• 한국재료학회지
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• 제6권12호
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• pp.1257-1262
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• 1996

1.0Cr-1.0Mo-0.25V강 용접부의 크립 파단 시험시 파단 발생 원인에 관한 연구가 시행되었다. 파괴는 Intercritical Heat Affected Zone에서 발생하였으며 파단면에서 구상의조대한 M6C탄화물이 발견되었다. 모재는 molybdenum 주성분의 M2C, vanadium 주성분의 M4C3 및 chromium 주성분의 M23C6와 M7C3 탄화물이 존재하였다. 모의 실험 결과 준안정 상태인 M2C 탄화물은 85$0^{\circ}C$, 10oh에서 안정한 M6C탄화물로 변태하였다. M6C 탄화물은 주변의 molybdenum 농도를 떨어뜨려 강도의 저하를 가져오며 크립 기공의 발생 원인을 제공하였다.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2012년도 추계총회 및 학술대회 논문집
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• pp.101-102
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• 2012

Thermal Diffusion Process(TD Process)을 통하여 베어링강 소재인 SUJ2 표면에 Vanadium Carbide를 석출시켜 표면 물성에 관한 연구를 진항하였다. $900{\sim}950^{\circ}C$ 온도와 2~6H 공정시간에 따라 TD Process에 의한 코팅층의 변화를 Micro Vikers Hardness Tester와 광학현미경, SEM, EDS를 통하여 관찰하였다. 그 결과 공정시간 및 온도는 코팅층 성장과 비례한다는 것을 확인 할 수 있었고 SUJ2 표면에 성장된 코팅층은 높은 경도값을 갖는 VC, CrC 코팅층임을 확인하였다.

• 한국기계연구소 소보
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• 통권16호
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• pp.29-39
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• 1986

Several heat treatment were applied to on HSLA steel of type StE47 (German standard) to produce five ferrite microstructures of different strength and at least two different grain sizes respectively. Whereas the ferrite microstructure had a strong influence on yield strength the effect of grain size was negligible. The different strength levels could be explained by regarding the arrangement of dislocations and vanadium carbide particles, and their mutual interaction. Specimens tranformed at $600^{\circ}C$ showed the highest strength levels. In this case precipitation has occured after the $\gamma$- $\alpha$ transformation. Very small VC particles are arranged mostly along dislocation lines. Increasing both, grain size and pearlite volume fraction leads to a remarkable shift of transition temperature which was further enhanced by increasing ferrite strength.

• 대한금속재료학회지
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• 제46권8호
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• pp.477-481
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• 2008

The secondary hardening and fracture behavior in P/M high speed steels bearing V content of 9 to 10 wt% have been investigated in terms of austenitizing temperature and precipitation behavior. Austenitizing was conducted at 1,100 and $1,175^{\circ}C$ of relatively low and high temperatures. Coarse primary carbides retained after austenitization were mainly V-rich MC type. They give a significant influence on hardeness and toughness, as well as wear resistance. Tempering was performed in the range of $500{\sim}600^{\circ}C$. The peak hardness resulting from the precipitation of the fine MC secondary carbides was observed near 520, irrespective of austenitizing temperature. Aging acceleration(or deceleration) did not occur with increasing austenitizing temperature because it mainly influences contents of V and C of matrix through the dissloution of coarse primary MC containing lots of V and C. The precipitation of secondary MC carbides, which also contain V and C, did not change the aging kinetics itself. In the 10V alloy containing much higher C content, the impact toughness was lower than 9V alloy, because of the larger amount of primary carbide and high hardness.

• 한국재료학회지
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• 제9권10호
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• pp.1018-1024
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• 1999

