• Title/Summary/Keyword: Ultraviolet-Light

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Photosensitive Polymers: Effects of Photoreactive Group and UV-Exposure on Alignment of Liquid-Crystals on the Film Surface

  • Ree, Moon-Hor;Kim, Sang-Il;Lee, Seung-Woo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.41-42
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    • 2000
  • Photosensitive polyimides containing cinnamoyl and coumarin side groups were synthesized in a high molecular weight, giving a good quality of films. Nematic liquid-crystal (LC) molecules on the film were aligned along the direction with an angle of $97-99^{\circ}$ respect to the polarization of ultraviolet (UV) light. The LC alignment was induced mainly by the photoaligned polymer chains made by the first UV-exposure even though the film was treated by multiple exposures with changing the polarization of UV light. From these results, it is concluded that the LC alignment on the film is induced by the photodimerization rather than the trans-cis photoisomerization.

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Measurements of Photoabsorption Cross Sections of Nitric Oxide by Using Double-Ionization Chamber

  • Chung, Yang-Soo;Kim, Hyun;Chung, Young-Min
    • Journal of the Optical Society of Korea
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    • v.10 no.4
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    • pp.157-161
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    • 2006
  • A synchrotron light source is useful in the vacuum ultraviolet (VUV) regime for olecular spectroscopy, such as photo absorption, photoionization, and dissociative hotoionization. In this research, we used a double-ion chamber (DIC) to measure hotoabsorption cross sections of a NO molecule in the wavelength range from 90 to 135 nm of 3B1 beam-line of the Pohang synchrotron light source with the resolution of the onochromator being 0.06 nm. The appearance wavelength for ionization was measured to be $134.19{\pm}0.09nm$ that is placed in the middle of the reported values though they don't agree with each other within the relative error limits. The auxiliary experimental works ave been done to test if there are any systematic error sources. The resultant ross-sections agree with previous results in general.

Optical Properties of blue emitting (Ca, Sr)$Mg_2Si_3O_9:Eu^{2+}$ phosphor

  • Lee, Hyun-Ju;Pil, Kyung;Yoo, Jae-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1276-1278
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    • 2009
  • A novel blue emitting $Ca_{1-x}Mg_2Si_3O_9:Eu_x$ phosphor was synthesized by the solid state reaction and its photoluminescence properties were optimized by controlling concentration of the activator contents and substituting concentration of Ca ion by Sr ion. The photoluminescence (PL) showed that this phosphor is efficiently excited by ultraviolet (UV)-visible light in the wavelength range from 200 to 410 nm. Also this phosphor emits intensely blue light with a broad peak at around 450 nm.

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Liquid crystal alignment and pretilt angle generation using oblique UV light irradiation on polymer surface (경사진 자외선조사를 이용한 셀의 프리틸트각의 입사각도 의존성)

  • 서대식;한정민;박두석;박태규;황율연
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.267-270
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    • 1998
  • In this study, we investigated the generation of pretilt angle for nematic liquid crystal (NLC) in a cell with oblique non-polarized ultraviolet (UV) light irradiation on polyimide (PI) surfaces. It was found that the monodomain alignment of the NLC is obtained in a cell with an angle of incidence of 70∼85$^{\circ}$on PI surface. We consider that the monodomain alignment of NLC is attributed to anisotropic dispersion force effect due to Photo-depolymerization of polymer on PI surfaces. Also, pretilt angle of NLC is generated about 3$^{\circ}$ with an angle of incidence of 70∼75$^{\circ}$. It is considered that the pretilt angle generation in NLC is attributed to interaction between the LC molecules and the polymer surfaces.

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Pretilt Angle Generation of Photo-aligned TN-LCD Using Oblique Non-polarized UV Light Irradiation on Polymer Surface (경사진 자외선조사를 이용한 네마틱액정의 프리틸각의 발생 및 광배향 TN-LCD의 전기광학특성)

  • 서대식;한정민;박두석
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.10
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    • pp.911-917
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    • 1998
  • In this paper, we have investigated the generation of pretilt angle for nematic liquid crystal (NLC) in a cell with oblique non-polarized ultraviolet(UV) light irradiation polyimide (PI) surface. It was found that the monodomain alignment of the NLC is obtained with an angle of incidence of 70∼85。 on PI surface. It is considered that the monodomain alignment of NLC is attributed to anisotropic of NLC is about 3。 with and angle of incidence of 70∼75。. Finally, we observed that the voltage-transmittance, response time, and voltage-holding-ratio(VHR) characteristics of photo-aligned twisted nematic(TN)-LCD with and angle of incidence of 85。 on PI surface were almost same compared to rubbing -treated TN-LCD.

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Characteristics of Residual Ozone Decomposition with Commercial Ozone Decomposition Catalyst (ODC) and Photo catalyst (상업용 오존촉매와 광촉매를 이용한 오존제거특성)

  • Byeon, Jeong-Hoon;Park, Jae-Hong;Hwang, Jung-Ho
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.1255-1260
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    • 2004
  • Decomposition of ozone at room temperature was investigated comparatively with commercial monolithic ozone decomposition catalyst (ODC, $MnO_2$) and monolithic photo catalyst ($TiO_2$). The effects of residence time, UV (ultraviolet) light dependence and ozone concentration on the conversion was presented. UV ray was irradiated using BLB (black light blue) lamp ($315{\sim}400$ nm), supplied with a constant intensity in the reactor. The concentration of ozone in the square-shape reactor can be controlled by combining the DBD (dielectric barrier discharge) reactor with an AC high voltage supply system. The catalytic performance, in presence of UV irradiation did not show significant changes for $MnO_2$ catalyst. $TiO_2$ catalyst was the different case, which showed higher decomposition activity in presence of UV irradiation. Deactivation of catalyst detected by real-time ozone monitor for 120 hours with a constant inlet ozone concentration.

