• Title/Summary/Keyword: VOC$_{2}$

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Degradation of VOC by Photocatalysts and Dark Discharge Hybrid Systems (광촉매와 암방전(dark discharge) 복합 시스템을 이용한 VOC의 분해)

  • Jung, Jihoon
    • Korean Chemical Engineering Research
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    • v.46 no.5
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    • pp.852-857
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    • 2008
  • The immobilization technique is important to extend the application field of a photocatalyst. Titanium surface was changed into a $TiO_2$ thin film by the anodizing process. The anodized $TiO_2$ had photocatalytic activity, and showed sponge like shape. The photocatalytic degradation of gas phase acetaldehyde and VOCs by anodized titania has been studied in various initial concentrations, humidity and discharge potentials. The reactivity of anodized titania was increased with relative humidity, but excessive humidity led to a decrease of the reaction rate. The electric dark discharge that was combined with photocatalytic reaction enhanced the decomposition rate of the organic compounds. But excessively applied voltage caused corona discharge, which decreased the reaction rate. Optimum relative humidity was 40% and discharge potential was 5 kV under dark discharge region in photocatalytic reaction.

Characterization of Air Quality in Various Types of Indoor Environments in Urban Areas - Focusing on Homes, Offices, and Restaurants - (도시지역 실내환경 유형별 공기질 특성 평가 -가정, 사무실 및 식당을 중심으로-)

  • 백성옥;김윤신
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.4
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    • pp.343-360
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    • 1998
  • In this study, comprehensive air quality monitoring was undertaken with a variety of objectives to collect data on the levels of various indoor and ambient air quality parameters in the urban areas of Seoul and Taegu. The sampling sites were comprised of six offices, six residences and six restaurants in each city. The ambient air adjacent to the indoor sites was also simultaneously sampled for the same constituents. The sampling was conducted in two phases: summer of 1994 and winter of 1994/95. A range of air quality parameters were measured simultaneously, which include RSP, CO, COB, NOB, a range of VOC, airborne microbials, temperature, and relative humidity. The indoor and ambient levels of the pollutants measured in this study varied widely between the three types of environments studied. Comparison of median values for the three groups revealed that restaurants had higher indoor levels of most pollutants than homes or offices. There was also a clear pattern of the indoor levels of target pollutants being higher than those outdoors, particularly in restaurants. Concentrations of CO and most of the VOC were found to be significantly higher in the commercial districts, indicating the influence of vehicle exhaust emissions. A very wide range of VOC levels was documented in this study. Although median indoorloutdoor ratios indicated a generally increasing level of VOC indoors when compared to those outdoors, no statistically significant differences were found between indoor and outdoor VOC levels in homes and offices, implying the importance of ambient air quality in determining the quality of indoor air for homes and offices in urban areas. In addition, there was a general pattern of increasing concentrations from summer to winter, and similarly from outdoor to indoor air for nearly all target compounds. The seasonal differences in median levels were very clearly seen for fuel combustion related pollutants such as RSP, CO and VOC, this being attributed to the effects of increased fuel consumption during the cold season and to meteorological factors.

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A Novel Parameter-independent Fictive-axis Approach for the Voltage Oriented Control of Single-phase Inverters

  • Ramirez, Fernando Arturo;Arjona, Marco A.;Hernandez, Concepcion
    • Journal of Power Electronics
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    • v.17 no.2
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    • pp.533-541
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    • 2017
  • This paper presents a novel Parameter-Independent Fictive-Axis (PIFA) approach for the Voltage-Oriented Control (VOC) algorithm used in grid-tied single-phase inverters. VOC is based on the transformation of the single-phase grid current into the synchronous reference frame. As a result, an orthogonal current signal is needed. Traditionally, this signal has been obtained from fixed time delays, digital filters or a Hilbert transformation. Nevertheless, these solutions present stability and transient drawbacks. Recently, the Fictive Axis Emulation (FAE) VOC has emerged as an alternative for the generation of the quadrature current signal. FAE requires detailed information of the grid current filter along with its transfer function for signal creation. When the transfer function is not accurate, the direct and quadrature current components present steady-state oscillations as the fictive two-phase system becomes unbalanced. Moreover, the digital implementation of the transfer function imposes an additional computing burden on the VOC. The PIFA VOC presented in this paper, takes advantage of the reference current to create the required orthogonal current, which effectively eliminates the need for the filter transfer function. Moreover, the fictive signal amplitude and phase do not change with a frequency drift, which results in an increased reliability. This yields a fast, linear and stable system that can be installed without fine tuning. To demonstrate the good performance of the PIFA VOC, simulation and experimental results are presented.

