• Title/Summary/Keyword: UV-visible absorbance

Search Result 89, Processing Time 0.022 seconds

A Study on Suggestion of Insulating Oil Ageing Degree in Pole-Transformer by Absorbance (흡광도법에 의한 주상변압기 절연유의 열화판정기준 설정에 관한 연구)

  • Lee, Dong-Zoon;Jung, Jong-Uk;Kim, Kyung-Hwa;Kwak, Hee-Ro;Yun, Yong-Ja
    • Proceedings of the KIEE Conference
    • /
    • 1996.07c
    • /
    • pp.1851-1853
    • /
    • 1996
  • In this paper the criteria for insulating oil condition of pole transformer were suggested by applying the UV-Visible spectrophotometric method. Ageing of insulating oil caused the change in absorbances of oil os well os the deterioration of electrical properties of oil. By comparing the electrical properties such as $tan{\delta}$ and breakdown voltage with the UV-Visible absorbances of oil, criteria for absorbance values determining oil condition were established. This UV-Visible spectrophotometric method might be applied in ageing analysis of oil and be expected to replace the current method.

  • PDF

The Dyeing Properties of Korean Knotweed Extract(Ⅱ) - The UV-visible Spectrophotometric Characteristics of Korean Knotweed Extracts - (호장근 추출액에 의한 염색성(Ⅱ) - 호장근 추출액의 자외 · 가시부 분광 특성 -)

  • Kim, Mi Suk;Choe, Seok Cheol
    • Textile Coloration and Finishing
    • /
    • v.13 no.5
    • /
    • pp.10-10
    • /
    • 2001
  • The Purpose of this study was to investigate spectrophotometric characteristics of Korean knotweed extracts. The properties were evaluated by it′s extracting solvent, effect of metallic ion, variations of pH values and effect of light exposure. The results were as following; The highest absorbance was found in methanol extract of Korean knotweed, while the lowest absorbance was carbon tetrachloride extract. The UV-vis. spectra of Korean knotweed colors in several solvents showed hypsochromic shift of n-π/sup */ transition with the polarity of solvent. Absorbance and peak of UV-vis. spectra of Korean knotweed colors became lower and broader by addition of metallic ion. The light stability in irradiation with xenon ]amp of the color solution with Cu were higher than those of Al and Fe. The UV-vis. spectra of Korean knotweed extracts in various pH values showed bathochromic shift under alkaline condition, and their peaks disappeared after 5 hours exposure.

The Dyeing Properties of Korean Knotweed Extract( II ) - The UV-visible Spectrophotometric Characteristics of Korean Knotweed Extracts - (호장근 추출액에 의한 염색성(II) -호장근 추출액의 자외 . 가시부 분광 특성 -)

  • 김미숙;최석철
    • Textile Coloration and Finishing
    • /
    • v.13 no.5
    • /
    • pp.298-305
    • /
    • 2001
  • The Purpose of this study was to investigate spectrophotometric characteristics of Korean knotweed extracts. The properties were evaluated by it's extracting solvent, effect of metallic ion, variations of pH values and effect of light exposure. The results were as following; The highest absorbance was found in methanol extract of Korean knotweed, while the lowest absorbance was carbon tetrachloride extract. The UV-vis. spectra of Korean knotweed colors in several solvents showed hypsochromic shift of $n->\pi^*$ transition with the polarity of solvent. Absorbance and peak of UV-vis. spectra of Korean knotweed colors became lower and broader by addition of metallic ion. The light stability in irradiation with xenon ]amp of the color solution with Cu were higher than those of Al and Fe. The UV-vis. spectra of Korean knotweed extracts in various pH values showed bathochromic shift under alkaline condition, and their Peaks disappeared after 5 hours exposure.

  • PDF

Synthesis of CdSe-TiO2 Photocatalyst and Their Enhanced Photocatalytic Activities under UV and Visible Light

  • Lim, Chang-Sung;Chen, Ming-Liang;Oh, Won-Chun
    • Bulletin of the Korean Chemical Society
    • /
    • v.32 no.5
    • /
    • pp.1657-1661
    • /
    • 2011
  • In this study, CdSe-$TiO_2$ photocatalyst were synthesized by a facile solvothermal method and characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis and UV-vis diffuse reflectance spectrophotometer. The photocatalytic activity was investigated by degrading methylene blue (MB) in aqueous solution under irradiation of UV light as well as visible light. The absorbance of degraded MB solution was determined by UV-vis spectrophotometer. The results revealed that the CdSe-$TiO_2$ photocatalyst exhibited much higher photocatalytic activity than $TiO_2$ both under irradiation of UV light as well as visible light.

Enhanced UV-Visible Absorbance Detection in Capillary Electrophoresis Using Modified T-Shaped Post-Column Flow Cell

  • Lim, Kwan-Seop;Kim, Su-Hyeon;Hahn, Jong-Hoon
    • Bulletin of the Korean Chemical Society
    • /
    • v.23 no.2
    • /
    • pp.295-300
    • /
    • 2002
  • The construction of the T-shaped post-column flow cell has been changed to enhance the practicability as a UV-visible absorbance detector for capillary electrophoresis. In this new design, a rectangular cube-shaped inner structure is employed, which completely fits the outer rectangular tubing. This arrangement has greatly facilitated the fabrication of the T-cells. In addition, the volume for the auxiliary flow has been dramatically reduced down to 300 ${\mu}L$, and its volume flow rate is optimized at 4.2 ${\mu}L$/min. The short optical path length in the sheath flows (500 ${\mu}m$ on each side) minimizes background absorption, and thus enhances its performance in low-UV wavelengths. We have optimized the auxiliary flow rate at 50 ${\mu}m$/s, so that migration times are insensitive to the flow rate. This optimization has improved repeatabilities in migration times and peak heights. A double-beam detection scheme using a pair of photodiodes is employed to increase the signal-to-noise ratio.

