• Title/Summary/Keyword: Vapor phase

Search Result 1,127, Processing Time 0.031 seconds

Mass production of carbon nanotubes using Vapor Phase Growth (기상합성법을 이용한 탄소나노튜브의 대량합성)

  • 류승철;이태재;이철진
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2001.07a
    • /
    • pp.123-126
    • /
    • 2001
  • Multiwalled carbon nanotubes were massively produced by the catalytic reaction of C$_2$H$_2$ - Fe(CO)$\sub$5/ mixture at 750 - 950$^{\circ}C$ in a quartz tube reactor and over quartz substrates. Well-aligned MWNT array grows perpendicular to the quartz tube reactor and the quartz substrates at an average of 60 nm in diameter and up to several thousands of micrometers in length. This method does not require any pretreatment of substrates and CNTs are grown at atmospheric pressure. It could be suitable for mass production of multiwalled nanotubes. Scanning electron microscope and transmission electron microscope images of the nanotubes deposited on the substrates allowed us to monitor the quality of MWNTs grown under different operating conditions.

  • PDF

Numerical Analysis of the Effect of Injection Pressure Variation on Spray Characteristics (분사압력변화가 분무특성에 미치는 영향에 관한 수치적 고찰)

  • Park K.
    • Journal of computational fluids engineering
    • /
    • v.2 no.2
    • /
    • pp.89-96
    • /
    • 1997
  • High injection pressure system has been developed as a measure to reduce harmful exhaust gases. In order to understand the effect of pressure on diesel spray injection process, wide range of high injection pressure was tested. The gas phase is modelled by the Eulerian continuum conservation equations of mass, momentum, energy and fuel vapour fraction. The liquid phase is modelled following the discrete droplet model approach in Lagrangian form. The droplet distributions, vapor fractions and gas flows are analyzed in various injection pressure cases. The distributions of spray and vapor increase and the Sauter mean diameter decreases with increasing injection pressure quickly in a low pressure area but slowly in a high pressure area.

  • PDF

Synthesis of Mullite Whiskers by Vapor-Solid Reaction in the System of Al(OH)3-SiO2-AlF3 (Al(OH)3-SiO2-AlF3계에서 기상-고상반응에 의한 뮬라이트 휘스커 합성)

  • Lee, Hong-Lim;Kang, Jong-Bong
    • Journal of the Korean Ceramic Society
    • /
    • v.43 no.6 s.289
    • /
    • pp.376-382
    • /
    • 2006
  • In the $Al(OH)_3-SiO_2-AlF_3$ system, leaf-shaped fluorotopaz was first formed at $800^{\circ}C$ and mullite whisker was formed at $1,100^{\circ}C$. The mass transportation of Al and Si as gas phase, the fast reaction and growth, and the absence of liquid phase existence in mullite whisker showed that the formation and growth of mullite was from the solid-vapor reaction.

Characteristics of Spray Development from Vapor/Liquid Phase Distribution for GDI Spray (GDI 분무의 기.액상 분포를 통한 분무의 성장 특성)

  • 황순철;최동석;김덕줄
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.9 no.2
    • /
    • pp.50-58
    • /
    • 2001
  • The purpose of this research is to obtain the information of the development process of a vaporizing GDI spray using exciplex fluorecence method. Fluorobenzene/DEMA system was used as the exciplex-forming dopants. The 2-D spray images of liquid and vapor phases were acquired, and the behavior of both phases was analyzed by the image processing. The experiment was performed at the three different ambient perssures and the ambient temperature of 273K and 473K. As the result of this work, it was found that the development characteristics of GDI spray have stronger effect on the ambient pressure than on the ambient temperature. With an increase of ambient pressure, the distribution of vapor phase was decreased and the concentration of that was denser. Two regions, namely cone and mixing regions could be identified from those resulrs.

