• 제목/요약/키워드: VOCs: Volatile Organic Compounds

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광촉매 플라즈마 반응에 의한 몇가지 VOCs의 제거에 관한 연구 (Study on the Decomposition of Some Volatile Organic Compounds by Photocatalyst Plasma Reaction)

  • 허경욱
    • 한국대기환경학회지
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    • 제16권4호
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    • pp.373-380
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    • 2000
  • A new type of photocatalyst plasma air purification filter for decomposition of some VOCs has been developed. The photocatalyst plasma air purification filter employs the pulsed discharge plasma as an energy source of TiO2. photocatalyst instead of UV light. In closed room(2m3) test removal efficiency of some VOCs was 80∼100% in 15∼24 hours. In the initial step of phptocatalyst plasma reaction. Acetone and Nitromethane etc were detected. But they were completely oxidized to CO2 and H2O.

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Daily Life Cycle에서의 VOCs 노출정도 분석연구 (A Study on Exposure to Volatile Organic Compounds through Daily Life Cycle)

  • 조정범;이병규
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2000년도 춘계학술대회 논문집
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    • pp.317-318
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    • 2000
  • 오늘날 우리는 문명이 발달하고 고도로 산업화된 사회의 구성원으로써 살아나가고 있다. 그러나 우리의 삶을 영위하는 과정에서 생긴 각종 환경오염에 노출되고 있어서 이로 인하여 우리의 삶의 질이 저하되기도 한다. 여러 가지 오염물질이 대기중에 가득한 가운데서 순간순간 숨을 쉬며 살아가는 우리 인간은 호흡기나 피부를 통하여 각종 대기오염물질에 직·간접적으로 노출되고 있는 실정이다. 이중 특히, 벤젠이나 톨루엔과 같은 휘발성유기화합물(Volatile Organic Compounds : VOCs)은 실내 생활이나 작업, 야외활동, 또 여러 삶의 과정에서도 노출되고 있는 듯 하다. (중략)

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산업도시의 Daily Life Cycle에서 VOCs 노출에 따른 위해도 분석연구 (Risk Assessment on Exposure to Volatile Organic Compounds through Daily Life Cycle in City with Industrial Complex)

  • 조정범;이병규
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2000년도 추계학술대회 논문집
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    • pp.283-284
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    • 2000
  • 석유화학, 비철금속공단, 조선 및 기계공단 등과 같은 대형 산업단지를 가진 울산지역의 대기오염은 타 지역에 비하여 꽤 높은 것으로 보고되고 있다. 또한 울산지역은 인구가 백만이 넘는 대형도시이고, 사람과 각종 공단 생산제품을 수송하기 위한 교통밀도도 꽤 높으므로 많은 양의 휘발성 유기화합물(Volatile Organic Compounds : VOCs)이 배출되고 있다. 흔히 VOC는 대류권 오존 농도의 전구체로서 역할을 하여 대류권 오존농도 감소를 위한 연구가 활발히 진행되고 있다. (중략)

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상태방정식을 이용한 주유소 탱크에서의 유증기 배출량 산정법에 관한 연구 (A Study on the Calculation Method of VOCs Emissions Using Equation of State in the Gas Station Tank)

  • 박태준;오휘성;이창언
    • 한국연소학회지
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    • 제20권4호
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    • pp.42-48
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    • 2015
  • This study was investigated the estimation of VOCs (Volatile Organic Compounds) emission from a gas station tank. To improve the atmosphere environmental quality near the gas station, the installation of vapor recovery system has been expanded recently. Therefore, it was necessary to calculate VOCs emissions from the gas station tank with vapor recovery systems for evaluation of their performance. The VOCs emissions are difficult to measure directly because of various sources and irregularly emission by pressure rise. In this study, VOCs emissions were estimated by simple calculation based on the equation of state for measured pressure, temperature and volume of a gasoline tank at a gas station. The result confirmed that the present national emission factor did not have significant discrepancy with the calculated value.

