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Fabrication and Electrical Properties of PZT/BFO Multilayer Thin Films

  • Jo, Seo-Hyeon;Nam, Sung-Pil;Lee, Sung-Gap;Lee, Seung-Hwan;Lee, Young-Hie;Kim, Young-Gon
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.5
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    • pp.193-196
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    • 2011
  • Lead zirconate titanate (PZT)/ bismuth ferrite (BFO) multilayer thin films have been fabricated by the spin-coating method on Pt(200 nm)/Ti(10 nm)/$SiO_2$(100 nm)/p-Si(100) substrates using $BiFeO_3$ and $Pb(Zr_{0.52}Ti_{0.48})O_3$ metal alkoxide solutions. The PZT/BFO multilayer thin films show a uniform and void-free grain structure, and the grain size is smaller than that of PZT single films. The reason for this is assumed to be that the lower BFO layers play an important role as a nucleation site or seed layer for the formation of homogeneous and uniform upper PZT layers. The dielectric constant and dielectric losses decreased with increasing number of coatings, and the six-layer PZT/BFO thin film has good properties of 162 (dielectric constant) and 0.017 (dielectric losses) at 1 kHz. The remnant polarization and coercive field of three-layer PZT/BFO thin films were 13.86 ${\mu}C/cm^2$ and 37 kV/cm respectively.

Experimental studies of validation and stability of Sweet Bee Venom using HPLC (Sweet BV의 조제물 농도분석 및 안정성 확인을 위한 시험적 연구)

  • Kang, Kye-Sung;Kwon, Ki-Rok
    • Journal of Pharmacopuncture
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    • v.12 no.4
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    • pp.33-50
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    • 2009
  • Objectives : This study was conducted to confirm validation and stability of concentration analysis method of pure melittin (Sweet Bee Venom-Sweet BV) extracted from the bee venom by utilizing protein isolation method of gel filtration. Methods : All experiments were conducted at Biotoxtech, a non-clinical studies authorized institution, under the regulations of Good Laboratory Practice (GLP). Standard solutions of melittin (SIGMA, USA) and test substances were dispensed and were analyzed with HPLC for Sweet BV to secure the validation of analysis. Results : 1. Measurement of system suitability of Sweet BV satisfied criterion of below 3%. 2. Confirming Linearity of Sweet BV in 10-200${\mu}g/m\ell$ solution yielded correlation coefficient (r) of 0.995 and accuracy of 85-115% which satisfy criterion. 3. Measurement of Specificity of Sweet BV didn't yield any substance affecting the peak of test substances, but detected at 21.22min verified as the test substance. 4. Confirming Intra-day of Sweet BV, accuracy and precision of 0.1, 100${\mu}g/m\ell$ were 105.70, 95.81 and 0.66, 0.73, respectively, satisfying both criteria of accuracy (85-115%) and precision (within 10%). 5. To measure Stability in autosampler, all samples used in Intra-day reproducibility sat in the autosampler for five hours and were re-analyzed. Both variability and precision satisfied the criteria. 6. Homogeneity of Sweet BV (0.1, 100${\mu}g/m\ell$) at upper, middle, and lower layers all satisfied the accuracy and precision criteria. 7. Stability of Sweet BV (0.1, 100${\mu}g/m\ell$) at room temperature for four hours and refrigerated for 7 days all satisfied the criterion. 8. For the measurement of Quality control, QC samples measured on the first and eighth day all satisfied accuracy and precision criteria. Conclusion : Above experiment data satisfies validation and stability of concentration analysis method of Sweet BV.

