• Title/Summary/Keyword: UV-visible spectrum

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Feasibility Study of IAQ Enhancement by Visible Light Photocatalyst (가시광 응답형 광촉매 제조와 이를 활용한 실내공기환경 개선 적용 타당성 조사)

  • Lee, Tai-Kyu;Yoon, Woo-Sug;Kim, Dong-Hyung;Hwang, Chul-Soon;Lim, Ji-Hun;Yoon, Jung-Ho;Kim, Young-mi
    • KIEAE Journal
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    • v.4 no.2
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    • pp.37-40
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    • 2004
  • New visible photocatalyst(Nanovis$^{(R)}$) has been synthesized to overcome the barrier of limitation of UV light utilization of current $TiO_2$ photocatalyst. It was found that red shift of absorption spectrum to 550nm was achieved. Its physical properties were characterized by XRD, BET and TEM. It is also observed that Nanovis$^{(R)}$ has a photocatalytic activity for photodegradation of Trichloroethylene under visible light irradiation. V,VII group doped into substitutional sites of $TiO_2$ has proven to be indispensable for band-gap narrowing and photocatalytic activity. These test results lead us to conclude that Nanovis$^{(R)}$ can be used for IAQ improvemen and for photocatalytic water splitting to hydrogen.

Preparation of ZnO Thin Films with UV Emission by Spin Coating and Low-temperature Heat-treatment (스핀코팅 및 저온열처리에 의한 자외선 발광특성을 갖는 산화아연 박막의 제조)

  • Kang, Bo-An;Jeong, Ju-Hyun
    • Journal of Korean Ophthalmic Optics Society
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    • v.13 no.3
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    • pp.73-77
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    • 2008
  • Purpose: This research is that prepare amorphous or crystalline ZnO thin films with pure strong UV emission on soda-lime-silica glass (SLSG) substrates by low-temperature annealing. Methods: Growth characteristic and optical properties of the amorphous or nano-crystalline ZnO thin films prepared on soda - lime - silica glass substrates by chemical solution deposition at 100, 150, 200, 250 and $300^{\circ}C$ were investigated using X-ray diffraction analysis, ultraviolet - visible - near infrared spectrophotometer, and photoluminescence. Results: The films exhibited an amorphous pattern even when finally annealed at $100^{\circ}C{\sim}200^{\circ}C$ for 60 min, while crystalline ZnO was obtained by prefiring at 250 and $300^{\circ}C$. The photoluminescence spectrum of amorphous ZnO films shows a strong NBE emission, while the visible emission is nearly quenched. Conclusions: These results indicate it should be possible to cheaply and easily fabricate ZnO-based optoelectronic devices at low temperature, below $200^{\circ}C$, in the future.

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Characteristics of organic electroluminescent devices having buffer layers (Buffer층을 가진 유기 전기 발광 소자의 특성)

  • 이호식;고삼일;정택균;이원재;김태완;강도열
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.399-402
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    • 1998
  • Electroluminescent(EL) devices based on organic thin films have attracted lots of interests in large-area light-emitting display. One of the problems of such device is a lifetime, where a degradation of the cell is possibly due to an organic layers thickness, morphology and interface with electrode. In this study, light-omitting organic electroluminescent devices were fabricated using Alq$_3$(8-hydroxyquinolinate aluminum) and TPD(N,N'-diphenyl-N,N'-bis(3-methylphenyl(1-1\`-biphenyl]-4,4'-diamine). Where Alq$_3$ is an electron-transport and emissive layer, TPD is a hole-transport layer. The cell structure is ITO/TPD/Alq$_3$/Al and the cell is fabricated by vacuum evaporation method. In a measurement of current-voltage characteristics, we obtained a turn-on voltage at about 9 V. We also investigated stability of the devices using buffer layer with blend of PEI (Poly ether imide) and TPD by varying mot ratios between ITO and Alq$_3$. In current-voltage characteristics measurement, we obtained the turn-on voltage at about 6 V and observed an anomalous behavior at 3∼4 V. And we used other buffer layer of PEDT(3,4-pyrazino-3',4'-ethylenedithio-2,2',5,5'-tetrathiafulvalenium) with ITO/PEDT/TPD/Alq$_3$Al structure. We observed a surface morphology by AFM(Atomic Force Microscopy), UV/visible absorption spectrum, and PL(Photoluminescence) spectrum. We obtained the UV/visible absorption peak at 358nm in TPD and at 359nm in Alq$_3$, and the PL peaks at 410nm in TPD and at 510nm in Alq$_3$. We also studied EL spectrum in the cell structure of ITO/(TPD+PEI)/Alq$_3$/Al.

