• 대한기계학회논문집B
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• 제35권6호
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• pp.625-632
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• 2011

[ $CH_4$ ]고온공기 대향류 확산화염의 점화특성을 화염제어 연속계산법을 이용하여 수치해석적으로 검토하였다. 화학반응의 계산에는 GRI-v1.2 반응기구를 이용하였으며, 화염 최고온도를 총괄 스트레인율의 역수에 대해 나타내어 점화 및 소화특성에 관한 화염 최고온도의 S-곡선을 얻을 수 있었다. 총괄 스트레인율 변화에 따른 화염구조를 고찰하기 위해 S-곡선에서 Upper Branch와 Middle Branch의 화염 온도 분포와 속도구배를 비교하였다. 총괄 스트레인율값은 화염면과 혼합층의 연료과 공기측 경계에서 정의되는 국소 스트레인율값과도 비교하였다. 연료측과 공기측의 국소 스트레인율은 총괄 스트레인율과의 좋은 상관관계에 있음을 알 수 있었다. 화염제어 연속계산법이 확산화염의 점화, 소화특성을 검토하는 데 매우 유용한 방법임을 확인하였다.

• Macromolecular Research
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• 제16권7호
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• pp.620-625
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• 2008

A novel nitrogen-phosphorus compound, diphenyl piperazine-1,4-diylbis(methylphosphinate)(DPPMP) was synthesized via a two step reaction and its flame retarding efficiency as a single component additive was investigated. The success of synthesis was confirmed by FTIR and $^1H$ and $^{31}P$ NMR analysis. The product was mixed with polycarbonate (PC), poly(butylene terephtalate) (PBT), ethylene-vinyl-acetate copolymer (EVA), and acrylonitrile-butadiene-styrene copolymer (ABS). The flame-retarding efficiency was evaluated using the limiting oxygen index (LOI) and the UL-94 vertical test methods. The addition of DPPMP enhanced the flame retardancy of the polymers and the V-0 ratings were obtained for the polymers examined in this study at a loading of 7-30 wt%. The gas-phase flame retardancy mode of action was suggested for this material from the thermogrametry experiment results.

• 한국산학기술학회논문지
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• 제7권4호
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• pp.743-748
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• 2006

본 논문에서는 연구에서는 Nylon6를 기재로 하여 두 가지 Melamine계 난연제(melamine cyanurate: MC-100 and melamine phosphate:MPP-100)를 사용한 난연 Nylon를 개발하여 난연성 및 물성평가를 수행하였다. 난연Test는 UL-94 측정방법(수직연소 시험방법)을 이용하였고, 물성평가는 만능물성시험기(UTM)를 이용하여 인장강도, 굴곡강도, 굴곡탄성율 등을 측정하였고, 충격강도 시험기를 이용하여 충격강도를 측정하였다. 또한 Nano-clay(Cloisite 30B) 5wt%를 사용하여 물성에 미치는 효과를 관찰하였다. 수지의 난연성 평가결과에 의하면, 난연제의 함량이 5wt% 이상이면 V0급을 얻을 수 있었다. 난연제 함량이 증가함에 따라 인장강도. 굴곡강도는 감소하고, 굴곡탄성율은 증가하였다. MC-100의 경우, 5wt%까지는 Nylon6의 동등 이상의 물성을 유지하였다. Nano-clay의 경우, 분산 상태가 불량하여 기대 수준의 물성 향상과 난연 효과는 얻지 못했다.

• 대한기계학회논문집B
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• 제34권7호
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• pp.729-738
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• 2010

질소로 희석된 부탄 층류 부상 화염에서 발생할 수 있는 화염진동 메커니즘을 살펴보기 위하여 실험적 연구를 수행하였다. 화염 진동은 층류 자유제트 부상 화염에서 5가지 영역으로 구분되었다: 화염 안정화 영역 (I), 열손실에 의한 진동 (II), 열손실에 의한 진동과 부력에 의한 진동이 혼재된 영역 (III),열손실에 의한 진동과 화염날림 직전의 진동이 혼재된 영역 (IV), 그리고 열손실에 의한 진동, 부력에 의한 진동 및 화염날림 직전의 진동이 모두 혼재된 영역(V). 각각의 화염진동의 특성을 규명하기 위해 화염의 시간에 따른 부상 높이 변화에 대한 FFT분석을 수행하였고 각 영역에 관련된 무차원 변수와 스트라훌 수의 조합으로 특성화 작업을 수행하였다.

• 한국자동차공학회논문집
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• 제5권2호
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• pp.60-68
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• 1997

Rayleigh Scattering Cross Sections($\sigma$i) of various gases and the temperature distributions of premixes C3H8/O2 flame are measured by high power KrF(248nm) Exci- mer laser and ICCD camera. Results show that $\sigma$i of O2 and Propane(C3H8) gases agree well in the 5% error range, but of H2 has the more or less difference from the calcul- ated value by other groups. This is attributed to the low RS signal of H2 to Nosie level(S/N ratio). The temperature distributions of flame range out between 300K in the air and about 2000K in the burned area. In this temperature range, out system has the about 250K temperature resolution. Because low RS signals in the reaction area with high temperature are affected highly by noises, temperature uncertainty of this area is relatively high to another part of flame. Experimental results show that UV Rayleigh Scattering can be used for the measurement of mixing ratio of mixed gases and the temperature distributions of flame. Especially, this technique can be applied for the measurement of the mixing ratio of air/fuel before the ignition and the flame structure after the ignition inside the Engine.

