• 제목/요약/키워드: UV-visible absorbance

검색결과 89건 처리시간 0.024초

흡광도법에 의한 주상변압기 절연유의 열화판정기준 설정에 관한 연구 (A Study on Suggestion of Insulating Oil Ageing Degree in Pole-Transformer by Absorbance)

  • 이동준;정종욱;김경화;곽희로;윤영자
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 하계학술대회 논문집 C
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    • pp.1851-1853
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    • 1996
  • In this paper the criteria for insulating oil condition of pole transformer were suggested by applying the UV-Visible spectrophotometric method. Ageing of insulating oil caused the change in absorbances of oil os well os the deterioration of electrical properties of oil. By comparing the electrical properties such as $tan{\delta}$ and breakdown voltage with the UV-Visible absorbances of oil, criteria for absorbance values determining oil condition were established. This UV-Visible spectrophotometric method might be applied in ageing analysis of oil and be expected to replace the current method.

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호장근 추출액에 의한 염색성(Ⅱ) - 호장근 추출액의 자외 · 가시부 분광 특성 - (The Dyeing Properties of Korean Knotweed Extract(Ⅱ) - The UV-visible Spectrophotometric Characteristics of Korean Knotweed Extracts -)

  • 김미숙;최석철
    • 한국염색가공학회지
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    • 제13권5호
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    • pp.10-10
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    • 2001
  • The Purpose of this study was to investigate spectrophotometric characteristics of Korean knotweed extracts. The properties were evaluated by it′s extracting solvent, effect of metallic ion, variations of pH values and effect of light exposure. The results were as following; The highest absorbance was found in methanol extract of Korean knotweed, while the lowest absorbance was carbon tetrachloride extract. The UV-vis. spectra of Korean knotweed colors in several solvents showed hypsochromic shift of n-π/sup */ transition with the polarity of solvent. Absorbance and peak of UV-vis. spectra of Korean knotweed colors became lower and broader by addition of metallic ion. The light stability in irradiation with xenon ]amp of the color solution with Cu were higher than those of Al and Fe. The UV-vis. spectra of Korean knotweed extracts in various pH values showed bathochromic shift under alkaline condition, and their peaks disappeared after 5 hours exposure.

호장근 추출액에 의한 염색성(II) -호장근 추출액의 자외 . 가시부 분광 특성 - (The Dyeing Properties of Korean Knotweed Extract( II ) - The UV-visible Spectrophotometric Characteristics of Korean Knotweed Extracts -)

  • 김미숙;최석철
    • 한국염색가공학회지
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    • 제13권5호
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    • pp.298-305
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    • 2001
  • The Purpose of this study was to investigate spectrophotometric characteristics of Korean knotweed extracts. The properties were evaluated by it's extracting solvent, effect of metallic ion, variations of pH values and effect of light exposure. The results were as following; The highest absorbance was found in methanol extract of Korean knotweed, while the lowest absorbance was carbon tetrachloride extract. The UV-vis. spectra of Korean knotweed colors in several solvents showed hypsochromic shift of $n->\pi^*$ transition with the polarity of solvent. Absorbance and peak of UV-vis. spectra of Korean knotweed colors became lower and broader by addition of metallic ion. The light stability in irradiation with xenon ]amp of the color solution with Cu were higher than those of Al and Fe. The UV-vis. spectra of Korean knotweed extracts in various pH values showed bathochromic shift under alkaline condition, and their Peaks disappeared after 5 hours exposure.

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Synthesis of CdSe-TiO2 Photocatalyst and Their Enhanced Photocatalytic Activities under UV and Visible Light

  • Lim, Chang-Sung;Chen, Ming-Liang;Oh, Won-Chun
    • Bulletin of the Korean Chemical Society
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    • 제32권5호
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    • pp.1657-1661
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    • 2011
  • In this study, CdSe-$TiO_2$ photocatalyst were synthesized by a facile solvothermal method and characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis and UV-vis diffuse reflectance spectrophotometer. The photocatalytic activity was investigated by degrading methylene blue (MB) in aqueous solution under irradiation of UV light as well as visible light. The absorbance of degraded MB solution was determined by UV-vis spectrophotometer. The results revealed that the CdSe-$TiO_2$ photocatalyst exhibited much higher photocatalytic activity than $TiO_2$ both under irradiation of UV light as well as visible light.

Enhanced UV-Visible Absorbance Detection in Capillary Electrophoresis Using Modified T-Shaped Post-Column Flow Cell

  • Lim, Kwan-Seop;Kim, Su-Hyeon;Hahn, Jong-Hoon
    • Bulletin of the Korean Chemical Society
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    • 제23권2호
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    • pp.295-300
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    • 2002
  • The construction of the T-shaped post-column flow cell has been changed to enhance the practicability as a UV-visible absorbance detector for capillary electrophoresis. In this new design, a rectangular cube-shaped inner structure is employed, which completely fits the outer rectangular tubing. This arrangement has greatly facilitated the fabrication of the T-cells. In addition, the volume for the auxiliary flow has been dramatically reduced down to 300 ${\mu}L$, and its volume flow rate is optimized at 4.2 ${\mu}L$/min. The short optical path length in the sheath flows (500 ${\mu}m$ on each side) minimizes background absorption, and thus enhances its performance in low-UV wavelengths. We have optimized the auxiliary flow rate at 50 ${\mu}m$/s, so that migration times are insensitive to the flow rate. This optimization has improved repeatabilities in migration times and peak heights. A double-beam detection scheme using a pair of photodiodes is employed to increase the signal-to-noise ratio.