VOCs의 위해성 평가를 위한 노출분석 방법 연구 (The Development of Exposure Assessment Tools for Risk Assessment of Volatile Organic Compounds)

  • 조성준;신동천;정용;이덕희
    • Environmental Analysis Health and Toxicology
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    • 제17권2호
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    • pp.147-160
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    • 2002
  • Volatile organic compounds (VOCs) are an important public health issue in Korea and many important questions remain to be addressed with respect to assessing exposure to these compounds. Because they are ubiquitous and highly volatile, special techniques must be applied in their analytic determination Valid Personal exposure assessment methods are needed to evaluate exposure frequency, duration and intensity, as well as their relationship to personal exposure characteristics. Biological monitoring is also important since it may contribute significantly in risk assessment by allowing the estimation of effective absorbed doses. This study was on ducted to establish the environmental measurement, personal dosimetry and biological monitoring methods for VOCs. These methods are needed to compare blood, urinary and exhalation breath VOC levels and to provide tools for risk assessment of VOC exposure. Passive monitors (badge type) and a active samplers (trap) for the VOCs collection were used for air sampling. Methods development included determining the minimum detectable amounts of VOCs in each media, as well as evaluating collection methods and developing analytical procedures. Method reliability was assessed by determining breakthrough volumes and comparing results between laboratories and with other methods. A total capacity of trap used in this study was 60ι. Although variable by compound, the average breakthrough was 20%. Also, there was no loss of compounds in trap even if keep for 45 day in -7$0^{\circ}C$. The recovery of active and passive methods was 69% ~ 126% and method detection limit was 0.24 $\mu\textrm{g}$/trap and 0.07 $\mu\textrm{g}$/badge. There was no statistical difference (P > 0.05) between active and passive methods.

어린이용품에 함유된 휘발성유기화합물의 비발암 위해성평가 (Risk Assessment for Non-Cancer Effects of Volatile Organic Compounds in Children's Products)

  • 김정곤;서정관;김탁수;박건호
    • 한국환경보건학회지
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    • 제40권3호
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    • pp.178-186
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    • 2014
  • Background: This study was conducted to assess health risks in regard to exposure by children to volatile organic compounds (VOCs) in children's products. Methods: Ten VOCs were measured by head-space gas chromatography in children's products, including toys, oil pastels, sign pens, furniture, ball pools, and playmats. We estimated the average daily dose (ADD) via inhalation during the use of these children's products and calculated hazard quotient (HQ) by dividing ADD by reference dose of VOCs. Results: Among the measured VOCs, five compounds were identified in children's products: benzene, ethylbenzene, styrene, toluene, and xylene. The detection rates of VOCs in toys, ball pools, furniture, playmats, sign pens, and oil pastels were 85%, 100%, 100%, 30%, 100%, and 60%, respectively. The maximum levels of VOCs were 0.18 mg benzene/kg in toys, 5.92 mg toluene/kg in playmats, 10.37 mg ethylbenzene/kg in ball pools, 24.85 mg xylene/kg in toys, and 118.29 mg styrene/kg in ball pools. From exposure levels of VOCs in the children's products HQs were calculated within a range of $5.71{\times}10^{-10}$ to $4.77{\times}10^{-4}$. The HQ of xylene was the highest for children aged 0-6 playing on the playmats. However, the HQ via inhalation exposure to VOCs in individual products did not exceed 1.00. Conclusion: Based on the results, it was concluded that the use of these children's products do not pose health risks to children.

생물살수여과법을 이용한 공기 중 VOC 제거 기술 (Technology of VOC Removal in Air by Biotrickling Filter)

  • 원양수
    • 한국대기환경학회지
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    • 제19권1호
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    • pp.101-112
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    • 2003
  • Biological methods are frequently used for treatment of contaminated air, containing volatile organic compounds and odor compounds in low concentrations and high flow rate of air streams. For more than 20 years. biofilter has been recognized as a cost effective technology for the purification of contaminated air. Most commercial applications before 1990 were for control of odors. In the past decades major progress has been accomplished in the development of vapor phase bioreactor. in particular biotrickling filers. Biotrickling filters are more complex than biofilters. but are usually more effective, especially for the treatment of compounds which are difficult to degrade or compounds that generate acidic by-products. While the level of understanding of biotrickling filtration process for VOCs still remains limited. the evidence success of biotreatment of VOC in air resulted in pursuing active research. This paper presents fundamental and practical aspert of VOCs treatment from air in biotrickling filter. Special emphasis is given to the operating parameters and the factors influencing performance for biotrickling filter.