Estimation of Contribution by Pollutant Source of VOCs in Industrial Complexes of Gwangju Using Receptor Model (PMF) (수용모델(PMF)을 이용한 광주산업단지 VOCs의 오염원별 기여도 추정)

  • Park, Jin-Hwan;Park, Byoung-Hoon;Kim, Seung-Ho;Yang, Yoon-Cheol;Lee, Ki-Won;Bae, Seok-Jin;Song, Hyeong-Myeong
    • Journal of Environmental Science International
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    • v.30 no.3
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    • pp.219-234
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    • 2021
  • Industrial emissions, mainly from industrial complexes, are important sources of ambient Volatile Organic Compounds (VOCs). Identification of the significant VOC sources from industrial complexes has practical significance for emission reduction. VOC samples were collected from July 2019 to June 2020. A Positive Matrix Factorization (PMF) receptor model was used to evaluate the VOC sources in the area. Four sources were identified by PMF analysis, including coating-1, coating-2, printing, and vehicle exhaust. The coating-1 source was revealed to have the highest contribution (41.5%), followed by coating-2 (23.9%), printing (23.1%), and vehicle exhaust (11.6%). The source showing the highest contribution was coating emissions, originating from the northwest to southwest of the sample site. It also relates to facilities that produce auto parts. The major components of VOC emissions from the coating facilities were toluene, m,p-xylene, ethylbenzene, o-xylene, and butyl acetate. Industrial emissions should be the top priority to meet the relevant control criteria, followed by vehicular emissions. This study provides a strategy for VOC source apportionment from an industrial complex, which is helpful in the development of targeted control strategies.

A Study on the Characteristics of Natural VOC Emissions from Pine Trees in Season (계절별 소나무로부터 배출되는 자연 VOC(NVOC) 배출특성에 관한 연구)

  • 김조천;임준호;홍지형;전의찬;주명칠;조규탁
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.93-94
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    • 2003
  • 대기 중 휘발성유기화합물(Volatile Organic Compounds)은 인간에게 직접적으로 위해한 영향을 준다는 보건학적인 측면과 광화학스모그 생성에 관여한다는 이유 등으로 많은 주목을 받고있다. 식생은 자연 VOC(NVOC)의 가장 주요한 배출원이며, 대기중으로 유입되는 반응성이 강한 탄소의 주요한 배출원이며, 전 세계적으로는 NVOC의 배출량이 인위적인 것의 약 7배정도에 이를 것으로 추정되고 있다. 우리나라의 경우 전 국토의 2/3이상이 산림으로 이루어져 있어 NVOC가 인위적인 VOC의 양을 훨씬 초과할 것이라고 사료된다. (중략)

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Studies of $VOC_s$ Emission Rate Calculation in the Kwang-ju Area (광주지역의 $VOC_s$ 배출량산정에 관한 연구)

  • 이영재;신대윤
    • Journal of Environmental Health Sciences
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    • v.26 no.3
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    • pp.103-110
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    • 2000
  • This study was conducted from January to December in Kwang-ju city, 1999. Calculated methods were studied by emission factors in each industrial species. The results was that total emission rate of VOC was calculated at a mount of 12305 ton/year as coating(49.4) > vehicles(27.4) > gasoline vapors(6.1) > petroleum refineries(5.6) > graphic arts(4.4) > road covering(4.1) > dry cleang(3.0%) respectively. In vehicles emission rate, passenger car and taxi were about 2,700 ton/yr(60%) of total vehicle emission(3,300 ton/yr). The amount of building emission rate was about 1,900 ton/yr(30%) of total coating emission 6,083 ton/yr.

