feed and permeate.

Performance Characteristics of Air-Cooled Heat Pump System using Hydrocarbon Refrigerants According to Variation of Outdoor Temperature (실외 온도 변화에 따른 HC계 공랭식 히트펌프 시스템의 성능 특성)

  • Jun Chul-Ho;Lee Ho-Saeng;Kim Jae-Dol;Yoon Jung-In
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.18 no.3
    • /
    • pp.218-224
    • /
    • 2006
  • The performance of an air to water vapor compression heat pump has been investigated experimentally. The main purpose of this study was to study the possibilities of using hydrocarbon refrigerants as a working fluid to replace R-22 for vapor compression heat pumps. Pure R-22 and R-290, R-600a, R-1270 were considered as working fluids. The performance of the system was characterized by compression shaft work, refrigeration capacity, pressure ratio, discharge temperature and COP. The experimental apparatus has basic parts of cycle that uses the air as a heat source. The experimental results show that refrigeration capacity of HC refrigerants is same or higher than that of R-22. On the other hand, compression shaft work of HC refrigerants is lower than that of R-22. Compression shaft work is lower than that of R-22. Come to the conclusion that, it is possible that hydrocarbon refrigerants could be drop-in alternatives for R-22.

Effects of Individual Sweating Response on Changes in Skin Blood Flow and Temperature Induced by Heat of Sorption Wearing Cotton Ensemble

  • Tanaka, Kaori;Hirata, Kozo
    • Fashion & Textile Research Journal
    • /
    • v.2 no.5
    • /
    • pp.398-404
    • /
    • 2000
  • We examined the effect of individual sweating responses on thermoregulatory responses induced by heat of sorption, immediately after the onset of sweating. The present study consists of two experiments. In experiment 1, made of 100% cotton (C) and 100% polyester (P) clothing were exposed in the chamber at ambient temperature (Ta) of $27.2^{\circ}C$ and relative humidity (rh) raised from 50% to 95% at five different increase rates of environmental vapor pressure (VP). The increase rate of clothing surface temperature (Tcs), peak Tcs and peak time showed significant correlation with the increase rate of environmental VP in C-clothing (p<0.05). In experiment 2, seven female subjects were studied during leg water immersion ($35-41^{\circ}C$) for 70min in Ta of 27.2 and 50%rh. There were significant positive correlations in the increase rate of clothing microclimate VP vs. changes in Tcs, skin blood flow, mean skin temperature and mean body temperature (p<0.05). The present results showed that individual clothing microclimate VP had significant effects on thermoregulatory responses induced by heat of sorption wearing C ensembles.

  • PDF

Phase Behavior of Sorbitan Monopalmitate Surfactant in Supercritical Carbon Dioxide (초임계 이산화탄소에서 소르비탄 모노팔미테이트 계면활성제의 상거동에 관한 연구)

  • Oh, Kyung Hwan;Kim, Eun Jin;Shin, Hun Yong
    • Clean Technology
    • /
    • v.19 no.1
    • /
    • pp.8-12
    • /
    • 2013
  • Phase behavior of carbon dioxide + surfactant binary system and carbon dioxide + surfactant + water ternary system was investigated at the temperatures from 318 K to 348 K by using high pressure vapor liquid equilibrium apparatus containing variable-volume view cell. Sorbitan monopalmitate was used as the surfactant. The cloud point pressures for the binary mixture of carbon dioxide + sorbitan monopalmitate increased with an increasing of system temperatures and the maximum cloud point pressure was observed at the composition of 0.226 wt% of sorbitan monopalmitate. On the other hand, as the temperatures and compositions of water increased, the cloud point pressures for ternary system containing 0.1 wt% of sorbitan monopalmitate increased significantly. For the ternary system of constant 0.2 wt% of water, the cloud point pressure curves show relatively flat according to the change of compositions of surfactant. The cloud point pressures increased when the temperatures and compositions of water increased.

