• Title/Summary/Keyword: Unburned hydrocarbon

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Modeling of Piston Crevice Hydrocarbon Oxidation in SI Engines (전기점화 기관 간극 체적 내 미연탄화수소의 산화 모델링)

  • Choi, Hoi-Myung;Kim, Se-Jun;Min, Kyung-Doug
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.884-889
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    • 2001
  • Combustion chamber crevices in SI engines are identified as the largest contributor to the engine-out hydrocarbon emissions. The largest of crevice region is the piston ring pack crevice. To predict and understand the oxidation process of piston crevice hydrocarbons, a 3-dimensional numerical simulation method was developed. A engine shaped computational mesh with moving grid for piston and valve motions was constructed. And a 4-step oxidation model involving 7 species was used and the 16 coefficients in the rate expressions were optimized based on the results from a detailed chemical kinetic mechanism for the oxidation condition of engine combustion chamber. Propane was used as a fuel in order to eliminate oil layer absorption and liquid fuel effect.

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Estimation of Hydrocarbon Oxidation by Measuring He Concentrations in an SI Engine Exhaust Port (프로판 엔진의 배기 포트에서 탄화수소 산화율 추정)

  • Yi, Hyung-Seung;Park, Jong-Bum;Min, Kyoung-Doug;Kim, Eung-Seo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.5
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    • pp.660-667
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    • 2000
  • In order to investigate the exhaust structure and secondary oxidation of unburned hydrocarbon (HC) in the exhaust port, concentrations of individual HC species were measured in exhaust process, the degree of oxidation were obtained. Using a solenoid-driven fast sampling system on single-cylinder research engine fueled with 94% propane, the profiles of unburned hydrocarbons (HCs) and non-fuel HCs with a propane fueled engine were obtained from several locations in the exhaust port during the exhaust process. The sampled gases were analyzed using a gas chromatography of HC species with 4 or lesser carbon atoms. The change of total HC concentration and HC fractions of major components through the exhaust port were discussed. The results showed that non-uniform distribution of HC concentration existed around the exhaust valve and changed with time, and that the exhaust gas exhibited nearly uniform concentration profile at port exit, which was due to mixing and oxidation. Also it could be known that bulk gas with relatively high HC concentration came out through the bottom of the exhaust valve. To estimate the mass-based degree of HC oxidation in the exhaust port from measured HC concentrations, a 3-zone diagnostic cycle simulation and plug flow modeling were used. The degree of oxidation ranged between 26 % and 36 % corresponding to the engine operation conditions.

Determination of Air Fuel Ratio According to Fuel Composition (II) -Compensation of Unburned Gas Concentration in Eltinge Chart- (연료 조성에 따른 공연비 산정 (II) -Eltinge 차트에서 미연 성분의 보상-)

  • Ohm, In-Yong;Park, Chan-Jun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.11
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    • pp.1563-1571
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    • 2003
  • This paper is the second part of several companion papers which compare the method of Air-fuel ratio(AFR) determination. In the previous paper, Eltinge chart was applied to the arbitrary fuel composition and the charts for gasoline, diesel, methanol, M85, liquefied petroleum gas(LPG), natural gas(NG), propane and butane were illustrated. In Eltinge chart, however, unburned hydrocarbon (UHC) is not used for determination of AFR. For improving accuracy, Eltinge suggested UHC compensation after the AFR reading in the chart. This compensation reduced the difference between real and reading value. In the compensation, however, the correction of oxygen and carbon dioxide is uncertain and there might be a mistake in conversion of UHC reading value. Therefore, the error is overestimated comparing with Spindt one which is most widely used. In addition, there is no comparison of the value with other useful methods. In this paper, the compensation of unburned HC was performed in Eltinge chart and the compensated value was compared with Spindts formula over wide range of AFR. The objects of investigating fuel are gasoline, methanol, NG and LPG. The result shows that Eltinge and Spindt method is flawlessly compatible and the difference between the two methods is under 0.3% in a λrange from 0.9 to 1.7. The method fur debugging instrumentation error is also presented.

An Experimental Study on Hydrocarbon Emission Characteristics of Hydrogen Enriched LPG Fuel in a LPG Engine at Cold Start (LPG 기관의 수소 분사비율에 따른 냉간시동시 미연탄화수소 배출 특성에 관한 실험적 연구)

  • LEE, YEONGJAE;KIM, HYUNGKEUN;BANG, TAESEOK;LEE, JAEWOONG;CHO, YONGSEOK
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.4
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    • pp.363-368
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    • 2015
  • Finding an alternative fuel and reducing environmental pollution are the main goals for future internal combustion engines. The purpose of this study is to obtain low-emission and high-efficiency by hydrogen enriched LPG fuel in a LPG engine. An experimental study was carried out to obtain fundamental data for the emit HC emission characteristics at cold start of pre-mixed LPG and hydrogen in a LPG engine with various fractions of hydrogen-LPG blends. To maintain equal volume ratio of fuel blend, the amount of HC was decreased as hydrogen was gradually added. The results showed that as hydrogen increases, in-cylinder pressure increased. Also emission of unburned hydrocarbon (HC) is sharply decreased.

A Numerical Study on the Propane Combustion Characteristics in a Catalytic Combustor (프로판의 촉매연소 특성에 관한 수치적 연구)

  • Lee, Youn-Hwa;Kim, Chong-Min;Kim, Man-Young;Yu, Myoung-Jong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.247-250
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    • 2009
  • The catalytic combustor has the advantage of stable combustion under very lean conditions with low emissions of $NO_x$, CO and unburned hydrocarbon(UHC). Notwithstanding these advantages, the commercial application of the catalytic combustion has been delayed due to the complicated reaction process. For the stable operation of catalytic combustor, study on the combustion characteristics of the catalytic combustor is needed. So, in this study, numerical study on the propane combustion characteristics of the catalytic combustor with Pd-based catalyst is performed.

