• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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• pp.462-468
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• 2017

KYP 모델은 화약의 폭굉 반응속도를 기술하는 압력기반모델이다. 본 연구에서는 PETN 기반 복합 화약(PBXN-301)의 KYP 모델 및 JWL EOS의 파라미터를 결정하였다. 크기효과를 얻기 위하여 반응 막대 시험을 수행하였고 2차원 하이드로다이나믹 해석 결과와 비교하였다. 해석 결과, 정성적으로 얻어진 LLNL의 구성방정식보다 KYP 모델링을 통해 도출된 파라미터가 PBXN-301 화약의 역반지름에 따른 폭굉파속을 잘 예측하는 것으로 나타났다.

• International Journal of Aeronautical and Space Sciences
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• 제16권3호
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• pp.418-424
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• 2015

The chemical response of energetic materials is analyzed in terms of 1) the thermal decomposition under the thermal stimulus and 2) the reactive flow upon the mechanical impact, both of which give rise to an exothermic thermal runaway or an explosion. The present study aims at building a set of chemical kinetics that can precisely model both thermal and impact initiation of a heavily aluminized cyclotrimethylene-trinitramine (RDX) which contains 35% of aluminum. For a thermal decomposition model, the differential scanning calorimetry (DSC) measurement is used together with the Friedman isoconversional method for defining the frequency factor and activation energy in the form of Arrhenius rate law that are extracted from the evolution of product mass fraction. As for modelling the impact response, a series of unconfined rate stick data are used to construct the size effect curve which represents the relationship between detonation velocity and inverse radius of the sample. For validation of the modeled results, a cook-off test and a pressure chamber test are used to compare the predicted chemical response of the aluminized RDX that is either thermally or mechanically loaded.