  • PDF

The prediction of vapor-liquid equilibrium data for 2-methyl-2-propanol-2-butanone system at low pressure (저압하에서 2-methyl-2-propanol-2-butanone계의 기액평형치의 추산)

  • Shim, Hong-Seub;Rhew, Jong-Ha
    • Journal of the Korean Society of Industry Convergence
    • /
    • v.7 no.1
    • /
    • pp.97-105
    • /
    • 2004
  • The Vapor-liquid equilibrium data for the binary system of 2-methyl-2-propanol-2-butanone are measured at subatmospheric pressure of 100, 200, 300, 400, 500, 600, 700 and 760 torr. This study shows that the relations between logarithmic values of relative valatility(log ${\alpha}$)and liquid phase composition(${\chi}$) in the above binary systems are expressed as a linear function. When the linear relationships of between logarithmic values of relative volatilities and liquid phase compositions in the binary systems of various pressure intersect at a point, this empirical equation can be applied to the systems of this kind. From these relations the vapor-liquid equilibrium data are estimated and compared with the measured values to be in a good agreement with in accuracy ${\pm}0.0021$ for the various pressure.

  • PDF

Estimation of Flash Points of Flammable Liquid Mixtures with Non-flammable Liquids (난연성액체에 따른 가연성 액체혼합물의 인화점 추산)

  • 이수경;엄종호;하동명;이성민
    • Journal of the Korean Society of Safety
    • /
    • v.7 no.3
    • /
    • pp.53-59
    • /
    • 1992
  • A general theory is developed which enables closed-cup flash points of mixtures of flammable and non-flammable liquid to be estimated from a knowledge of a certain properties of flammability diagram by thermodynamic method. The estimated equations is shown the effect of both the flame inhibiting properties of the vapor of the non-flammable component and the relative volatility of that component. The vapor phase flame inhibition effect results in a even greater elevation of flash points than the rotative volatility of that component. Especially in cases of similar vapor phase flame inhibition of the non-flammable component, the rotative volatility is affected greater elevation of flash points(extinguishing effect).

  • PDF

An Analysis on Structure of Impinging and Free Diesel Spray with Exciplex Fluorescence Method in High Temperature and Pressure Field

  • Yeom, Jeong-Kuk;Park, Jong-Sang;Chung, Sung-Sik
    • Journal of Mechanical Science and Technology
    • /
    • v.19 no.12
    • /
    • pp.2281-2288
    • /
    • 2005
  • Because an injected spray development process consists of impinging and free spray in the diesel engine, it is needed to analyze the impinging spray and free spray, simultaneously, in order to study the diesel spray behavior. To dominate combustion characteristics in diesel engine is interaction between injected fuel and ambient gas, that is, process of mixture formation. Also it is very important to analyze liquid and vapor phases of injected fuel on the investigation of mixing process, respectively and simultaneously. Therefore, in this study, the behavior characteristics of the liquid phase and the vapor phase of diesel spray was studied by using exciplex fluorescence method in high temperature and injection pressure field. Finally, it can be confirmed that the distribution of vapor concentration is more uniform in the case of the high injection than in that of the low injection pressure.

A Study on the Development of Vapor Phase Cleaning Equipment for Semiconductor Processing (반도체 공정에서의 기상 세정장비 개발에 관한 연구)

  • 박헌휘;이춘수;최승우;함승주
    • Proceedings of the KAIS Fall Conference
    • /
    • 2001.05a
    • /
    • pp.79-81
    • /
    • 2001
  • 저압 기상 영역에서 Anhydrous HF 가스와 Methanol vapor를 사용하는 산화막 식각공정을 수행하기 위하여 (1) 반응기 부피의 최소화, (B) 공정압력의 최소화, (3) 고순도 알루미나 Reactor 적용, (4) Cluster화의 개념을 적용한 VPC 장치를 제작하였다. Wafer의 온도, HF의 분압 및 Working Pressure 등의 공정변수에 따른 Oxide Wafer의 식각특성의 변화를 확인하였다. 또한 Etch Uniformity를 향상시키기 위하여 Shower Head 구조를 변경시켜서 실험하였으며, CFD Simulation을 이용하여 Reactor내에서의 HF gas 및 Methanol vapor의 분율을 예측하였다.

