• Title/Summary/Keyword: UV.

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Photocatalytic Oxidation of Han River Humic Substances and Change of Their Characteristics by $TiO_2/UV$ in a Rotating Photoreactor ($TiO_2/UV$ 회전반응기를 이용한 한강 휴믹물질의 광촉매산화 처리 및 특성 변화)

  • Shin, Jee-Won;Kim, Hyun-Chul;Han, Ihn-Sup
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.10
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    • pp.1129-1135
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    • 2005
  • In this study. the applicability of a rotating reactor for the oxidative removal of aqueous humic substances extracted from the Han River in Seoul, Korea was investigated. As air blowing for proper mixing of $TiO_2$ photocatalyst could inhibit UV-irradiation between a UV lamp and photocatalyst by air bubbles, a rotating reactor with some baffles was used for better UV-irradiation effect in this study. Han River humic substances are different from the other commercial humic substances(e.g., from Aldrich and International Humic Substance Society). Their characteristics were investigated with structural and spectroscopic analyses using FT-IR(Fourier transform-infrared), and $^{13}C$-NMR (nuclear magnetic resonance). The humic substances were extracted by XAD-7HP and treated with $TiO_2$-coated hollow beads under UV-A and UV-C irradiation in order to solve problems of separation and recovery of photocatalyst after reaction. At approximately 5 mg/L of initial TOC concentration, pH 3 and $2.0\;g-TiO_2/L$ dose, photocatalytic oxidation of Han River humic substances showed the optimum removal efficiency. Also, UV-C and UV-A lamps showed similar TOC removal efficiency. However, under UV-C irradiation, Han River humic substances were degraded to smaller compounds and increased the proportion of low molecular weight fractions compared to UV-A.

UV-B Effects on Growth and Nitrate Dynamics in Antarctic Marine Diatoms Chaetoceros neogracile and Stellarima microtrias (중파 자외선에 노출된 남극 규조 Chaetoceros neogracile와 Stellarima microtrias의 성장과 질산염 흡수량의 변화)

  • Gang, Jae Sin;Gang, Seong Ho;Lee, Yun Ho;Sim, Jeong Hui;Lee, Sang Hun
    • ALGAE
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    • v.18 no.1
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    • pp.13-20
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    • 2003
  • Two isolated Antarctic marine diatoms, Chaetoceros neogracile VanLandingham and Stellarima microtrias (Ehrenberg) Hasle and Sims were examined to show changes of growth and uptake rate of nitrate due to UV-B irradiance. Chlorophyll (chl) a concentration was regarded as the growth index of diatom. The diatoms were treated with UV-B radiation and cultured for 4 days under cool-white fluorescent light without UV-B radiation. Two levels of UV-B exposures were applies: 1 and 6 W $m^{-2}$. Durations of UV-B treatment were 20, 40 and 60 minutes under 6 W $m^{-2}$ and 1, 2, 3, 4 and 5 hrs under 1 W $m^{-2}$. The control groups were cultured at the same time without UV-B radiation. The growth rates of two diatoms decreased under 1 and 6 W $m^{-2}$ UV-B irradiances than that of control group. After 4 days, chl a concentrations of C. neogracile were increased more than 4 times from 133 μgo$l^{-1}$ to 632 μgo$l^{-1}$ in control group. However, the concentration of experimental groups under 1 W $m^{-2}$ UV-B were only increased from 139 μgo$l^{-1}$ to 421 μgo$l^{-1}$ during one hour and the chl a concentrations were decreased from 144 μgo$l^{-1}$ to 108 μgo$l^{-1}$ during five hour. Growth of diatom dramatically more decreased under 6 W $m^{-2}$ UV-B than 1 W $m^{-2}$ UV-B. The chl a concentration of experimental groups under 6 W $m^{-2}$ UV-B for one hour was only increased from 111 μgo$l^{-1}$ to 122 μgo$l^{-1}$. In the case of S. microtrias showed also similar pattern to C. neogracile by UV-B radiation. The uptake rates of nitrate by the two strains were decreased abruptly under 6 W $m^{-2}$ UV-B irradiances. When two strains were treated under 1 and 6 W $m^{-2}$ UV-B during one hour, the strains were only continued growth and uptake of nitrate under 1 W $m^{-2}$ UV-B. This experimental evidence shows that exposure to UV-B radiation especially to high irradiance of UV-B decreases diatom survival and causes lower decrease of nutrient concentrations by microalgae in Antarctic water. Furthermore, evidence suggests that microalgal communities confined to near-surface waters in Antarctica will be harmed by increased UV-B radiation, thereby altering the dynamics of Antarctic marine ecosystems.

