• 한국환경보건학회지
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• 제39권2호
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• pp.144-150
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• 2013

Objectives: Cooking activity in indoor environments can generate particulate matter. The objective of this study was to determine the concentrations of ultrafine particles (UFP), $PM_{2.5}$, and $PM_{10}$ in cooking and non-cooking areas of major department stores in Seoul. Methods: Eighteen department stores in Seoul, Korea were measured for concentrations of particulate matter. Using real-time monitors, concentrations of UFP, $PM_{2.5}$ and $PM_{10}$ were simultaneously measured in cooking and non-cooking areas on the floor with a food court and a non-cooking floor. Results: The concentrations of UFP, $PM_{2.5}$ and $PM_{10}$ were significantly higher in cooking areas than in noncooking areas and non-cooking floors (p<0.05). UFP and $PM_{2.5}$ were significantly correlated in cooking areas and non-cooking areas but not in non-cooking floors. $PM_{2.5}$ were consisted of approximately 81% in $PM_{10}$ and highly correlated with $PM_{10}$ in all places. Conclusion: A higher correlation between UFP and $PM_{2.5}$ was shown on cooking floor than on non-cooking floor in department stores. High levels of fine particles were caused by cooking activities at food courts. The further management of PM is needed to improve the indoor PM levels at food courts in department stores.

• 한국세라믹학회지
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• 제36권4호
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• pp.343-353
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• 1999

2.45 GHz의 microwave가 수열 합성법으로 제조된 BaTiO3 분말의 특성에 미치는 영향을 조사하였다. 700W 출력으로 반응시켰을 때, microwave-autoclave system에서는 약 5분만에 BaTiO3 결정이 형성되기 시작하여, 10분 이상의 반응에서는 더 이상 결정성 증가는 관찰되지 않았다. Microwave-system의 경우에는 15분만에 결정이 형성되기 시작하여, 1시간정도의 반응으로 충분한 BaTiO3 분말을 얻을 수 있었다. Microwave를 이용한 균일가열의 영향으로 분말들은 균일하게 분산되어 있었고, 기존의 전기적인 가열 방법에서 나타나는 응집 현상이나 grain의 성장 등은 보이지 않았다. 제조된 분말의 크기는 보통 30~60 nm정도였는데, 졸 안의 Ba/Ti의 비가 분말의 크기를 결정하는데 중요한 역할을 하였다. 이는 여분의 바륨이 Ba(OH)2등과 같은 다른 상을 형성하여 BaTiO3 분말의 계면에 얇은 막을 형성하여 분말들의 응집 현상이나 grain의 성장을 억제하는 것으로 추정하였다. M1-crowave-autoclave 에서는 15분 정도의 반응만으로도 미량이지만 tetragonal-BaTiO3를 직접적으로 형성할 수 있었고, microwave-reflux에서는 25$0^{\circ}C$의 건조로써 미량의 tetragonal-BaTiO3를 얻을 수 있었다.

• 환경위생공학
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• 제17권2호
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• pp.11-17
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• 2002

Diesel particulate matter (DPM) is known to be one of the major harmful emissions produced by diesel engines. The majority of diesel particles are in the range of smaller than $I{\mu}\textrm{m}$. Because of their tiny volume, ultrafine diesel particles contribute very little to the total mass concentration which is currently regulated for automobile emissions. Diesel particles are known to have deleterious effects upon human health because they penetrate human respiratory tract and have negative effects on the health. The measurement of the number distribution of nanometer size particles (nanoparticles) in the diesel exhaust emission is important in order to evaluate their environmental and health impact, and to develop new types of diesel particulate filters. In this study, we directly sampled particulate matters emitted from a diesel truck mounted on the chassis dynamometer by a flow separator and dilution system, and measured the nanoparticles using two types of differential mobility analyzers combined with a Faraday cup electrometer (FCE) and a condensation particle counter (CPC). The particle size distributions were analyzed by changing engine operation condition, i.e. ratio of engine loading. The total number concentration of particles were increased with the engine loading ratio and the nanoparticles (less than 50nm) were affected by hydrocarbon (HC) concentration in the diesel exhaust.

• Asian Journal of Atmospheric Environment
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• 제11권2호
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• pp.131-137
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• 2017

A cyclone is an effective tool to facilitate the collection of aerosol particles without using filters, and in cell exposure studies is able to collect a sufficient amount of aerosol particles to evaluate their adverse health effect. In this study, we examined two different methods to improve the aerosol particle collection efficiency of a cyclone. The individual and combined effects of reducing the surface roughness of the inner wall of the cyclone and of using a circular cone attachment were tested. The collection efficiency of particles of diameter $0.2{\mu}m$ was improved by approximately 10% when using a cyclone with a smoothened inner wall (average roughness $Ra=0.08{\mu}m$) compared with the original cyclone ($Ra=5.1{\mu}m$). A circular cone attachment placed between the bottom section of the cyclone and the top section of a collection bottle, resulted in improved collection of smaller particles without the attachment. The 50% cutoff diameter of the modified cyclone (combined use of smoothened inner wall and attachment) was $0.23{\mu}m$ compared to $0.28{\mu}m$ in the original model. The combined use of these two techniques resulted in improved collection efficiency of aerosol particles.