Experimental investigation of two-phase flow and wall heat transfer during reflood of single rod heater (단일 가열봉의 재관수 시 2상유동 및 벽면 열전달에 관한 실험적 연구)

  • Park, Youngjae;Kim, Hyungdae
    • Journal of the Korean Society of Visualization
    • /
    • v.18 no.3
    • /
    • pp.23-34
    • /
    • 2020
  • Two-phase flow and heat transfer characteristics during the reflood phase of a single heated rod in the KHU reflood experimental facility were examined. Two-phase flow behavior during the reflooding experiment was carefully visualized along with transient temperature measurement at a point inside the heated rod. By numerically solving one-dimensional inverse heat conduction equation using the measured temperature data, time-resolved wall heat flux and temperature histories at the interface of the heated rod and coolant were obtained. Once water coolant was injected into the test section from the bottom to reflood the heated rod of >700℃, vast vapor bubbles and droplets were generated near the reflood front and dispersed flow film boiling consisted of continuous vapor flow and tiny liquid droplets appeared in the upper part. Following the dispersed flow film boiling, inverted annular/slug/churn flow film boiling regimes were sequentially observed and the wall temperature gradually decreased. When so-called minimum film boiling temperature reached, the stable vapor film between the heated rod and coolant was suddenly collapsed, resulting in the quenching transition from film boiling into nucleate boiling. The moving speed of the quench front measured in the present study showed a good agreement with prediction by a correlation in literature. The obtained results revealed that typical two-phase flow and heat transfer behaviors during the reflood phase of overheated fuel rods in light water nuclear reactors are well reproduced in the KHU facility. Thus, the verified reflood experimental facility can be used to explore the effects of other affecting parameters, such as CRUD, on the reflood heat transfer behaviors in practical nuclear reactors.

Growth and Properties of GaN on $\textrm{MgAl}_{2}\textrm{O}_{4}$ Substrate by Hydride Vapor Phase Epitaxy Method ($\textrm{MgAl}_{2}\textrm{O}_{4}$ 기판위에 GaN의 Hydride Vapor Phase Epitaxy성장과 특성)

  • Lee, Yeong-Ju;Kim, Seon-Tae;Kim, Bae-Yong;Hong, Chang-Hui
    • Korean Journal of Materials Research
    • /
    • v.7 no.8
    • /
    • pp.707-713
    • /
    • 1997
  • HVPE(hydride vapor phase epitaxy)법으로 (111)MgAI$_{2}$ $O_{4}$기판위에 GaN 후막을 성장하였다. GaN를 성장하기 전에 기판에 표면을 GaCI로 처리한 수 성장하였을 때 이중 X선 회절 피크의 반치폭이 710 arcsec로서 N $H_{3}$로 처리한 후 성장한 GaN에 비하여 작았으며, 무색 투명의 경면상태가 얻어\ulcorner다. 113$0^{\circ}C$의 온도에서 성장한 GaN 의 광루미네센스(PL)특성과 동일하게 나타났다. 10K의 온도에서 측정된 PL 스펙트럼은 자유여기자와 속박여기자의 재결합천이에 의한 피크들과 Mg과 관련된 도너-억셉터 쌍 사이의 재결합 및 이의 1LO, 2LO, 3LO 및 4 LO 포논복제에 의한 피크들이 나타났다. 성장된 GaN는 n형의 전도성을나타내었으며, 캐리어 이동도와 농도는 각각 21.3$\textrm{cm}^2$/V ㆍsec와 4.2 x $10^{18}$$cm^{-3}$이었다.

  • PDF