Development of a New-type Apparatus Decomposing Volatile Organic Compounds using a Combination System of an Electrical Exothermic SiC Honeycomb and a Catalytic Filter

  • Nishikawa, Harumitsu;Takahara, Yasumitsu;Takagi, Osamu;Tsuneyoshi, Koji;Kato, Katsuyoshi;Ihara, Tadayoshi;Wakai, Kazunori
    • Asian Journal of Atmospheric Environment
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    • 제2권2호
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    • pp.75-80
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    • 2008
  • A new-type apparatus decomposing volatile organic compounds (VOCs) using a combination system of an electrical exothermic SiC honeycomb and a catalytic filter was developed. This linear combination system is very useful to the catalytic decomposition of VOCs, because the gas involving VOCs is well heated in the SiC honeycomb and then flows into the catalytic filter. In the proposed apparatus, the outlet gas temperatures of SiC honeycomb maintained at ca. $300^{\circ}C$ after 5 min from the starting of applying electric current, and sufficient for the catalytic degradation of VOC components, i.e. toluene, isopropanol, methyl ethyl ketone and ethyl acetate. The average decomposition rate of total VOCs exhausted from a printing factory was 85% using pt catalyst at SV=19,000 in this system.

활성탄소섬유를 이용한 휘발성유기화합물 (VOCs-BTX)의 흡착특성 (Adsorption Characteristics of Volatile Organic Compounds-BTX on Activated Carbon Fiber)

  • 김한수;박영성
    • 한국대기환경학회지
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    • 제15권6호
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    • pp.805-812
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    • 1999
  • Adsorption characteristics of volatile organic compounds(VOCs) by activated carbon fiber(ACF) were investigated using a continuous system for benzene, toluene, xylene(BTX) generation. Studied characteristics for adsorption were equilibrium capacity, accumulative adsorption, and breakthrough curve. Operating variables were adsorption temperature(25~45$^{\circ}C$) and partial pressure(1.2~12 mmHg) of BTX. The experimental results show that the adsorption equilibrium capacity increases with increasing partial pressure of BTX and decreases with increasing temperature. It was also found that the break point was decreased with increasing partial pressure, temperature and gas flow rate due to an effect of mass transfer of adsorbate.

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울산공단지역의 대기중 휘발성 유기화합물에 대한 위해도 평가 (Risk Assessment of Airborne Volatile Organic Compounds in Ulsan Industrial Complex Area)

  • 남병현;윤미정;이진홍
    • 한국안전학회지
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    • 제14권2호
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    • pp.103-108
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    • 1999
  • This study focused on risk assessment for inhalation of airborne volatile organic compounds (VOCs) in Ulsan industrial complex area. For non-carcinogenic risk, even the highest hazard index of toluene was estimated to be $4.8\times10^{-2}$, which was much lower than 1. The total hazard index of VOCs was estimated to be $5.8\times10^{-2}$. However, lifetime average cancer risk from the inhalation of airborne VOCs was estimated to be about $1.1\times10^{-3}/$, which was much higher than a risk standard of $10^{-5}$. The risk of $4.4\times10^{-5}$. came from benzene, the only human carcinogen among VOCs, while that of $1.05\times10^{-3}$ from probable human carcinogens including 1,3-butadiene and 1,2-dichloroethane. About 70% and 20% of total VOC cancer risk was due to the inhalation of 1,3-butadiene and 1,2-dichloroethane, respectively. Therefore, proper risk management of these 3 VOCs was required for the protection of health from cancer burden in Ulsan industrial complex area.

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