• Macromolecular Research
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• v.11 no.6
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• pp.444-450
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• 2003

Hydrophobically End-capped polyethylene oxide Urethane Resin(HEUR)-associating polymers, HEUR 35(8), HEUR 35(12), and HEUR 35(18), comprise a polyethylene oxide (PEO) having a molecular weight of 35,000 that is end capped with two C$\_$8/H$\_$17/, C$\_$12/H$\_$25/, and C$\_$18/H$\_$37/ alkyl chains, respectively. These associating polymers were synthesized by condensation reactions with polyethylene oxides and alkyl isocyanates. The self-diffusion coefficients of HEUR-associating polymers were measured in aqueous solution by pulsed-gradient spin-echo (PGSE) nuclear magnetic resonance (NMR) spectroscopy. All polymers underwent a decrease in their mean diffusion coefficients as the concentration was increased. However, the dispersion of the diffusion coefficients, ${\beta}$, about the mean fluctuated with changes in concentration. The large dispersion at low concentrations of HEUR 35(8) and HEUR 35(12) is related to the interaction between hydrophobic end groups, and the large dispersion at high concentrations of HEUR 35(18) is correlated with transient network formation. These results are valuable for predicting the associating mechanism of the large aggregates before and after their critical micelle concentration.

• Polymer(Korea)
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• v.35 no.4
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• pp.320-324
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• 2011

Two functional urethane acrylates were synthesized by using polycarprolactonediol (PCLD) and diisocyanate. The synthesized fuctional urethane acrylate was mixed with butyl acrylate(BA) or adhesion promoters, and their properties were investigated. To synthesize an excellent transparent urethane acrylate, isophorone diisocyanate(IPDI) was used. In addition, the effect of adding butyl acrylate for the improvement of shrinkage of urethane acrylate was studied. The results showed that the addition of butyl acrylate improved the shrinkage, and the optimum butyl acrylate content was 15 wt%. Both 2-ethyl hexyl acrylate (2-EHA) and ethyl acrylate(EA) were polymerized at $85^{\circ}C$ for 4 hrs to use as adhesion promoters, and the polymerized adhesion promoters were mixed to the UV-curing resin. The results showed that the adhesion properties increased with the increase of adhesion promoters content up to 15 wt%.

• Journal of the Korean Wood Science and Technology
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• v.27 no.1
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• pp.30-36
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• 1999

This paper describes the relationship between the bending strength properties of sloped finger-jointed woods and the acoustic emissions (AEs) generated during the test. Pinus densiflora pieces were cut in sloped-finger types and glued with four kinds of adhesives (polyvinyl acetate, polyvinyl-aeryl, oilic urethane and resorcinol-phenol resin). The results were as follows: The lower the bending strength(load) was, the earlier the generation time of AE event count got and the higher the increasing rate of AE event count became in the sloped finger-jointed specimens bonded with polyvinyl acetate and oilic urethane resin adhesives. Therefore, the slope from load-AE cumulative event count curve was very steep. The AE event count for resorcinol-phenol resin adhesive obtained even from low load level was abundant. The AE event count continuously increased as load increased and the event count was much more than one in the other conditions. The slope from load-AE cumulative event count curve was very gentle compared with other conditions. The patterns of AE event count and count were very similar. The relationship between the MOR and the AE parameter from load and AE cumulative event count in the early stage of the sloped finger-jointed specimens bonded with polyvinyl acetate, oilic urethane and resorcinol-phenol resin adhesives was much greater than that between the MOE and the MOR. Therefore, the AE signals obtained during bending test are useful for estimating the strength of sloped finger-jointed specimens.

• Journal of the Korean Wood Science and Technology
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• v.25 no.4
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• pp.61-67
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• 1997

The bending performances of sloped finger-joints in Pinus densiflora S. et Z. were tested in order to improve the strength properties of finger-joint Sloped finger-cut pieces were jointed with four kinds of adhesives(resorcinol-phenol, oilic urethane, polyvinyl acetate, and polyvinyl-acryl acetate resin). The slope ratios of finger joints were 0, 0.5, 1.0, 2.0. The MOE, MOR and defletion to maximum load in bending of sloped finger-joints and solid wood specimen were measured. The results were: 1. The efficiencies of MOE to finger and sloped finger-joints were 82% or greater in every kind of adhesives except polyvinyl-acryl acetate resin adhesive and there were some effect of slope on the MOE in a sloped finger-joint for polyvinyl-acryl acetate and oilic urethane resin adhesives. 2. The effects of slope on the MOR to sloped finger-joints were showed in every kind of adhesive, because the efficiencies of MOR increased with increasing slope ratio in sloped finger-joints. The efficiencies of MOR to slope ratios of 0 and 2.0 ranged 43~65% and 76~82%, respectively. There was almost no effect of the kinds of adhesives on the MOR to the slope ratio of 2.0. 3. It was found impossible to estimate the bending strength of sloped finger-jointed Pinus densiflora S. et Z. by using MOE. The correlation coefficient(0.124) between MOE and MOR was very low and not significant at 5% level.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2006.05a
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• pp.31-35
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• 2006