Joint Subcarriers and Power Allocation with Imperfect Spectrum Sensing for Cognitive D2D Wireless Multicast

  • Chen, Yueyun;Xu, Xiangyun;Lei, Qun
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.7 no.7
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    • pp.1533-1546
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    • 2013
  • Wireless multicast is considered as an effective transmission mode for the future mobile social contact services supported by Long Time Evolution (LTE). Though wireless multicast has an excellent resource efficiency, its performance suffers deterioration from the channel condition and wireless resource availability. Cognitive Radio (CR) and Device to Device (D2D) are two solutions to provide potential resource. However, resource allocation for cognitive wireless multicast based on D2D is still a great challenge for LTE social networks. In this paper, a joint sub-carriers and power allocation model based on D2D for general cognitive radio multicast (CR-D2D-MC) is proposed for Orthogonal Frequency-Division Multiplexing (OFDM) LTE systems. By opportunistically accessing the licensed spectrum, the maximized capacity for multiple cognitive multicast groups is achieved with the condition of the general scenario of imperfect spectrum sensing, the constrains of interference to primary users (PUs) and an upper-bound power of secondary users (SUs) acting as multicast source nodes. Furthermore, the fairness for multicast groups or unicast terminals is guaranteed by setting a lower-bound number of the subcarriers allocated to cognitive multicast groups. Lagrange duality algorithm is adopted to obtain the optimal solution to the proposed CR-D2D-MC model. The simulation results show that the proposed algorithm improves the performance of cognitive multicast groups and achieves a good balance between capacity and fairness.

Optimal Design Of Multisite Batch-Storage Network under Scenario Based Demand Uncertainty (다수의 공장을 포함하는 불확실한 수요예측하의 회분식 공정-저장조 망의 최적설계)

  • 이경범;이의수;이인범
    • Journal of Institute of Control, Robotics and Systems
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    • v.10 no.6
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    • pp.537-544
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    • 2004
  • An effective methodology is reported for determining the optimal lot size of batch processing and storage networks which include uncertain demand forecasting. We assume that any given storage unit can store one material type which can be purchased from suppliers, internally produced, infernally consumed, transported to or from other sites and/or sold to customers. We further assume that a storage unit is connected to all processing and transportation stages that consume/produce or move the material to which that storage unit is dedicated. Each processing stage transforms a set of feedstock materials or intermediates into a set of products with constant conversion factors. A batch transportation process can transfer one material or multiple materials at once between sites. The objective for optimization is to minimize the probability averaged total cost composed of raw material procurement, processing setup, transportation setup and inventory holding costs as well as the capital costs of processing stages and storage units. A novel production and inventory analysis formulation, the PSW(Periodic Square Wave) model, provides useful expressions for the upper/lower bounds and average level of the storage inventory. The expressions for the Kuhn-Tucker conditions of the optimization problem can be reduced to two sub-problems. The first yields analytical solutions for determining lot sires while the second is a separable concave minimization network flow subproblem whose solution yields the average material flow rates through the networks for the given demand forecast scenario. The result of this study will contribute to the optimal design and operation of the global supply chain.

Wave Propagation Characteristics in Saturated Porous Media II. Parametric Studies (포화된 다공성매체에서 파동의 전파특성 II. 파라미터 연구)

  • Kim, Sun-Hoon;Kim, Kwang-Jin
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.20 no.2
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    • pp.191-206
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    • 2007
  • The general theoretical solutions for the wavespeed and damping derived in Part 1 of this work, are incorporated into the computer code. In this paper the code is used in a parametric study of the influence of excitation frequency and variations in material properties on propagation velocity and damping. Compressional wave velocity for waves of the first kind is shown to vary as a function of the frequency-permeability product, with a zone where wavespeed transitions from a lower bound value to a higher bound value with increasing values of the product. Damping is seen to be a maximum where the rate of change in wavespeed is greatest. Waves of the second kind also show a transition in wavespeed from near zero at low values of the frequency-permeability product to an upper bound value at higher values of the product.