• 한국세라믹학회지
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• 제26권6호
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• pp.836-842
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• 1989

In this study, finely divided vanadium pentoxide was prepared by carrying vapor of vanadyl trichloride into the flame of an C3H8-O2-H2 with a specially designed burner. The flame-synthesized oxide particles had a nonporous spherical shape with nearly constant diameter in the range of 200-600$\AA$. The surface area of these particles depends on the residence time and the concentration of metal chloride vapor in the burner. The experimental results showed that the growth of particles is controlled by fusion rather than collision. The crystal size of finely divided V2O5 particle was increased after calcination at temperature above 50$0^{\circ}C$.

• 대한기계학회논문집B
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• 제20권12호
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• pp.4044-4052
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• 1996

Planar images of OH and $O_{2}$ with tunable KrF excimer laser which has a) 0.5 $cm^{-1}$ / linewidth, b) 0.5 nm tuning range, c) 150 mJ pulse energy, and d) 20 ns pulse width are obtained to determine spatial distributions of OH and $O_{2}$ in premixed $C_{3}$H$_{8}$ /O$_{2}$ flame. The technique is based on planar laser induced pre-dissociative fluorescence(PLIPF) in which collisional quenching is almost avoided because of the fast pre-dissociation. Dispersed LIPF spectra of OH and $O_{2}$ are also measured in a flame in order to confirm the excitation of single vibronic state of OH and $O_{2}$, OH and $O_{2}$ are excited on the P$_{2}$(8) line of the $A^{2}$.SIGMA.$^{+}$(v'= 3)-X$^{2}$.PI.(v'||'||'&'||'||'quot;= 0) band and R(17) line of the Schumann-Runge band B$^{3}$.SIGMA.$_{u}$ $^{[-10]}$ (v'= 0)- X$^{3}$.SIGMA.$_{g}$ $^{[-10]}$ (v'||'||'&'||'||'quot;= 6), respectively. Dispersed OH and $O_{2}$ spectra show an excellent agreement with simulated spectrum and previous works done by other group respectively. It is confirmed that OH widely distributed around flame front area than $O_{2}$.

• 조명전기설비학회논문지
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• 제15권4호
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• pp.43-50
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• 2001

본 논문은 구대구전극 사이에 고체절연체와 화염을 배치하여 방전시 절연체표면에서 발생되는 연면방전광과 화염의 변화를 CCD(Charged Coupled Device) 카메라로 관측하였으며, 방전시 발생되는 방사전자파는 스펙트럼 분석기와 바이코니칼 안테나를 이용하여 측정하였다. 인가전압 증가에 따른 고체절연체 표면에서 발생되는 연면 방전광은 커졌으며, 화염의 크기는 작아지는 것을 확인하였다. 또한 절연체표면 오염시와 화염시에는 전압강하에 의한 전압왜곡현상이 나타났다. 방사전자파의 전계세기는 절연체표면 무오염시에는 오염시보다 10∼17(dBuV/m), 절연체표면 오염시와 화염시에는 5∼9[dBuV/m]정도 높게 나타났다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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• pp.325-328
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• 2012

Radiation effects on the partially premixed methane flames diluted with water vapor in the air stream were numerically investigated. OPPDIF code and GRI-v3.0 were used in the numerical simulation. Adiabatic condition was compared with two different radiation models, optically-thin and WSGGM models. It was found that the radiation effect on the flame structure for the equivalence ratio (${\Phi}$) of 2.5 was less than ${\Phi}=1.5$. Extinction limit was not affected significantly, however, local flame structure was markedly influenced by the radiation models as increasing the water vapor concentration.

• Macromolecular Research
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• 제13권2호
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• pp.128-134
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• 2005

The phosphorus comonomer [(6-oxido-6H-dibenz<1,2>oxaphosphorin-6-yl)methyl]-methyl butane-dioate (DOP-MBDA) was synthesized through the addition reaction of dimethyl itaconate (DMI) with 9,10-dihydro­9-oxa-10-phosphaphenan threne-10-oxide (DOP). A series of novel flame retardant poly(butylene terephthalate)s (PBTs) containing different amounts of phosphorus were prepared using DOP-MBDA as a comonomer. These novel polymers were characterized by $^{1}H-NMR$, IR, and differential scanning calorimetry (DSC). The novel phosphorus­containing poly(butylene terephthalate)s, referred to as FR-PBTs, exhibited interesting thermal and mechanical behavior, as well as superior flame retardancy. These properties are attributed to the effect of incorporating the rigid structure of DOP-MBDA and the pendant phosphorus group into the poly(butylene terephthalate) (PBT) homopolymer. The UL 94-V2 rating could be achieved with this novel flame retardant PBT, which has a phosphorus content as low as $0.5 wt\%$, and the FR-PBTs emitted less fumes and toxic gases than the PBT homopolymer.