Degradation characteristics of filament-winded composites due to accelerated environmental aging have been evaluated under high temperature, water immersion and thermal impact conditions. Two kinds of laminated composites coated by an urethane resin have been used: carbon-fiber reinforced epoxy(T700/Epon-826, CFRP) and glass-fiber reinforced phenolic (E-glass/phenolic, GFRP). For tensile strength of $0^{\circ}$ composites, CFRP did high reduction by 25% under the influence of high temperature and water while CFRP showed little degradation. However for water-immersed $90^{\circ}$ composites both CFRP and GFRP showed high reduction in tensile strength. Bending strength and modulus of $90^{\circ}$ composites were largely reduced in water-immersion as well as high temperature environment. Urethane coating on the composite surface improved the bending properties by 20%, however hardly showed such improvement for water-immersed $90^{\circ}$ composites.

• International Journal of Concrete Structures and Materials
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• v.2 no.2
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• pp.83-90
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• 2008

Permeability to vapor and water among other performances required for finishing materials is dealt with in this study. The relative moisture content of concrete coated/covered with a finishing material was experimentally investigated while changing the environmental conditions including temperature, relative humidity, and rainfall. An organic paint (water-based urethane), organic synthetic resin emulsion-type film coating (film coating E), and inorganic porcelain tiles were selected as the finishing materials. When compared from the aspect of vapor and water permeability, the vapor permeability and water permeability of water-based urethane were high and low, respectively; those of film coating E were high and high, respectively; and those of porcelain tiles were low and low, respectively. This means that the moisture state of concrete structures is governed not only by the environmental conditions but also by the performance of finishing materials. It is therefore of paramount importance to appropriately select a finishing material to address the specific deteriorative factors involved in the concrete structure to be finished.

• Journal of the Korean Applied Science and Technology
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• v.33 no.1
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• pp.92-99
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• 2016

Polyurethane resin used to leather coat was synthesized by the addition reaction of PPG and PTMG with different mole ratios. Physical characteristics of the synthesized polyurethane resin were measured by the SEM, FT-IR and the UTM. Increasing mole ratio of PTMG having four methylene groups caused the increase of abrasion resistance and tensile strength. The elongation was decreased. As we measured the solvent(toluene) resistance of poly urethane resin, it was found the there were no effect of PTMG mole ratios on the phyhsical properties of the resin. The viscosity was increased by ratio of PTMG mole ratio.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.9
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• pp.2396-2401
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• 2009

This study is on development of UV-cured hard coating compounds which have more improved abrasion resistance than existing UV-cured urethane-acrylic resin, to prevent a surface of a widely used PVC tile as a constructive material from being scratched. To make a high abrasion resistant hard coating solution compared to UV-cured urethane-acrylic resin which has no abrasion resistance and been used for PVC tiles, we added powder substances of different abrasion resistant level, $Al_2O_3$(Al-160SG-3), $Al(OH)_3$(SH-8W), $SiO_2$(KS-5000), etc., to the resin, changing their contents from 10% to 30% against quantities of resin, and compounded it using Ring-Mill. After coating PVC tiles with the hard coating solution using bar-coating method that can adjust a thickness, we estimated some surface properties-abrasion resistance, pencil hardness, adhesive power, thickness of coating, and so on. As a result, a hard coating solution added 30% $Al_2O_3$ powder to the resin had the finest surface properties-the first grade in abrasion resistance, H in pencil hardness, 100% in adhesive power, and a hard coating solution which showed excellent solidity and abrasion resistance has smaller particle size, higher powder content, and thicker coating thickness.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2018.11a
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• pp.193-194
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• 2018

In this study, various materials such as epoxy material, urethane material, cement material, and acrylic material are used to solve the water leakage occurring in underground structures. However, in the reality that the durability is insufficient and the effect is insufficient, it is aimed to improve the repairing effect by using acrylics. As a second study, it is confirmed that leachate can be used as a repair material by considering long time under water stability, elongation range test, fatigue resistance test, tube stability test, damage recovery performance ana temperature stability considering leakage environment for polyacrylate. In addition, this material is applied to Expansion Joint to perform leakage repair, and to verify the effect of repairing leakage by monitoring and visual observation of concrete humidification.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2013.11a
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• pp.168-169
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• 2013

In this study, the chemical resistance of polyurea resin waterproofing and anti-corrosion materials that is applied to the social infrastructure was analyzed. The result in this study will be utilizing as a basic data for establishing the quality standards which are able to judge the chemically resistant characteristic of polyurea resin waterproofing and anti-corrosion materials.