Rutile-$TiO_2$를 이용한 Mordant Yellow-12의 광촉매 분해반응 (Photocatalytic Destruction of a Mordant Yellow-12 Using Rutile-$TiO_2$)

  • 김창석;최인원
    • 분석과학
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    • 제13권5호
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    • pp.646-651
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    • 2000
  • $TiO_2$ 촉매 하에 염료 Mordant Yellow-12를 광촉매 분해하였다. 이때 사용한 광원은 각각 15-W, 21-W와 26-W 형광 램프를 이용하였다. 분해 정도는 자외선-가시광선 분광기와 pH 메타를 이용하였다. 실험 결과 반응 1시간 후에 각 광원에 따라 각각 17%, 24%, 34% 이상의 분해를 보였고 완전히 분해되는데는 각각 3, 4, 5시간 걸렸다. pH의 변화는 흡광도의 변화와 같이 급격한 결과를 나타내지 않았다. 분해 반응 속도는 15-W 보다 26-W에서 2배의 빠를 분해 반응속도를 보였다.

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Mn-TiO2 촉매의 가시광촉매 특성 (The characteristics of Mn-TiO2 catalyst for visible-light photocatalyst)

  • 김문찬
    • 분석과학
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    • 제24권6호
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    • pp.493-502
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    • 2011
  • 본 연구에서는 가시광촉매의 특성을 나타낼 수 있는 촉매를 제조하여 촉매를 특성화 하였으며, toluene, xylene, MEK (methyl ethyl ketone), ammonia를 반응물로 하여 기존의 UV-광촉매와 분해능을 비교 실험하였다. UV-광촉매는 파장범위가 280~360 nm 근처에서 광촉매가 활성화된다. 그러나 가시광촉매는 가시광영역인 400~750 nm의 파장영역에서도 광촉매가 활성화 된다. 이것을 UV-Vis 흡수도로 파악하였다. 그리고 가시광촉매의 성능을 향상시키기 위하여 여러 가지 재료로 도핑하는데, 여기서는 망간에 Pt를 부가하여 성능향상을 꾀하였다. Pt를 첨가한 가시광 촉매의 경우 성능이 향상되었음을 알 수 있었다. 그리고 바인더로 MTMS (methyl tri methoxy silane)를 사용하였으며 바인더양에 따른 접촉각을 측정하였다. MTMS 함량이 증가할수록 접촉각이 커졌다. 따라서 친수성이 줄어든 것으로 나타났다. 그리고 Mn-$TiO_2$ 촉매의 항균성이 매우 우수한 것으로 나타났다.

VRFB-ESS용 전해질의 이온가수 분석방법 및 SOC 분석 (Analysis of Vanadium Ions and SOC in the Electrolytes of VRFB-ESS)

  • 서혜경;박원식;김강산
    • KEPCO Journal on Electric Power and Energy
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    • 제7권2호
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    • pp.309-316
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    • 2021
  • For the detection of the state of charge in VRFB-ESS, the analyses of UV-Visible spectrometry and the measurements of potential between the anolyte and catholyte were used in parallel. This paper includes the production of 4-valant ion from VOSO4 powder, 3- and 5-valant ions from electrochemical charge of 4-valant ion and 2-valant ion from 3-valant ion. It also includes the analyses of these valance ions and unknown electrolyte at any time using UV-Visible spectrometry. Through the analyses of the valance ions in samples, the SOCs of the samples at any charge-discharge times were verified.

지방산과 인지질의 혼합비에 따른 단분자 LB막의 광이성질화 현상에 관한 연구 (Photoisomerization of Monolayer LB Films mixed with Fatty Acid and Phospholipid at mixture ratios)

  • 박근호;강동완;김성일;박태곤
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.479-482
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    • 2000
  • We investigated UV-vis absorbances to observe photoisimerization and effect of temperature using the mixture solution in chloroform and the LB monolayer mixed with DLPE and 8A5H containing azobenzene which shows reversible cis-trans isomerization irradiated by alternate lights. We could find that the absorption spectrum of the mixtures solution and LB monolayer was reversibly induced to photoisomerization irradiated by Uv of both and visible lights, in addition the absorbance by alternate temperatures.

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폴리피롤을 이용한 약물전달시스템 (Using Polypyrrole for Drug Delivery System)

  • 이상조;이승기;오명환;박정호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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    • pp.448-451
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    • 2002
  • The possibility of using polypyrrole as a drug delivery system(DDS) has been studied using indicate (Phenol red) and substance with therapeutic activity(Sodium salicylate). In aqueous solution, negative potential is applied to polypyrrole then anion(with therapeutic activity) of sodium salicylate is released by redox processes of polypyrrole. The release amount of anionic drugs from polypyrrole is measured by UV-visible spectrometer which can measure UV-absorbance of materials. Electrode area that use for release amount measurement is$50mm^{2}(5{\times}10mm)$,and thickness of polypyrrole membrane is $15{\mu}m$. DC 1V applied in saline solution, the release amount according to time increased gradually. In various electrode area, release amount of anionic drug is directly to electrode area.

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