Sn-3.5Ag 무연합금을 Cu 및 Alloy42 리드프레임에 납땜접합 (solder joint)하고 미세조직, 젖음성, 전단강도, 시효효과를 측정하여 비교하였다. Cu의 경우, 땜납의 Sn기지상안에 Ag(sub)3Sn과 Cu(sub)6Sn(sub)5상이, 그리고 땜납/리드프레임의 경계면에서는 1∼2㎛ 두께의 Cu(sub)6Sn(sub)5상이 형성되었다. Alloy42의 경우, 기지상내에 있는 낮은 밀도의 Ag(sub)3Sn상만이, 그리고 계면에는 0.5∼1.5㎛ 두께의 FeSn(sub)2이 형성되었다. 한편, Cu에 비해 Alloy42 리드프레임에서 퍼짐면적은 크고 접촉각은 작아 더 우수한 젖음성을 나타내었으나, 전단강도는 35%, 연신율은 75%로 낮았다. 180℃에서 1주일간 시효처리 후, Cu 리드프레임에는 계면에 η-Cu(sub)6Sn(sub)5 층외에 ξ-Cu(sub)3Sn층이 성장하였고, Alloy42 리드프레임에는 기지상내에 Ag(sub)3Sn이 구형으로 조대하게 성장하였고, 계면에는 FeSn(sub)2층만이 약 1.5㎛로 성장하였다.

• 열처리공학회지
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• 제6권2호
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• pp.59-69
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• 1993

Bending fracture strength test and impact strength test were made for VC coated die steels treated by immersing in molten borax bath and for hardened steels which were quenched and tempered, in order to clarify the effect of VC coating at $1000^{\circ}C$. The material used in this investigation was representative cold and hot work die steels STD11, STD61. The results obtained are as follows. 1) The bending fracture strength of VC coated die steel (STD11, STD61) was lessened with increasing the thickness of the VC coated layer. 2) With increasing the immersing time (imcreasing the thickness of the VC coated layer) the maximum hardness was obtained at 480 minutes holding, after that holding time hardness was decreased. 3) The impact strength of the VC coated die steel was not decreased. In the casse of STD11, it was higher than that of the quenched condition especially at low tempering temperature, and vice versa at high tempering temperature. However in the case of STD61 shows the result to the contrary.

• 열처리공학회지
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• 제6권3호
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• pp.166-177
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• 1993

Bending fatigue strength tests were made for VC coated die steels which were coated by immersing in a molten borax bath and for hardened die steels which were quenched and tempered, in order to clarify the effect of VC coating at $1000^{\circ}C$ and $1025^{\circ}C$. The material used in this investigation was a representative cold and hot die steels STD11, STD61. The results obtained are as follows. 1) The endurance limit of VC coated die steels was a little lower than that of hardened die steels. It is considered to be mainly due to the decfl.lase of hardness in the substrates. Accordingly, the endurance limit reo covered almost to the level of hardened die steels by an additional diffusion treatment. 2) The initiation point of fatigue fracture of VC coated die steels in reversed bening was on the substrate just under the VC layer. Hence, the endurance limit is corrected to the hardness of this part. 3) But, there is a considerable scatter in this relationship and the endurance limit of VC coated die steels was a little lower than that of hardened die steels with equal hardness. These results suggest that the fatigue strength of VC coated die steels is determined not only by the hardness but also by other factors. For example. the residual stress in the substrate just under VC coating layer is one of the factors besides hardness which is mainly related to the retained austenite(${\gamma}_R$).

• 대한금속재료학회지
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• 제46권10호
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• pp.634-645
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• 2008

In this study, surface composites were fabricated with Fe-based amorphous alloy powders and VC powders by high-energy electron beam irradiation, and the correlation of their microstructure with hardness and fracture toughness was investigated. Mixture of Fe-based metamorphic powders and VC powders were deposited on a plain carbon steel substrate, and then electron beam was irradiated on these powders without flux to fabricate surface composites. The composite layers of 1.3~1.8 mm in thickness were homogeneously formed without defects and contained a large amount (up to 47 vol.%) of hard $Cr_2B$ and $V_8C_7$ crystalline particles precipitated in the solidification cell region and austenite matrix, respectively. The hardness of the surface composites was directly influenced by hard $Cr_2B$ and $V_8C_7$ particles, and thus was about 2 to 4 times greater than that of the steel substrate. Observation of the microfracture process and measurement of fracture toughness of the surface composites indicated that the fracture toughness increased with increasing additional volume fraction of $V_8C_7$ particles because $V_8C_7$ particles effectively played a role in blocking the crack propagation along the solidification cell region heavily populated with $Cr_2B$ particles. Particularly in the surface composite fabricated with Fe-based metamorphic powders and 30 % of VC powders, the hardness and fracture toughness were twice higher than those of the surface composite fabricated without mixing of VC powders.