Relationship Between Frictional Sounds and Mechanical Properties of Vapor Permeable Water Repellent Fabrics for Active Wear (스포츠웨어용 투습발수직물의 마찰음과 역학적 성질 간의 상관성)

  • Yang, Yoon-Jung;Park, Mi-Ran;Cho, Gil-Soo
    • Fashion & Textile Research Journal
    • /
    • v.10 no.4
    • /
    • pp.566-571
    • /
    • 2008
  • Frictional sounds of 8 vapor permeable water repellent fabrics by sound generator were recorded and analyzed through FFT fast Fourier transform analysis. The frictional Sounds were quantified by calculating level pressure of total sound(LPT), the level range(${\Delta}L$) and the frequency difference(${\Delta}f$). Mechanical properties were measured by KES-FB. LPT values of specimens finished wet coating were higher than those of other kinds of finishing. ${\Delta}L$ values of specimens laminated were highest. Absolute values of ${\Delta}f$ were high in the cire finished and laminated specimens. Values for bending rigidity, shear stiffness and energy required for the compression of coated specimens increased compared with the cire finished and laminated specimens. Laminated specimens had high values of frictional coefficient and low values of surface roughness. Relationship between frictional sounds and mechanical properties analysed by use of correlation coefficients and stepwise regression. LPT showed significant correlation with elongation, tensile energy, geometrical roughness, weight and thickness. ${\Delta}L$ was highly correlated with tensile linearity, frictional coefficient, and ${\Delta}f$ with tensile linearity, weight and thickness. LPT were revealed to be explained by elongation and weight. ${\Delta}L$were predicted by tensile linearity, and ${\Delta}f$ by tensile linearity and thickness.

Numerical Analysis of Vertical Plate Absorber for Optimal Design

  • Yoon, Jung-In;Moon, Choon-Geun;Phan, Thanh-Tong
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.28 no.2
    • /
    • pp.252-262
    • /
    • 2004
  • A model of simultaneous heat and mass transfer process in absorption of refrigerant vapor into a lithium bromide solution of water-cooled vertical plate absorber. which was considered to the change of refrigerant vapor pressure along the plate width direction. was developed to evaluate the compactness of plate absorber and supply basis data for optimal design of plate absorber. The effects of plate interval as well as the effect of capacity for one piece of plate absorber on plate absorber size such as plate height. plate heating area and plate absorber volume have been investigated. It is confirmed that there is exist an optimal plate interval minimizing plate absorber volume. And the smaller capacity for one piece of plate absorber. the smaller plate absorber volume is obtained.

Development of Sodium Voiding Model for the KALIMER Analysis

  • Chang, Won-Pyo;Dohee Hahn
    • Nuclear Engineering and Technology
    • /
    • v.34 no.4
    • /
    • pp.286-300
    • /
    • 2002
  • An algorithm for the sodium boiling model has been developed for calculation of the void reactivity feedback as well as the fuel and cladding temperatures in the KALIMER core after onset of sodium boiling. Modeling of sodium boiling in liquid metal reactors using sodium as a coolant is necessary because of phenomenon difference comparing with that observed generally in light water reactor systems. The applied model to the algorithm is the multiple-bubble slug ejection model. It allows a finite number of bubbles in a channel at any time. Voiding is assumed to result from formation of bubbies that (ill the whole cross section of the coolant channel except for the liquid film left on the cladding surface. The vapor pressure, currently, is assumed to be uniform within a bubble The present study is focused on not only demonstration of the vapor bubble behavior predicted by the developed model, but also confirmation of a qualitative acceptance for the model. As a result, the model can represent important phenomena in the sodium boiling, but it is found that further effort is also needed for its completition.

Comparison of the neural networks with spline interpolation in modelling superheated water (물의 과열증기 모델링에 대한 신경회로망과 스플라인 보간법 비교)

  • Lee, Tae-Hwan;Park, Jin-Hyun;Kim, Bong-Hwan
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • v.12 no.4
    • /
    • pp.685-690
    • /
    • 2008
  • In numerically evaluating the thermal performance of the heat exchanger, numerical values of thermodynamic properties such as temperature, pressure, specific volume, enthalpy and entropy are required. But the steam table or diagram itself cannot be directly used without modelling. In this study the applicability of neural networks in modelling superheated water vapor was examined. The multi-layer neural networks consist of an input layer with 2 nodes, two hidden layers with 15 and 25 nodes respectively and an output layer with 3 nodes. Quadratic spline interpolation was also applied for comparison. Neural networks model revealed smaller percentage error compared with spline interpolation. From this result, it is confirmed that the neural networks could be a powerful method in modelling the superheated water vapor.