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Ozone Simulation and Sensitive Test under Varying Emission Condition (오존농도 시뮬레이션과 배출량 변화에 따른 민감도 분석)

  • Han, Jin-Seok;Kim, Byung-Gon;Kim, Shin-Do
    • Journal of Environmental Impact Assessment
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    • v.5 no.1
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    • pp.69-77
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    • 1996
  • The variations of ozone concentration and the sensitivity test for VOC emission intensities was investigated by means of a PBM(Photochemical Box Model). Compared to monitoring data, the typical variations of $NO_2$, CO, $O_3$ for days were successfully reproduced. Model results revealed that maximum ozone concentration got increased with the increase of VOC emission, that is, VOC played the important role in producing the photochemical smog.

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Measurements of VOC and Fine Particles at KIST in Seoul in June 2001 - I. Analysis of the Results from VOC Measurements (2001년 6월 서울 KIST에서의 VOC 및 미세입자 측정 - I. VOC 측정 결과 분석)

  • 김영주;김영성;김진영;윤용석;이시혜
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.161-162
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    • 2001
  • 최근 1, 2년 사이 기체와 입자 등 서로 다른 매체의 대기 중 성분 변화를 하나의 틀 속에서 해석하고자 하는 노력이 가속화되고 있다(예를 들면, NARSTO Synthesis Team, 2000). 이와 같은 시도는 물론 이들 변화가 서로 연결되어 있으므로 대기 중 변화를 보다 완전히 이해할 수 있고 그만큼 이들에 대한 대책도 효과적일 수 있기 때문이다. 그러나 다른 한편으로 기체 혹은 입자 등 개별 매체에 대한 분석을 보완하기 위하여 이와 같은 시도가 이루어질 수 있다. (중략)

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On-line GC Analysis of Odorous VOC and S Gas Pollutant Levels in Ambient Air of a Residential Area at Ansan City, Korea (안산시 주거지역을 중심으로 한 환경대기 중 휘발성 유기화합물과 황계열 성분의 온라인 연속측정 연구)

  • Kim K.-H;Ju DW;Choi YJ;Hong YJ;Sa JH;Park JH;Jeon EC;Choi CR;Koo YS
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.1
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    • pp.107-118
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    • 2005
  • In this study, the concentrations of major odorous compounds including reduced sulfur compounds (OMS, CS$_2$, and DMDS) and aromatic VOC (benzene, toluene, xylene, etc.) were measured continuously using an on-line GC analytical system. Our measurements were made from a residential area of Ansan sity during about two week period of October, 2004. The highest mean concentrations of Sand VOC were found as 56.9 pbb of DMS and 21.7 ppb of toluene, respectively. The results of this study generally show that the pollution levels for both types of chemicals are significant relative to previous measurement results reported from comparable sites, if the results are compared simply in terms of the magnitude of the measured concentration data. Moreover, when the relative importance of different compounds is compared in terms of the odor strength, it indicated that the contribution of reduced S compounds may be much more important than that of VOC in the study area.

The Comparison of VOC Characteristics Emitted from Wood-based Panels Using GC/FID and GC/MS (GC/FID와 GC/MS 분석법에 의한 목질제품에서의 VOC 방출특성 비교)

  • Hwang, Yoon-Seo;Park, Hyun-Ju;Son, Youn-Suk;Kim, Jo-Chun
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.4
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    • pp.436-442
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    • 2011
  • In this study, the Total Volatile Organic Compounds (TVOC) emitted from wood-based panels were compared by two analytical methods using the GC/FID and the GC/MS. Japanese Larch, Yellow Poplar, Particle Board (PB) and Medium Density Fiberboard (MDF) were selected as target materials. Major compounds emitted from the panels were Toluene, ${\alpha}$-pinene, ${\beta}$-pinene and limonene. In case of TVOC using GC/FID method, MDF E2 (1,497 ${\mu}g/m^3$) revealed the highest concentration among all wood-based panels, while Japanese Larch (1,772 ${\mu}g/m^3$) showed the highest value with respect to GC/MS method. Furthermore, it was found that the amount of VOC emitted from panels was different depending upon analytical methods. This significant difference was attributed to analytical sensitivities of GC/FID and GC/MS for various VOC. Besides, it was found that the composition ratios of main VOC compounds were not significantly different.