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Dyeability and Functionality of Chaenomelis Fructus Extract (모과 추출물의 염색성과 기능성)

  • Nam, Ki-Yeon;Lee, Jung-Soon
    • Fashion & Textile Research Journal
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    • v.14 no.3
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    • pp.478-485
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    • 2012
  • The dying properties of fabrics with Chaenomelis Fructus extract were studied through an investigation of the characteristic of Chaenomelis Fructus colorants, the effect of dyeing conditions (dye temperature, dyeing concentration, and times on dye uptakes), effect of mordant, effect of UV irradiation, and color change in addition, antimicrobial ability and deodorant ability were estimated. In the UV-Visible spectrum, the wavelength of maximum absorption of Chaenomelis Fructus extract was 280 nm and showed that tannin is the major pigment component. From the increase of absorbance by UV irradiation, it was assumed that catechol tannin color was developed through UV irradiation. An increased dyeing concentration resulted in a larger dye uptake. Dye uptake increased as the dyeing time and temperature increased. Chaenomelis Fructus extract showed relatively good affinity to silk than cotton. Mordant, Fe and Cu were effective to increase the dye uptake of cotton fabric in addition, the dye uptake of silk fabric mordanted with Fe and K improved. UV irradiation let the color of dyed fabrics develop regardless of the UV irradiation stage however, UV irradiation on the dyed fabric was more effective than on the extract for the color development. Dyed silk fabric showed very good antimicrobial abilities of 99.9% in addition, deodorant ability improved in the fabric dyed with Chaenomelis Fructus extract.

Multi-spectral Flash Imaging using Region-based Weight Map (영역기반 가중치 맵을 이용한 멀티스팩트럼 플래시 영상 획득)

  • Choi, Bong-Seok;Kim, Dae-Chul;Lee, Cheol-Hee;Ha, Yeong-Ho
    • Journal of the Institute of Electronics and Information Engineers
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    • v.50 no.9
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    • pp.127-135
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    • 2013
  • In order to acquire images in low-light environments, it is usually necessary to adopt long exposure times or resort to flash lights. However, flashes often induce color distortion, cause the red-eye effect and can be disturbing to subjects. On the other hand, long-exposure shots are susceptible to subject-motion, as well as motion-blur due to camera shake when performed hand-held. A recently introduced technique to overcome the limitations of traditional low-light photography is that of multi-spectral flash. Multi-spectral flash images are a combination of UV/IR and visible spectrum information. The general idea is that of retrieving details from the UV/IR spectrum and color from the visible spectrum. However, multi-spectral flash images themselves are subject to color distortion and noise. This works presents a method to compute multi-spectral flash images so that noise can be reduced and color accuracy improved. The proposed approach is a previously seen optimization method, improved by the introduction of a weight map used to discriminate uniform regions from detail regions. The weight map is generated by applying canny edge operator and it is applied to the optimization process for discriminating the weights in uniform region and edge. Accordingly, the weight of color information is increased in the uniform region and the detail region of weight is decreased in detail region. Therefore, the proposed method can be enhancing color reproduction and removing artifacts. The performance of the proposed method has been objectively evaluated using long-exposure shots as reference.

The Development of UV-IR Combination Flame Detector (UV-IR 복합형 화재감지장치 개발)

  • 이복영;권오승;정창기;박상태
    • Journal of the Korean Society of Safety
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    • v.16 no.1
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    • pp.1-8
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    • 2001
  • All objects emit thermal radiation and this radiation is the basis of the techniques used to detect flames. The usual phenomena occurring in the initial stage of the fire are generally invisible products of a combustion and visible smoke. Liquid or gaseous materials do not undergo a smoldering stage so that fires develop very rapidly. Also, the heat generated by the initial flames is usually not sufficient to activate a heat detector. In this case the most effective criterion for automatic fire detection is the flame. According to the fire regulation of korea, the compulsory standard provided that a flame detector shall be installed in a place that the attachment height of detector is higher than 20 m, chemical plants, hangar, refinery, etc.. The results of the research and development are discriminated between a flame and other radiant emitters, developed a UV detector tube contains an inert gas which absorbs UV radiation, developed PZT pyroelectric element is based on the use of photovoltanic cell, developed IR band-pass filter that only allow a 4.3 $\mu\textrm{m}$ radiation wavelength to reach the sensors and developed UV-IR combination flame detector combined into a single detection device.

