• Corrosion Science and Technology
• /
• v.18 no.6
• /
• pp.267-276
• /
• 2019

The purpose of this study was to examine the influence of conditions for quenching and/or tempering on the corrosion and hydrogen diffusion behavior of ultra-strong automotive steel in terms of the localized plastic strain related to the dislocation density, and the precipitation of iron carbide. In this study, a range of analytical and experimental methods were deployed, such as field emission-scanning electron microscopy, electron back scatter diffraction, electrochemical permeation technique, slow-strain rate test (SSRT), and electrochemical polarization test. The results showed that the hydrogen diffusion parameters involving the diffusion kinetics and hydrogen solubility, obtained from the permeation experiment, could not be directly indicative of the resistance to hydrogen embrittlement (HE) occurring under the condition with low hydrogen concentration. The SSRT results showed that the partitioning process, leading to decrease in localized plastic strain and dislocation density in the sample, results in a high resistance to HE-induced by aqueous corrosion. Conversely, coarse iron carbide, precipitated during heat treatment, weakened the long-term corrosion resistance. This can also be a controlling factor for the development of ultra-strong steel with superior corrosion and HE resistance.

• Korean Journal of Materials Research
• /
• v.28 no.7
• /
• pp.428-434
• /
• 2018

Hydrogen evolution on a steel surface and subsequent hydrogen diffusion into the steel matrix are evaluated using an electrochemical permeation test with no applied cathodic current on the hydrogen charging side. In particular, cyclic operation in the permeation test is also conducted to clarify the corrosion-induced hydrogen evolution behavior. In contrast to the conventional perception that the cathodic reduction reaction on the steel in neutral aqueous environments is an oxygen reduction reaction, this study demonstrates that atomic hydrogen may be generated on the steel surface by the corrosion reaction, even in a neutral environment. Although a much lower permeation current density and significant slower diffusion kinetics of hydrogen are observed compared to the results measured in acidic environments, they contribute to the increase in the embrittlement index. This study suggests that the research on hydrogen embrittlement in ultra-strong steels should be approached from the viewpoint of corrosion reactions on the steel surface and subsequent hydrogen evolution/diffusion behavior.

• Journal of Welding and Joining
• /
• v.34 no.1
• /
• pp.7-20
• /
• 2016

A brief overview is given of the development of various structural steels and their welding application technology. Firstly, the general characteristics and welding performance of structural steels used in architecture and bridge are introduced. For safety against earthquakes or strong wind, and for highly efficient welding in high-rise building constructions, ultra high strength steel with tensile strength over 800 MPa or high HAZ toughness steel plates under high heat input welding have been developed. In particular, efficient welding technology ensuring high resistance to cold and hot cracking of ultra high strength steel is reviewed in the present paper. Secondly, various coated steels used mainly for outer part in construction are briefly discussed. Moreover, a major drawback of coated steel during welding operation, and several solutions to overcome such technical problem are proposed. It is hoped that this review paper can lead to significant academic contributions and provide readers interested in the structural steels with useful welding technology.

• Korean Journal of Materials Research
• /
• v.17 no.12
• /
• pp.634-636
• /
• 2007

The texture and microstructure in Cu/Nb added ultra low carbon steels through the different thickness layer were studied after hot rolling. It was found that the two ultra low carbon steels all show the inhomogeneity of hot rolling texture and the Cu-added ultra low carbon steel was far more inhomogeneous than Nb-added one. In the center layer, the strong ${\alpha}\;fibre,\;{\gamma}\;fibre$ textures and the shear textures including 001<110>, 111<112> were founded. Near the surface, the ${\alpha}\;fibre$ texture and the orientation texture caused by a typical plane-strain deformation condition of bcc metals were observed.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
• /
• 2002.10b
• /
• pp.157-158
• /
• 2002

A surface hardenable low alloy carbon steel was implanted with medium energy (20 - 50KeV) $N_2^+$ ions to produced a modified hardened surface. The implantation conditions were varied and are given in several doses. The surface hardness of treated and untreated steels were measured using depth sensing ultra micro indentation system (UMIS). It is shown that the hardness of nitrogen ion implanted steels varied from 20 to 50GPa depending on the implantation conditions and the doses of implantation. The structure of the modified surfaces was examined by X-ray photoelectron spectroscopy (XPS). It was found that the high hardness on the implanted surfaces was as a result of formation of non-equilibrium nitrides. High-resolution XPS studies indicated that the nitride formers were essentially C and Si from the alloy steel. The result suggests that the ion implantation provided the conditions for a preferential formation of C and Si nitrides. The combination of evidences from nano-indentation and XPS, provided a strong evidence for the existence of $sp^3$ type of bonding in a suspected $(C,Si)_xN_y$ stoichiometry. The formation of ultra hard surface from relatively cheap low alloy steel has significant implication for wear resistance implanted low alloy steels.