Photocatalytic Destruction of a Mordant Yellow-12 Using Rutile-$TiO_2$ (Rutile-$TiO_2$를 이용한 Mordant Yellow-12의 광촉매 분해반응)

  • Kim, Chang Suk;Choi, In Won
    • Analytical Science and Technology
    • /
    • v.13 no.5
    • /
    • pp.646-651
    • /
    • 2000
  • The photocatalytic degradation of Mordant Yellow-12 (MY-12) was investigated using a UV-Visible Spectrophotometer and pH meter. The UV-Visible absorbance spectra of the MY-12 contaminated water before and after treatment were presented in figure. The decrease of absorbance occurs at the range of 250 and 450 nm, this result suggests that photocatalytic degradation involves destruction of the aromatic rings in this experiment. More than 32% of the MY-12 was decomposed after one hour in 26-W fluorescent lamp, whereas it was 17% and 24% respectively in 15-W and 21-W lamps. MY-12 was decomposed completely after three hours in 26-W fluorescent lamp. The destruction rate constants were calculated from the change of absorbance and pH.

  • PDF

The characteristics of Mn-TiO2 catalyst for visible-light photocatalyst (Mn-TiO2 촉매의 가시광촉매 특성)

  • Kim, Moon-Chan
    • Analytical Science and Technology
    • /
    • v.24 no.6
    • /
    • pp.493-502
    • /
    • 2011
  • The catalyst works for visible-light region was characterized. Toluene, xylene, MEK and ammonia were used as reactants. The decomposition efficiency was compared between visible-light photocatalyst and UV-light one. UV-photocatalyst can be activated with UV-light wave length of 280~360 nm. However, visible-light photocatalyst can be activated with visible wave length of 400~750 nm. This result was found by using UV-Vis absorbance. A lot of materials were doped to visible light photocatalyst in order to increase its performance. Platinum was added to visible light photocatalyst with manganese in order to increase performance of the visible light photocatalyst. MTMS (Methyl tri methoxy silane) was used as a binder. Contact angle was analyzed varying with amount of binder. Contact angle was increased with increasing the amount of MTMS. As a result, the hydrophilic property of photocatalyst with MTMS binder was decreased due to its hydrophobic one. And Mn-$TiO_2$ catalyst had an excellent anti-bacterial property.

Analysis of Vanadium Ions and SOC in the Electrolytes of VRFB-ESS (VRFB-ESS용 전해질의 이온가수 분석방법 및 SOC 분석)

  • Seo, Hai-Kyung;Park, Wonshik;Kim, Kangsan
    • KEPCO Journal on Electric Power and Energy
    • /
    • v.7 no.2
    • /
    • pp.309-316
    • /
    • 2021
  • For the detection of the state of charge in VRFB-ESS, the analyses of UV-Visible spectrometry and the measurements of potential between the anolyte and catholyte were used in parallel. This paper includes the production of 4-valant ion from VOSO4 powder, 3- and 5-valant ions from electrochemical charge of 4-valant ion and 2-valant ion from 3-valant ion. It also includes the analyses of these valance ions and unknown electrolyte at any time using UV-Visible spectrometry. Through the analyses of the valance ions in samples, the SOCs of the samples at any charge-discharge times were verified.

Photoisomerization of Monolayer LB Films mixed with Fatty Acid and Phospholipid at mixture ratios (지방산과 인지질의 혼합비에 따른 단분자 LB막의 광이성질화 현상에 관한 연구)

  • 박근호;강동완;김성일;박태곤
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2000.07a
    • /
    • pp.479-482
    • /
    • 2000
  • We investigated UV-vis absorbances to observe photoisimerization and effect of temperature using the mixture solution in chloroform and the LB monolayer mixed with DLPE and 8A5H containing azobenzene which shows reversible cis-trans isomerization irradiated by alternate lights. We could find that the absorption spectrum of the mixtures solution and LB monolayer was reversibly induced to photoisomerization irradiated by Uv of both and visible lights, in addition the absorbance by alternate temperatures.

  • PDF

Using Polypyrrole for Drug Delivery System (폴리피롤을 이용한 약물전달시스템)

  • Lee, Sang-Jo;Lee, Seung-Ki;Oh, Myung-Hwan;Park, Jung-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2002.11a
    • /
    • pp.448-451
    • /
    • 2002
  • The possibility of using polypyrrole as a drug delivery system(DDS) has been studied using indicate (Phenol red) and substance with therapeutic activity(Sodium salicylate). In aqueous solution, negative potential is applied to polypyrrole then anion(with therapeutic activity) of sodium salicylate is released by redox processes of polypyrrole. The release amount of anionic drugs from polypyrrole is measured by UV-visible spectrometer which can measure UV-absorbance of materials. Electrode area that use for release amount measurement is$50mm^{2}(5{\times}10mm)$,and thickness of polypyrrole membrane is $15{\mu}m$. DC 1V applied in saline solution, the release amount according to time increased gradually. In various electrode area, release amount of anionic drug is directly to electrode area.

  • PDF