A refined four variable plate theory for thermoelastic analysis of FGM plates resting on variable elastic foundations

  • Attia, Amina;Bousahla, Abdelmoumen Anis;Tounsi, Abdelouahed;Mahmoud, S.R.;Alwabli, Afaf S.
    • Structural Engineering and Mechanics
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    • v.65 no.4
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    • pp.453-464
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    • 2018
  • In this paper, an efficient higher-order shear deformation theory is presented to analyze thermomechanical bending of temperature-dependent functionally graded (FG) plates resting on an elastic foundation. Further simplifying supposition are made to the conventional HSDT so that the number of unknowns is reduced, significantly facilitating engineering analysis. These theory account for hyperbolic distributions of the transverse shear strains and satisfy the zero traction boundary conditions on the surfaces of the plate without using shear correction factors. Power law material properties and linear steady-state thermal loads are assumed to be graded along the thickness. Nonlinear thermal conditions are imposed at the upper and lower surface for simply supported FG plates. Equations of motion are derived from the principle of virtual displacements. Analytical solutions for the thermomechanical bending analysis are obtained based on Fourier series that satisfy the boundary conditions (Navier's method). Non-dimensional results are compared for temperature-dependent FG plates and validated with those of other shear deformation theories. Numerical investigation is conducted to show the effect of material composition, plate geometry, and temperature field on the thermomechanical bending characteristics. It can be concluded that the present theory is not only accurate but also simple in predicting the thermomechanical bending responses of temperature-dependent FG plates.

Investigation of influence of homogenization models on stability and dynamic of FGM plates on elastic foundations

  • Mehala, Tewfik;Belabed, Zakaria;Tounsi, Abdelouahed;Beg, O. Anwar
    • Geomechanics and Engineering
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    • v.16 no.3
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    • pp.257-271
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    • 2018
  • In this paper, the effect of the homogenization models on buckling and free vibration is presented for simply supported functionally graded plates (FGM) resting on elastic foundation. The majority of investigations developed in the last decade, explored the Voigt homogenization model to predict the effective proprieties of functionally graded materials at the macroscopic-scale for FGM mechanical behavior. For this reason, various models have been used to derive the effective proprieties of FGMs and simulate thereby their effects on the buckling and free vibration of FGM plates based on comparative studies that may differ in terms of several parameters. The refined plate theory, as used in this paper, is based on dividing the transverse displacement into both bending and shear components. This leads to a reduction in the number of unknowns and governing equations. Furthermore the present formulation utilizes a sinusoidal variation of displacement field across the thickness, and satisfies the stress-free boundary conditions on the upper and lower surfaces of the plate without requiring any shear correction factor. Equations of motion are derived from Hamilton's principle. Analytical solutions for the buckling and free vibration analysis are obtained for simply supported plates. The obtained results are compared with those predicted by other plate theories. This study shows the sensitivity of the obtained results to different homogenization models and that the results generated may vary considerably from one theory to another. Comprehensive visualization of results is provided. The analysis is relevant to aerospace, nuclear, civil and other structures.

Microstructure and Tensile Strength Property of Arc Brazed DP steel using Cu-Sn Insert Metal (Cu-Sn 삽입금속을 이용한 DP강의 아크 브레이징 접합부의 미세조직과 인장특성)

  • Cho, Wook-Je;Cho, Young-Ho;Yun, Jung-Gil;Kang, Chung-Yun
    • Journal of Welding and Joining
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    • v.31 no.1
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    • pp.58-64
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    • 2013
  • The following results were obtained, microstructures and tensile properties in arc brazed joints of DP(dual phase) steel using Cu-5.3wt%Sn insert metal was investigated as function of brazing current. 1) The Fusion Zone was composed of ${\alpha}Fe+{\gamma}Cu$ and Cu23Sn2. The reason for the formation of these solid solutions. Despite, Fe & Cu were impossible to solid solution at room temperature. It's melting & reaction to something of insert metal & Base Metal (DP Steel) by Arc. Brazing Process has faster cooling rate then Cast Process, Supersaturated solid solution at room temperature. 2) The increase Hardness of Fusion Zone was directly proportional to the rise of welding current. Because, ${\alpha}Fe+{\gamma}Cu$ phase (higher hardness than the Cu23Sn2.(104.1Hv < 271.9Hv)) Volume fraction was Growth, due to increasing the amount of base metal melting by High current. 3) The results of tensile shear test by Brazing, All specimens happen to fracture in Fusion Zone. On the other hand, when Brazing Current increasing tend to rise tensile load. but it was very small, about 26-30% of the base metal. 4) The result of fracture analysis, The crack initiate at Triple Point for meet to Upper B.M/Under B.M/Fusion Zone. This Crack propagated to Fusion zone. So ruptured by tensile strength. The Reason to in the fusion zone fracture, Fusion zone by Brazing of hardness (strength) was very lower then the base metal (DP steel). In addition the Fusion Zone's thickness in triple point was thin than the base metal's thickness in triple point.