Growth and Physiological Responses of Shade Intolerant and Intermediate Tree Seedlings to Enhanced UV-B Radiation (자외선(紫外線)-B 증가조사(增加照射)에 대한 양수(陽樹)와 중성수(中性樹) 유묘(幼苗)의 생장(生長)과 생리적(生理的) 반응(反應)에 관한 연구(硏究))

  • Kim, Jong Jin;Hong, Sung Gak
    • Journal of Korean Society of Forest Science
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    • v.88 no.4
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    • pp.469-476
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    • 1999
  • This study was carried out to investigate the growth and physiological response of shade intolerant and intermediate tree seedlings to enhanced UV-$B_{BE}$(biologically effective UV-B) radiation. The seedlings of Betula platyphylla var. japonica Hara(shade intolerant species) and Fraxinus rhynchophylla Hance(shade intermediate species) were treated with one of the three levels of UV-$B_{BE}$ dosages - ambient UV-$B_{BE}$, ambient+3.2, and ambient+$5.2\;KJ\;m^{-2}day^{-1}$) for 14 weeks in the field condition. Height and root collar diameter growth, leaf area, and biomass production of the seedlings of two species were reduced by enhanced UV-B radiation. Leaf stomatal resistance to water vapor of the F. rhynchophylla seedling was increased by the UV-B increment. The reductions in total chlorophyll and carotenoid were more apparent in the F. rhynchophylla than B. platyphylla seedling. There was no statistically significant changes in the concentration of UV-B absorbing compound($A_{300}$) in the leaves of the two species among the UV-B treatment. However the $A_{300}$ tented to be increased in F. rhynchophylla by enhanced UV-B radiation. These results indicate that the growth and the physiological and biochemical responses between B. platyphylla and F. rhynchophylla were different to enhanced UV-B environment.

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Changes in Chemical components of Peach (Prunus persica L. Batsch) Treated with Low Dose UV-C Irradiation (저선량의 UV-C 처리 복숭아의 주요 성분 변화)

  • Lee, Kyung-Haeng;Jang, Hyun-Jung;Choi, Ji-Hye;Ban, Ki-Eun;Park, Jae-Hee;Lee, Yu-Jin
    • The Korean Journal of Food And Nutrition
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    • v.26 no.3
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    • pp.573-577
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    • 2013
  • To extend the shelf-life of the domestic peach, a low dose UV-C irradiation (0~3.0 $kJ/m^2$) was treated and the changes of the major chemical components were investigated. The contents of polyphenols in UV-treated peaches were higher than that of control with the highest at 0.25 $kJ/m^2$ UV treatment. The contents of polyphenols of control and UV treatments were slightly reduced by storage period. The contents of flavonoid were not significantly different among the control and UV treatments. Detected free sugars of the control and UV treatments were fructose, glucose, maltose and sucrose. Sucrose content was higher than that of other free sugars and free sugar content increased during storage. And free sugar content was not significantly different between the control and UV treatments. The free amino acid content of the control and UV treatments were 115.38 mg% and 95.92~120.94 mg% respectively, but there was no significant difference between the control and UV treatments.

A Study on the Effect on UV Exposure in Coastal Buildings (연안건축물의 자외선 노출에 따른 안전성 연구)

  • Kim, Taehwan;Uh, Jesun
    • Journal of the Society of Disaster Information
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    • v.17 no.2
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    • pp.195-205
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    • 2021
  • Purpose: The ultraviolet reflectance and transmittance of coastal building materials are one of the important factors of ultraviolet radiation in and out of coastal building. In this research, the ultraviolet spectral reflectance of many kinds of building materials was measured. Also, the relationships with the lightness, roughness, and chromaticity, which are surface characteristics, were reviewed and suggested. Method: In this study, according to the CIE classification, the ultraviolet region was defined as short-wavelength region UV-C(10nm~280nm), medium-wavelength region UV-B (280-315 nm), and long-wavelength region UV-A (315-400nm), and the visible light region was defined as (400nm~780nm). Spectrophotometer was used to continuously measure the reflectance from the ultraviolet region to the visible light region. Results: From the measurement results, the ultraviolet reflectance on Wood was shown to be about Visible 55-68%, UV-A* 7-12%, and UV-B 4-5%. Wall tiles are about Visible18-40%, UV-A* 8-20%, and UV-B* 7-8%. That on concrete was shown to be about Visible 37%, UV-A* 28%, and UV-B*19%. Conclusion: The ultraviolet reflectance can be estimated by visible reflectance. Also, it is important to select a variety of materials according to the application when blocking UV.