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The Comparison Study on Reburning Effects of LNG and Rice Husk in Heavy Oil Flamed Furnace (중유 화염 연소로에서 LNG와 왕겨분말의 재연소 효과 비교)

  • Shin, Myeung-Chul;Kim, Se-Won;Lee, Chang-Yeop
    • Journal of the Korean Society of Combustion
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    • v.14 no.4
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    • pp.25-32
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    • 2009
  • In commercial combustion systems, heavy oil is one of main hydrocarbon fuel because of its economical efficiency. Regarding heavy oil combustion, due to increasing concerns over environmental pollutants such as carbon monoxide, unburned hydrocarbon and nitrogen oxides, development of low pollutant emission methods has become an imminent issue for practical application to numerous combustion devices. Also a great amount of effort has been tried to developed effective methods for practical using of biomass. It is also an important issue to reduce carbon tax. In this paper, an experimental study has been conducted to evaluate the effect of biomass reburning on NOx formation in a heavy oil flamed combustion furnace. Experiments were performed in flames stabilized by a multi-staged burner, which was mounted at the front of the furnace. Experimental tests were conducted using air-carried rice husk powder and LNG as the reburn fuel and heavy oil as the main fuel. The paper reports data on flue gas emissions and temperature distribution in the furnace for several kinds of experimental conditions. NOx concentration in the exhaust has decreased considerably due to effect of reburning. The maximum NOx reduction rate was 62% when the rice husk was used by reburn fuel, however it was 59% when the LNG was used by reburn fuel. The result shows the positive possibility of biomass reburning system for optimal NOx reduction.

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Power and Emission Characteristics of DI Diesel Engine with a Soybean Bio-diesel Fuel (바이오디젤유를 사용한 직접분사식 디젤엔진의 출력성능 및 배출가스 특성)

  • Choi, B.C.;Lee, C.H.;Park, H.J.
    • Journal of Power System Engineering
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    • v.6 no.3
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    • pp.11-16
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    • 2002
  • This paper describes the power performance and emission characteristics of the high speed direct injection diesel engine (2.9 litter displacements) driven by soybean oil asknown a bio diesel fuel. The results were compared to diesel fuel with blending bio diesel fuels. The soybean bio diesel fuel was added in the diesel fuel in concentration varying from 25% to 75% volume rates. We measured the emissions according to ECE 13 mode and full load, fixedengine speed. When the 25% bio diesel fuel was used, NOx emission at the ECE 13 mode test slightly decreased compared with diesel base engine. Over engine speed of 2000 rpm, the level of unburned hydrocarbon(HC) and carbon monoxide(CO) were the same to the diesel engine. Smoke emission decreased asthe blending bio diesel fuel rate increased.

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An Experimental Study on the Effect of Mixture Distribution in the Constant Volume Combustion Chamber on the Combustion Characteristics (정적 연소실내 혼합기 분포가 연소특성에 미치는 영향에 관한 실험적 연구)

  • 이기형;이창희;안용흠
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.3
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    • pp.10-18
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    • 2004
  • It is well known that the stratified charge combustion has many kind of advantages to combustion characteristics, such as higher thermal efficiency and less CO, NOx levels than conventional homogeneous mixture combustion. Although this combustion can be caused low fuel consumption, it is produced the high unburned hydrocarbon and soot levels because of different equivalence ratio in the combustion chamber. Moreover it has a lot of possibility of low output and misfire if the mixture gas would not be in existence around the spark plug. In this paper, fundamental studies for stratified combustion were carried out using a constant volume combustion chamber. The effect of locally mixture gas distribution according to control the direct injection and premixed injection in the chamber were examined experimentally. In addition, the effects of turbulence on stratified charge combustion process were observed by schlieren photography.

Characteristics of HC Emissions by Starting Conditions in an SI Engine (가솔린 기관의 시동조건에 따른 HC의 배출특성)

  • 김성수
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.3
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    • pp.1-9
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    • 2004
  • During the SI engine starting up, starting conditions directly contribute to the unburned hydrocarbon emissions in spark ignition engines. The effects of catalyst temperatures and fuel injection skip methods on HC emissions were investigated. The test was conducted on a 1.5 L, 4-cylinder, 16 valve, multipoint-port-fuel-injection gasoline engine. To understand the formation of HC emissions, HC concentration was measured in an exhaust port using a Fast Response Flame ionization Detector (FRFID). The result showed that HC emissions, which were emitted at the cold coolant and catalyst temperature, were generated much higher than those of hot coolant and catalyst temperatures. In additions, fuel injection skips reduced highly HC emissions. It is convinced that optimized fuel injection skip method according to coolant and catalyst temperatures could be applied to reduce HC emissions during the SI engine starts.

A Numerical Study on Stratified Charge Formation and Combustion Processes (성층급기 연소현상에 관한 수치적 연구)

  • Lee, Suk-Young;Huh, Kang-Y.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.5
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    • pp.86-96
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    • 2007
  • A direct-injection stratified-charge(DISC) engine has been considered as a promising alternative in spite of high unburned hydrocarbon emission levels during light load operation. In this paper investigation is made to characterize formation and combustion processes of stratified mixture charge in a simple constant volume combustion chamber. Both experimental and numerical analyses are performed for fluid and combustion characteristics with 3 different induction types for rich, homogeneous and lean mixture conditions. The commercial code FIRE is applied to the turbulent combustion process in terms of measured and calculated pressure traces and calculated distributions of mean temperature, OH radical and reaction rate. It turns out that the highest combustion rate occurs for the rich state condition at the spark ignition location due to existence of stoichiometric mixture and timing.