Mucoadhesion, Swelling and Drug Release Characteristics of Hydroxypropylcellulose/Carbopol Solid Dispersions (히드록시프로필셀룰로오스/카르보폴 고체분산체의 점막부착성과 팽윤 및 약물방출특성)

  • Kim, Sang-Heon;Yang, Su-Geun;Shin, Dong-Sun;Lee, Min-Suk;Choi, Young-Wook
    • Journal of Pharmaceutical Investigation
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    • v.24 no.3
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    • pp.155-165
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    • 1994
  • Some mucoadhesive polymers such as hydroxypropylcelluose (HPC) and carbopol-934 (CP) have been employed for the preparation of mucoadhesive polymeric systems, and their physical properties including mucoadhesion, swelling, and drug release were evaluated. A new simple experimental technique that can quantitatively measure the bioadhesive properties of various polymeric systems has been developed by the methods of detachment force test. As the polymeric systems, the discs of freeze-dried HPC/CP solid dispersions were prepared. The mucosa used in these tests were upper, middle, and lower parts of small intestine of male rats weighing $300{\sim}350\;g$. Detachment forces were increased as the mole fraction of CP increased in discs of HPC/CP solid dispersions. In the points of intestinal site dependence of mucoadhesion, the solid dispersions revealed non-specific mucoadhesion to the intestine. Swelling and drug release characteristics of mucoadhesive polymeric systems were studied extensively to find out the feasibility for the oral controlled delivery systems. Swelling ratio, expressed as the final height/initial height, has been determined in various pH buffer solutions. Hydrochlorothiazide (HCT) was employed as a model drug for release study. Apparent swelling and drug release rate constants, $K_s$ and $K_r$ respectively, were obtained from the square-root time plot of either swelling ratio or released amount of drug, particularly for the time periods before reaching the equilibrium. As a result, the swelling ratio of HPC/CP solid dispersions was increased as the weight percentage of CP increased. Similarly, the release of HCT from the solid dispersions was dependent on pH changes and CP contents, resulted in the slower release of HCT with the increases of pH and CP contents.

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Simulated Annealing for Two-Agent Scheduling Problem with Exponential Job-Dependent Position-Based Learning Effects (작업별 위치기반 지수학습 효과를 갖는 2-에이전트 스케줄링 문제를 위한 시뮬레이티드 어닐링)

  • Choi, Jin Young
    • Journal of the Korea Society for Simulation
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    • v.24 no.4
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    • pp.77-88
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    • 2015
  • In this paper, we consider a two-agent single-machine scheduling problem with exponential job-dependent position-based learning effects. The objective is to minimize the total weighted completion time of one agent with the restriction that the makespan of the other agent cannot exceed an upper bound. First, we propose a branch-and-bound algorithm by developing some dominance /feasibility properties and a lower bound to find an optimal solution. Second, we design an efficient simulated annealing (SA) algorithm to search a near optimal solution by considering six different SAs to generate initial solutions. We show the performance superiority of the suggested SA using a numerical experiment. Specifically, we verify that there is no significant difference in the performance of %errors between different considered SAs using the paired t-test. Furthermore, we testify that random generation method is better than the others for agent A, whereas the initial solution method for agent B did not affect the performance of %errors.