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Photoisomerization of Monolayer LB Films mixed with Fatty Acid and Phospholipid at mixture ratios (지방산과 인지질의 혼합비에 따른 단분자 LB막의 광이성질화 현상에 관한 연구)

  • 박근호;강동완;김성일;박태곤
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.479-482
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    • 2000
  • We investigated UV-vis absorbances to observe photoisimerization and effect of temperature using the mixture solution in chloroform and the LB monolayer mixed with DLPE and 8A5H containing azobenzene which shows reversible cis-trans isomerization irradiated by alternate lights. We could find that the absorption spectrum of the mixtures solution and LB monolayer was reversibly induced to photoisomerization irradiated by Uv of both and visible lights, in addition the absorbance by alternate temperatures.

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Soil Chemical Studies on the Humic Substances of Paddy soils(I) -Photoabsorption Spectra of Humic acid and Hymatomelanic acid- (답토양부식물(畓土壤腐植物)에 대(對)한 토양화학적연구(土壞化學的硏究)[I] -Humin 산(酸)과 Hymatomelan 산(酸)의 흡광(吸光) Spectrum-)

  • Lim, S.U.;Kim, M.J.;Lee, C.Y.
    • Applied Biological Chemistry
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    • v.12
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    • pp.115-118
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    • 1969
  • In a series of studies on the formation processes and chemical properties of humic substances from paddy soils the photoabsorption spectra of hymatomelanic and humic acids were recorded in the visible, ultraviolet and infrared regions. The spectra patterns of both fractions in the visible range were indicative of the decrease in optical density with the rise of wavelength and the UV-spectra showed the maximum peak at $235\;m{\mu}$, the minimum at $395\;m{\mu}$. The IR-spectra indicate a typical pattern showing a few sharp peaks in both fractions. The spectra of both fractions were compared and discussed.

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Surface Photooxidation of Poly(butylene terephthalate) Films by UV/Ozone Irradiation (자외선/오존 조사에 의한 Poly(butylene terephthalate) 필름의 표면 광산화)

  • Joo, Jin-Woo;Jang, Jinho
    • Textile Coloration and Finishing
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    • v.28 no.2
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    • pp.63-69
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    • 2016
  • Poly(butylene terephthalate)(PBT) surface was modified by UV/ozone irradiation and the effect of UV energy on the surface properties of the irradiated PBT films were characterized by the reflectance, surface roughness, contact angles, ESCA, and ATR analyses of the film surface. The surface reflectance, at the short wavelength of visible spectrum of particularly 400nm, decreased with increasing UV energy. And the irradiation roughened the film surface uniformly in the nano scale. The maximum surface roughness increased from 110nm for the unirradiated sample to 303nm at the UV energy of $10.6J/cm^2$. The surface energy of PBT film increased from $50.5mJ/m^2$ for the unirradiated PBT to $58.8mJ/m^2$ at the irradiation of $21.2J/cm^2$. The improvement in hydrophilicity was caused by the introduction of polar groups containing oxygens such as C-O and C=O bonds resulting in higher $O_{1s}/C_{1s}$. The increased dyeability of the modified film to cationic dyes may be resulted from the photochemically introduced anionic and dipolar dyeing sites on the PBT films surfaces.

Physicochemical Properties of Antioxidant Fractions Extracted from Freeze-Dried Coffee by Various Solvents (동결건조 커피의 순차용매 분획별 특성과 항산화 효과)

  • Rhi, Ju-Won;Shin, Hyo-Sun
    • Korean Journal of Food Science and Technology
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    • v.28 no.1
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    • pp.109-116
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    • 1996
  • The relationship between antioxidant activities and physicochemical properties of several fractions obtained from freeze-dried (FD) coffee were investigated. The nine kinds of fraction were consecutively extracted from FD coffee with solvents in increasing order of polarity, and the higher polarity of the solvent the higher extraction yield of the fraction. The antioxidant activities of the fractions were determined by Rancimat and oven test on edible oils. The antioxidant activities of the fractions increased in the order of acetone>ethanol>methanol>50% methanol/water>water fraction, and the antioxidant activities of them were higher on lard than on soybean oil. The antioxidant activity of each fraction was strongly related to the contents of total phenol, total nitrogen content and acidity, whereas color intensity, reducing power, carboxylic acid content showed little contribution to the activity. All fractions had three peaks maxima at 208, 275 and 324 nm on UV-visible spectra, but the only one at 324 nm was linealy proportional to the antioxidant activities of the fractions.

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