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A new gas jet type Z-pinch extreme ultraviolet light source for next generation lithography (리소그라피를 위한 새로운 가스젯 방식의 Z방전 극자외선 광원)

  • Song, In-Ho;Choi, Chang-Ho;Ko, Kwang-Cheol;Hotta, Eiki
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1459-1460
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    • 2006
  • A new gas jet Z-pinch EUV light source having double gas jet electrodes has been developed. It has two nozzles and two diffusers. The EUV beam is collected from the side of pinch plasma, generated in between the inner nozzle and corresponding diffuser. A cylindrical shell of He gas curtain produced by the outer nozzle is specially designed for shielding the debris and suppressing the inner gas expansion. We have succeeded in generating EUV energy of 1.22 mJ/sr/2%BW/pulse at 13.5nm. The estimated dimension of EUV source is to be FWHM diameter of 0.07 mm and length of 0.34 mm, and FW 1/e2 diameter of 0.15 mm and length of 1.2 mm.

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Liquid crystal alignment by photo-dimerization reaction of PCEMA photo polymer (PCEMA 광폴리머의 광중합 작용을 이용한 액정배향)

  • 황정연;서대식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.541-544
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    • 1999
  • We synthesised a novel photo-alignment material of PCEMA (poly(cinnamolyethyl methacrylate)) on photo-dimerization reaction. Next we investigated the electro-optical (EO) characteristics of photo-aligned twisted nematic (TN)-liquid crystal display (LCD) with linearly polarized ultraviolet (UV) light irradiation on PCEHA surface. The excellent voltage-transmittance characteristics of photo-aligned TN-LCD on PCEMA surface were obtained. The threshold voltage of photo-aligned TN-LCD decreases with increasing the UV light irradiation time on PCEMA surface. Also, the response time of photo-aligned TN-LCD on PCEMA surface is almost the same as rubbing-aligned TN-LCD.

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Investigation of Electro-optical Characteristics in A-TN-LCD on Poly(vinyl)cinnamate Surfaces (Poly(vinyl)cinnamate막을 이용한 A-TN-LCD의 전기광학 특성)

  • 서대식;박지호;이보호
    • Electrical & Electronic Materials
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    • v.10 no.6
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    • pp.576-580
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    • 1997
  • In this paper, the viewing angle characteristics of amorphous (a) - twisted nematic (TN)-liquid crystal display (LCD) on poly(vinyl)cinnamate (PVC) surface with UV (ultraviolet) light irradiation were investigated. It was found that the threshold voltage increases with increasing the polymerization of PVC surfaces. We observed that the domain size of a-TN-LCD decreases with increasing the photo polymerization by increasing UV light irradiation time on PVC films. Also, we observed that the viewing angle of a-TN-LCD increased with increasing the photo polymerization on PVC surfaces. Finally, we consider that the viewing angle of a-TN-LCD on PVC surfaces is large compared to a-TN-LCD on polyimide (PI) surface.

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Top-Emitting Organic Light-Emitting Diodes Based on the Interfacial Electronic Structures of Bis(8-Quinolinolato)Aluminum (III)/Barium

  • Im, Jong-Tae;Yeom, Geun-Yeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.04a
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    • pp.5-6
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    • 2007
  • 반투명 전도성 음극 (semi-transparent conducting cathode)인 Ba (x nm)/Au (20 nm)/ITO (100 nm)을 이용하여 전면발광 유기전계 발광 소자 (top-emitting organic light-emitting didodes, TEOLEDs)를 제작했다. Ba과 bis(8-quinolinolato)aluminum (III) ($Alq_3$) 계면의 전자구조는 엑스선 광전자 분광법 (X-ray photoelectron spectroscopy, XPS), 자외선 광전자 분광법 (ultraviolet photoelectron spectroscopy, UPS) 및 가까운 끝머리 엑스선 흡수 미세구조 (near-edge x-ray absorption fine structure, NEXAFS) 스펙트럼의 광 방출 특성을 통하여 조사되었다. $Alq_3$/Ba 계면 특성에 있어서 XPS와 NEXAFS 특성에 의하면, $Alq_3$ (10.0 nm) 위에 Ba이 연속적으로 증착됨에 따라 Ba으로부터 $Alq_3$로의 전자전달 (electron charge transfer) 특성은 꾸준희 증가된다. 그러나 Ba의 두께가 1.0 nm 이상 초과되면 Ba의 전자전달에 기인한 반응성때문에 $Alq_3$의 분자구조가 해리된다. 한편, 제작된 TEOLEDE의 전류-전압-휘도 곡선의 경우에서도 바륨의 증착 두께가 1.0 nm일 때 가장 우수한 구동특성을 나타냈다.

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