Fabrication of ZnO inorganic thin films by using UV-enhanced Atomic Layer Deposition

  • Song, Jong-Su;Yun, Hong-Ro;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.312.1-312.1
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    • 2016
  • We have deposited ZnO thin films by ultraviolet (UV) enhanced atomic layer deposition using diethylznic (DEZ) and water (H2O) as precursors with UV light. The atomic layer deposition relies on alternating dose of the precursor on the surface and subsequent chemisorption of the precursors with self-limiting growth mechanism. Though ALD is useful to deposition conformal and precise thin film, the surface reactions of the atomic layer deposition are not completed at low temperature in many cases. In this experiment, we focused on the effects of UV radiation during the ALD process on the properties of the inorganic thin films. The surface reactions were found to be complementary enough to yield uniform inorganic thin films and fully react between DEZ and H2O at the low temperature by using UV irradiation. The UV light was effective to obtain conductive ZnO film. And the stability of TFT with UV-enhanced ZnO was improved than ZnO by thermal ALD method. High conductive UV-enhanced ZnO film have the potential to applicability of the transparent electrode.

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UV transparent stamp fabrication for UV nanoimprint lithography (UV 나노임프린트 리소그래피용 UV 투과성 나노스탬프 제작)

  • Jeong, Jun-Ho;Sim, Young-Suk;Sohn, Hyon-Kee;Shin, Young-Jae;Lee, Eung-Suk;Hur, Ik-Boum;Kwon, Sung-Won
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1069-1072
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    • 2003
  • Ultraviolet-nanoimprint lithography (UV-NIL) is a promising nanoimprint method for cost-effectively defining nanometer scale structures at room temperature and low pressure. Nanostamp fabrication technology is a key technology for UV-NIL because fabricating a high resolution nanostamp is the first step for defining high resolution nanostructures in a substrate. We used quartz as an UV transparent stamp material for the UVNIL. A $5{\times}5{\times}0.09$ inch stamp was fabricated using the quartz etch process in which Cr film was used as a hard mask for transferring nanostructures into the quartz. In this paper, we describe the quartz etching process and discuss the results including SEM images.

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Single-step UV nanoimprint lithography on a 4" Si wafer (4" Si 웨이퍼에 대한 single-step UV 나노임프린트 리소그래피)

  • 정준호;손현기;심영석;신영재;이응숙;최성욱;김재호
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.199-202
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    • 2003
  • Ultraviolet-nanoimprint lithography (UV-NIL) is a promising method for cost-effectively defining nanoscale structures at room temperature and low pressure. Since the resolution of nanostructures depends strongly upon that of nanostamps, the nanostamp fabrication technology is a key technology to UV-NIL. In this paper, a 5$\times$5$\times$0.09 in. quartz stamp whose critical dimension is 377 nm was fabricated using the etch process in which a Cr film was employed as a hard mask for transferring nanostructures onto the quartz plate. To effectively apply tile fabricated 5-in. stamp to UV-NIL on a 4-in. Si wafer, we have proposed a new UV-NIL process using a multi-dispensing method as a way to supply resist on a wafer Experiments have shown that the multi-dispensing method can enable UV-NIL rising a large-area stamp.

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WTP UV Disinfection System (국내하수처리장 자외선소독조 운영실태 및 기술동향)

  • Lee, J.Y.;Kim, Y.T.;Lee, T.J.
    • 유체기계공업학회:학술대회논문집
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    • 2005.12a
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    • pp.126-132
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    • 2005
  • UV disinfection system allows the disinfection of municipal and industrial water and wastewater without the use of expensive chlorination and dechlorination techniques, labor intensive equipments In traditional ultraviolet systems the UV lamps are seperated from water by quartz sleeves. quartz is one of. the few materials that is virtually transparent to UV light, the UV lamp is placed inside the Quartz sleeve. UV light from the lamp is passed through the quartz and into the water, thereby providing disinfection. In fluoropolymer tube-used non-contact UV systems, the water flows through fluoropolymer plastic tubes. banks of UV lamps surround these tubes such that each tube gets exposed to ultra violet light from all sides. in non-contact design the lamps operates at almost constant temperature. this design is extremly efficient in the utilization of UV energy and superior to conventional contact- systems.

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One-side Water-repellent Finish of PET Fabrics using UV/Ozone (UV/Ozone 조사에 의한 PET 직물의 편면 발수가공)

  • Kim, Su-Jin;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.23 no.2
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    • pp.100-106
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    • 2011
  • UV-curable water-repellent finish was carried out to impart one-side repellency to the PET fabrics using a formulation of a UV-active fluorocarbon agent and a water soluble photoinitiator. The aqueous formulation was padded on the PET fabrics and it was subsequently UV-cured. The unirradiated side of the cured fabrics was made to wetteable to water by the prolonged UV/ozone irradiation. The influence of photoinitiator concentration, agent concentration and UV energy for photodegradation on the performance of the finished fabrics were investigated. The difference in the functional property of front and back sides was examined by measuring water repellency at each side of the treated fabrics, which resulted in four rating difference between two-side. The UV-cured and photodegraded PET surfaces were characterized by ATR, ESCA and FE-SEM.