• 한국세라믹학회지
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• 제25권6호
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• pp.631-638
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• 1988

Effect of Ca/P mole ratio on the precipitates and powder properties of hydroxyapatite was investigated. Powder and precipitates of hydroxyapatite were synthesized by the reaction of Ca(NO3)2.4H2O and (NH4)2 HPO4 solutions at room temperature. The pH value and compositions (Ca/P mole ratio) in starting solutions were 11 and 1.64-1.79(or 1.85), respectively. Rodlike hydroxyapatite precipitates were agglomerated together. The average agglomerated particle size was ranged from 2-8${\mu}{\textrm}{m}$. Among compositions, the minimum agglomerated particle size was shown at the Ca/P mole ratio 1.75. CO2 was contained in hydroxyapatite powders and these ultrafine powders had poor crystallinity. The specific surface area and specific total pore volume of hydroxyapatite powders were 104-137$m^2$/g and 0.396-0.467cc/g, respectively. When the Ca/P mole ratio was 1.75, these values were the maximum. And water content increased with the Ca/P mole ratio(Ca/P mole ratio>1.67). In most cases, hydroxyapaite was stable to 130$0^{\circ}C$. However, in the case of Ca/P mole ratio 1.64, hydroxyapatite was changed to $\alpha$-whitlockite at 120$0^{\circ}C$.

• 한국입자에어로졸학회지
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• 제17권3호
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• pp.71-79
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• 2021

Ultrafine dust, which is emitted from industrial factories or all kinds of vehicles, threatens the human's respiratory system and our environment. In this regard, separating airborne particles is essential to mitigate the severe problem. In this work, an axial cyclone for the effective technology of eliminating harmful dust is investigated by numerical simulation using Ansys 2020, Fluent R2. In addition, the optimized structure of the cyclone is constructed by means of multi objective optimization based on the response surface method which is a representative method to analyze the effect of design parameter on response variables. Among several design parameters, the modified length of the vortex finder and dust collector is a main point in promoting the performance of the axial cyclone. As a result, the optimized cyclone exhibits remarkable performance when compared to the original model, resulting in pressure drop of 307 Pa and separator efficiency of 98.5%.

• 한국세라믹학회지
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• 제30권4호
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• pp.325-331
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• 1993

Aqueous solutions of metallic salts, ZrO(NO3)2.2H2O and Y(NO3)3.5H2O were used as raw materials to synthesize crystalline submicron spherical powders of Zr0.94Y0.06O1.97 with tetragonal crystal phase. Each aqueous solution was mixed on the magnetic stirrer to homogenize for 12 hours. The concentration of the mixed solutionwas changed from 0.01mol/$\ell$ to 0.1mol/$\ell$ calculated as the concentration of Zr0.94Y0.06O1.97. Ultrafine droplets of starting mixed solution were sprayed by the ultrasonic vibrator and carried into the furnace kept at 55$0^{\circ}C$, $650^{\circ}C$, 75$0^{\circ}C$ and 85$0^{\circ}C$ using carrier gas of air (10$\ell$/min) and pyrolysed to form Y-TZP fine powders. The results of this exeriment were as follows. 1) Synthesized powders were nonagglomerated and spherical type. 2) Particle size distribution was narrow between 0.1${\mu}{\textrm}{m}$ and 1${\mu}{\textrm}{m}$. 3) Forming reaction Y-TZP was finished above synthetic temperature 75$0^{\circ}C$. 4) As the synthetic temperature rised from 55$0^{\circ}C$ to 85$0^{\circ}C$, the mean particle size decreased from 0.35${\mu}{\textrm}{m}$ to 0.22${\mu}{\textrm}{m}$ in the concentration of starting solution with 0.02mol/$\ell$. 5) At 75$0^{\circ}C$ of synthetic temperature, the concentration changes of starting solution from 0.01mol/$\ell$ to 0.1mol/$\ell$ increased the mean particle size from 0.24${\mu}{\textrm}{m}$ to 0.38${\mu}{\textrm}{m}$. 6) Chemical compositions of each synthesized particle were homogeneous nearly.

• 한국재료학회지
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• 제12권11호
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• pp.850-855
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• 2002

Silica powders were prepared from $SiCl_4$-$H_2$O system by chemical vapor deposition process, and investigated on size control of the products with reaction conditions. The products were amorphous and nearly spherical particles with 130nm~50nm in size. The size distribution became narrow with the increase of [$H_2$O]/[SiCl$_4$] concentration ratio. The particle size decreased with the increase of reaction temperature, [$H_2$O]/[SiCl$_4$] concentration ratio and total flow rate. The specific surface area measured by BET method was about three times larger than that of electron microscope method.

• 한국세라믹학회지
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• 제53권1호
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• pp.122-127
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• 2016

Tin oxide ($SnO_2$) nanoparticles have been synthesized by solution combustion method using citric acid as a fuel. The oxide to fuel ratio has been varied to obtain ultrafine nanoparticles with better surface area; such particles will be useful in many applications. With this synthesis method, spherical particles are formed having a particle size in the range of 11-30 nm and BET surface area of ~ $24m^2/g$. The degree of agglomeration of $SnO_2$ nanoparticles has been calculated.

• 한국분말재료학회지
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• 제19권5호
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• pp.356-361
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• 2012

The ultra-fine and less agglomerated titanium carbonitride particles were successfully synthesized by magnesiothermic reduction with low feeding rate of $TiCl_4+1/4C_2Cl_4$ solution. The sub-stoichiometric titanium carbide ($TiC_{0.5{\sim}0.6}$) particles were produced by reduction of chlorine component by liquid magnesium at $800^{\circ}C$ of gaseous $TiCl_4+1/4C_2Cl_4$ and the heat treatments in vacuum were performed for 5 hours to remove the residual magnesium and magnesium chloride mixed with produced $TiC_{{\sim}0.5}$. The final $TiC_{{\sim}0.5}N_{0{\sim}0.5}$ particle with near 100 nm in mean size and high specific surface area of $65m^2/g$ was obtained by nitrification under nitrogen gas at $1,150^{\circ}C$ for 2 hrs.