• Corrosion Science and Technology
• /
• v.20 no.5
• /
• pp.295-307
• /
• 2021

Effects of ε-carbide (Fe_2.4C) on corrosion and hydrogen diffusion behaviors of ultra-strong steel sheets for automotive application were investigated using a number of experimental and analytical methods. Results of this study showed that the type of iron carbide precipitated during tempering treatments conducted at below A₁ temperatures had a significant influence on corrosion kinetics. Compared to a steel sample with cementite (Fe₃C), a steel sample with ε-carbide (Fe_2.4C) showed higher corrosion resistance during a long-term exposure to a neutral aqueous solution. In addition, the diffusion kinetics of hydrogen atoms formed by electrochemical corrosion reactions in the steel matrix with ε-carbide were slower than the steel matrix with cementite because of a comparatively higher binding energy of hydrogen with ε-carbide. These results suggest that designing steels with fine ε-carbide distributed uniformly throughout the matrix can be an effective technical strategy to ensure high resistance to hydrogen embrittlement induced by aqueous corrosion.

• Advances in concrete construction
• /
• v.10 no.1
• /
• pp.1-11
• /
• 2020

This study intends to produce an ultra-high performance fibre reinforced concrete (UHPFRC) made with hybrid fibres (i.e., steel and polypropylene). Compressive and tensile strength characteristics of the hybrid fibres UHPFRC are considered. A total of 14 fibre-reinforced composites (FRCs) with different fibre contents or types of fibres were prepared and tested in order to determine a suitable hybrid fibre combination. The compressive and tensile strengths of each concrete at 7 days were determined. The results showed that a hybrid mix of micro-polypropylene and steel fibres exhibited good compromising performances and is the ideal reinforcement mixture in a strong, cost-effective UHPFRC. In addition, maximum compressive strength of 167 MPa was achieved for UHPFRC using 1.5% steel fibres blended with 0.5% macro-polypropylene fibres.

• Steel and Composite Structures
• /
• v.22 no.5
• /
• pp.1085-1114
• /
• 2016

This paper investigates the transverse impact response for ultra lightweight cement composite (ULCC) filled pipe-in-pipe structures through a parametric study using both a validated finite element procedure and a validated theoretical model. The parametric study explores the effect of the impact loading conditions (including the impact velocity and the indenter shape), the geometric properties (including the pipe length and the dimensions of the three material layers) as well as the material properties (including the material properties of the steel pipes and the filler materials) on the impact response of the pipe-in-pipe composite structures. The global impact responses predicted by the FE procedure and by the theoretical model agree with each other closely. The parametric study using the theoretical approach indicates the close relationships among the global impact responses (including the maximum impact force and the maximum global displacement) in specimens with the equivalent thicknesses, proposed in the theoretical model, for the pipe-in-pipe composite structures. In the pipe-in-pipe composite structure, the inner steel pipe, together with the outer steel pipe, imposes a strong confinement on the infilled cement composite and enhances significantly the composite action, leading to improved impact resistance, small global and local deformations.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.5 no.3
• /
• pp.290-297
• /
• 2017

The flexural behavior tests of UHPC segmental U-girder and composite U-girder which has 160MPa compressive strength and 15.4m length were carried out. The test variables are volume fraction of steel fibers and slab over the U-girder. Each U-girder has longitudinal re-bars in web and lower flange. PS tendons which has 2 of 15.2mm diameter in upper flange and PS tendons which has 7 of 15.2mm diameter in lower flange were arranged and prestressed at onetime in U-girder connection stage. Enough strong prestressing force which applied to U-girder due to ultra high performance concrete strength can withstand the self weight and dead load in U-girder stage. By comparison with the brittle behavior of U-girder, composite U-girder showed the stable and ductile behavior. After the construction of slab over U-girder, flexural load capacity of composite U-girder can bear the design load in final construction stage with only one time prestressing operation which already carried out in U-girder stage. This simple prestressing method due to the ultra high strength concrete have the advantage in construction step and cost. The shear key which has narrow space has the strong composite connection between ultra high strength concrete U-girder and high strength concrete slab didn't show any slip and opening right before failure load.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2021.05a
• /
• pp.187-188
• /
• 2021

In the case of the Busan North Port, where the Busan Opera House is located, it is an environment exposed to various external deterioration factors such as frequent strong winds, seawater and salty winds, and an exterior material using UHPC (Ultra High Performance Concrete), a highly durable exterior material as a solution to this. Has been adopted. in this study, an economical production and construction direction was reviewed by applying UHPC to the exterior panels of atypical buildings that cannot cope with GFRC, metal, and glass, which are the main exterior finishing materials applied so far. When steel fibers are used, structural performance may be better than organic fibers, but due to environmental factors in Busan, corrosion due to exposure to steel fibers or problems with safety management after construction and completion may occur. Therefore, the site used the newly developed SACF fiber. Facade design of atypical buildings, which will increase in the future, is an important part, and the scope of use of UHPC panels is expected to increase in the future as design trends and demand for high durability increase.